Wash 562 Safety Data Sheet

Transcription

1 0 Date of issue: 05/05/2015 Revision date: 14/04/2015 : Version: 2.1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Trade name : 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.3. Supplier's details Heidelberg Druckmaschinen AG Kurfuersten-Anlage 60 D Heidelberg - GERMANY T F Consumables-msds@heidelberg.com 1.4. Emergency telephone number Emergency number : SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification Flam. Liq. 4 Skin Irrit. 3 Asp. Tox. 1 Full text of H-phrases: see section 16 H227 H316 H304 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling Hazard pictograms (GHS-UN) : Signal word (GHS-UN) Hazardous ingredients Hazard statements (GHS-UN) Precautionary statements (GHS-UN) : Danger GHS08 : Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, <2% aromatics : H227 - Combustible liquid H304 - May be fatal if swallowed and enters airways H316 - Causes mild skin irritation : P210 - Keep away from heat. - No smoking P280 - Wear eye protection, protective gloves P301+P310 - IF SWALLOWED: Immediately call a doctor P331 - Do NOT induce vomiting P332+P313 - If skin irritation occurs: Get medical advice/attention P370+P378 - In case of fire: Use carbon dioxide (CO2), dry sand, extinguishing powder, foam to extinguish 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substance 3.2. Mixture 05/05/2015 EN (English) 1/5

2 Name Product identifier % Classification according to the United Nations GHS (Rev. 4, 2011) Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, <2% aromatics Full text of H-phrases: see section 16 >= 50 Flam. Liq. 4, H227 Acute Tox. Not classified (Oral) Acute Tox. Not classified (Dermal) Skin Irrit. 3, H316 Asp. Tox. 1, H304 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Allow victim to breathe fresh air. Allow the victim to rest. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. Repeated exposure may cause skin dryness or cracking. : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. : Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/physician Most important symptoms and effects, both acute and delayed Symptoms/injuries after ingestion : May be fatal if swallowed and enters airways Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream Special hazards arising from the substance or mixture Reactivity : Stable under normal conditions Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials : Keep only in the original container in a cool, well ventilated place away from : Direct sunlight. Keep container closed when not in use. : Strong bases. Strong acids. : Sources of ignition. Direct sunlight. 05/05/2015 EN (English) 2/5

3 SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Personal protective equipment : Avoid all unnecessary exposure. Hand protection Eye protection Respiratory protection : Protective gloves. PICM009. : Chemical goggles or safety glasses. PICM004. : In case of insufficient ventilation, wear suitable respiratory equipment. : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour : Blue. Odour : characteristic. Odour threshold ph : Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point : > 160 C Flash point : > 62 C Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density : 0,796 Solubility : Water: Slightly soluble Log Pow Log Kow Viscosity, kinematic : 1,7872 mm²/s Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. VOC content : 773,9 g/l SECTION 10: Stability and reactivity Reactivity Stable under normal conditions Chemical stability Stable under normal conditions Possibility of hazardous reactions Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Strong acids. Strong bases Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. 05/05/2015 EN (English) 3/5

4 SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, <2% aromatics LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 5000 mg/kg LC50 inhalation rat (mg/l) 4,951 mg/kg Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Viscosity, kinematic Potential adverse human health effects and symptoms : Causes mild skin irritation. ph: ph: : May be fatal if swallowed and enters airways. 1,7872 mm²/s : Based on available data, the classification criteria are not met. SECTION 12: Ecological information Toxicity Persistence and degradability Persistence and degradability Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, <2% aromatics Persistence and degradability May biodegrade Bioaccumulative potential Bioaccumulative potential Mobility in soil Other adverse effects : Avoid release to the environment. SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations Ecology - waste materials SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN : Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to Dispose in a safe manner in accordance with local/national regulations. : Avoid release to the environment. Hazardous waste due to toxicity. ADR IMDG IATA ADN RID UN number Not regulated for transport UN proper shipping name Not classified as dangerous in the meaning of transport Not classified as dangerous in the Not classified as dangerous in the meaning of transport 05/05/2015 EN (English) 4/5

5 ADR IMDG IATA ADN RID regulations meaning of transport regulations regulations Transport hazard class(es) Packing group Environmental hazards Marine pollutant Special precautions for user Overland transport Transport regulations (ADR) Transport by sea Transport regulations (IMDG) Air transport Transport regulations (IATA) Inland waterway transport Carriage prohibited (ADN) Not subject to ADN Rail transport Transport regulations (RID) Carriage prohibited (RID) Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture SECTION 16: Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. ne. Full text of H-phrases: Acute Tox. Not classified (Dermal) Acute toxicity (dermal) Not classified Acute Tox. Not classified (Oral) Acute toxicity (oral) Not classified Asp. Tox. 1 Aspiration hazard, Category 1 Flam. Liq. 4 Flammable liquids, Category 4 Skin Irrit. 3 Skin corrosion/irritation, Category 3 H304 May be fatal if swallowed and enters airways SDS UN This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 05/05/2015 EN (English) 5/5