: POLIMER PRO TRANSPARENTE 290ML

Transcription

1 Date of issue: 19/12/2014 Revision date: 19/12/2014 : Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : Product code : Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Intended for general public Main use category : Industrial use,professional use,consumer use Uses advised against 1.3. Details of the supplier of the safety data sheet KRAFFT S.L.U. Ctra. Urnieta s/n Andoain - España T F msds@krafft.es 1.4. Emergency telephone number Emergency number : Office hours SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Not classified Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Not classified Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Precautionary statements (CLP) EUH phrases : P102 - Keep out of reach of children : EUH208 - Contains ( ). May produce an allergic reaction 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification according to Directive 67/548/EEC trimethoxyvinylsilane (CAS No) (REACH-no) ,5 Xn; R20 R10 Solvent naphtha (petroleum), light arom., Low boiling point naphtha - unspecified, [A complex combination of hydrocarbons obtained from distillation of aromatic streams. It consists predominantly of aromatic hydrocarbons having carbon numbers predominantly in the range of C8 through C10 and boiling in the range of approximately 135 C to 210 C (275 F to 410 F).] (CAS No) (EC no) (EC index no) (REACH-no) ,1-1 Xn; R65 Xi; R37 N; R51/53 R10 R66 R67 24/02/2015 EN (English) 1/6

2 Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] trimethoxyvinylsilane (CAS No) (REACH-no) Solvent naphtha (petroleum), light arom., Low boiling point naphtha - unspecified, [A complex combination of hydrocarbons obtained from distillation of aromatic streams. It consists predominantly of aromatic hydrocarbons having carbon numbers predominantly in the range of C8 through C10 and boiling in the range of approximately 135 C to 210 C (275 F to 410 F).] Full text of R- and H-phrases: see section 16 (CAS No) (EC no) (EC index no) (REACH-no) ,5 Flam. Liq. 3, H226 Acute Tox. 4 (Inhalation), H332 0,1-1 Flam. Liq. 3, H226 STOT SE 3, H336 STOT SE 3, H335 Asp. Tox. 1, H304 Aquatic Chronic 2, H411 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Allow victim to breathe fresh air. Allow the victim to rest. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Most important symptoms and effects, both acute and delayed Symptoms/injuries : Not expected to present a significant hazard under anticipated conditions of normal use Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream Special hazards arising from the substance or mixture 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. 24/02/2015 EN (English) 2/6

3 7.2. Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials 7.3. Specific end use(s) : Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use. : Strong bases. Strong acids. SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Sources of ignition. Direct sunlight Exposure controls Personal protective equipment Hand protection Eye protection Respiratory protection Other information : Avoid all unnecessary exposure. : Wear protective gloves : Chemical goggles or safety glasses : Wear appropriate mask : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour : Colourless. Odour : characteristic. Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point : > 150 C Auto-ignition temperature Decomposition temperature Flammability (solid, gas) : Non flammable Vapour pressure Relative vapour density at 20 C Relative density : 1 Solubility Log Pow Viscosity, kinematic : > 21 cst Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Direct sunlight. Extremely high or low temperatures. 24/02/2015 EN (English) 3/6

4 10.5. Incompatible materials Strong acids. Strong bases Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity trimethoxyvinylsilane ( ) LD50 oral rat LC50 inhalation rat (mg/l) LC50 inhalation rat (ppm) 7460 mg/kg 16,79 mg/l/4h 2773 ppm/4h Solvent naphtha (petroleum), light arom., Low boiling point naphtha - unspecified, [A complex combination of hydrocarbons obtained from distillation of aromatic streams. It consists predominantly of aromatic hydrocarbons having carbon numbers predominantly in the range of C8 through C10 and boiling in the range of approximately 135 C to 210 C (275 F to 410 F).] ( ) LD50 oral rat 3900 mg/kg LD50 dermal rabbit 3160 mg/kg Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Viscosity, kinematic Potential adverse human health effects and symptoms > 21 mm²/s :. SECTION 12: Ecological information Toxicity Persistence and degradability Persistence and degradability Bioaccumulative potential Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects Additional information : Avoid release to the environment 24/02/2015 EN (English) 4/6

5 SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations Ecology - waste materials SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN : Dispose in a safe manner in accordance with local/national regulations. : Avoid release to the environment. ADR IMDG IATA ADN RID UN number Not regulated for transport UN proper shipping name Transport hazard class(es) Packing group Environmental hazards Marine pollutant : No Special precautions for user Overland transport Transport by sea Air transport Inland waterway transport Not subject to ADN : No Rail transport Carriage prohibited (RID) : No Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances National regulations Germany Water hazard class (WGK) : 3 - severe hazard to waters Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information Data sources Other information : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. : None. Full text of R-, H- and EUH-phrases: Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4 Aquatic Chronic 2 Hazardous to the aquatic environment Chronic Hazard, Category 2 24/02/2015 EN (English) 5/6

6 Asp. Tox. 1 Aspiration hazard, Category 1 Flam. Liq. 3 Flammable liquids, Category 3 STOT SE 3 Specific target organ toxicity Single exposure, Category 3, Narcosis STOT SE 3 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H226 Flammable liquid and vapour H304 May be fatal if swallowed and enters airways H332 Harmful if inhaled H335 May cause respiratory irritation H336 May cause drowsiness or dizziness H411 Toxic to aquatic life with long lasting effects R10 Flammable R20 Harmful by inhalation R37 Irritating to respiratory system R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment R65 Harmful: may cause lung damage if swallowed R66 Repeated exposure may cause skin dryness or cracking R67 Vapours may cause drowsiness and dizziness N environment Xi Irritant Xn Harmful SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 24/02/2015 EN (English) 6/6