3.2. Mixture Name Product identifier % Classification according to Directive 67/548/EEC

Transcription

1 Date of issue: 05/03/2015 Revision date: : Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : S2000 Product group : Ancillaries 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Industrial/Professional use spec : Industrial For professional use only Uses advised against 1.3. Details of the supplier of the safety data sheet U-POL LIMITED Denington Road NN8 2QH Wellingborough - UK T +44 (0) F +44 (0) technical.department@u-pol.com Emergency telephone number Emergency number : (07:30-17:00hrs UK time) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Not classified Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Not classified Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] EUH phrases : EUH210 - Safety data sheet available on request 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification according to Directive 67/548/EEC propan-2-ol (CAS No) (EC no) (EC index no) F; R11 Xi; R36 R67 2-butoxyethyl acetate, butylglycol acetate (CAS No) (EC no) (EC index no) Xn; R20/21 Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] propan-2-ol (CAS No) (EC no) (EC index no) Flam. Liq. 2, H225 Eye Irrit. 2, H319 STOT SE 3, H336 17/03/2015 EN (English) SDS Ref.: S2000 1/7

2 Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] 2-butoxyethyl acetate, butylglycol acetate (CAS No) (EC no) (EC index no) Full text of R- and H-phrases: see section Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Inhalation), H332 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Allow victim to breathe fresh air. Allow the victim to rest. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Most important symptoms and effects, both acute and delayed Symptoms/injuries t expected to present a significant hazard under anticipated conditions of normal use Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream Special hazards arising from the substance or mixture 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Protective equipment Emergency procedures For emergency responders Protective equipment Emergency procedures : Safety glasses. Protective clothing. Gloves. : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up For containment Methods for cleaning up 6.4. Reference to other sections : Contain leaking substance. Collect spillage. : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. See Heading 8. Exposure controls and personal protection. For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. : Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use. Keep container closed when not in use. 17/03/2015 EN (English) SDS Ref.: S2000 2/7

3 Incompatible products Incompatible materials Storage temperature : < 25 C Special rules on packaging 7.3. Specific end use(s) : Strong bases. Strong acids. : Sources of ignition. Direct sunlight. : Keep only in original container. SECTION 8: Exposure controls/personal protection 8.1. Control parameters propan-2-ol ( ) United Kingdom Local name Propan-2-ol United Kingdom WEL TWA (mg/m³) 999 mg/m³ United Kingdom WEL TWA (ppm) 400 ppm United Kingdom WEL STEL (mg/m³) 1250 mg/m³ United Kingdom WEL STEL (ppm) 500 ppm 2-butoxyethyl acetate, butylglycol acetate ( ) EU Local name 2-Butoxyethyl acetate EU IOELV TWA (mg/m³) 133 mg/m³ EU IOELV TWA (ppm) 20 ppm EU IOELV STEL (mg/m³) 333 mg/m³ EU IOELV STEL (ppm) 50 ppm EU Notes Skin United Kingdom Local name 2-Butoxyethyl acetate United Kingdom WEL TWA (mg/m³) 133 mg/m³ United Kingdom WEL TWA (ppm) 20 ppm United Kingdom WEL STEL (mg/m³) 332 mg/m³ United Kingdom WEL STEL (ppm) 50 ppm United Kingdom Remark (WEL) Sk 8.2. Exposure controls Personal protective equipment Materials for protective clothing Hand protection Eye protection Skin and body protection Respiratory protection Other information : Avoid all unnecessary exposure. : Impermeable clothing : Wear protective gloves : Chemical goggles or safety glasses : Wear suitable protective clothing : Wear appropriate mask : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Liquid. Colour : Colourless. Odour : slight. Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point : 100 C Flash point : > 100 C Auto-ignition temperature Decomposition temperature Flammability (solid, gas) n flammable Vapour pressure Relative vapour density at 20 C Relative density 17/03/2015 EN (English) SDS Ref.: S2000 3/7

4 Density : Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits : Miscible with water Other information VOC content VOC content - Actual VOC content - Regulatory SECTION 10: Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Strong acids. Strong bases Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Potential adverse human health effects and symptoms :. SECTION 12: Ecological information Toxicity 17/03/2015 EN (English) SDS Ref.: S2000 4/7

5 12.2. Persistence and degradability S2000 Persistence and degradability Bioaccumulative potential S2000 Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects Additional information : Avoid release to the environment SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number Not regulated for transport UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport hazard class(es) ADR Transport hazard class(es) (ADR) IMDG Transport hazard class(es) (IMDG) IATA Transport hazard class(es) (IATA) ADN Transport hazard class(es) (ADN) RID Transport hazard class(es) (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information supplementary information available 17/03/2015 EN (English) SDS Ref.: S2000 5/7

6 14.6. Special precautions for user Overland transport Transport by sea Air transport Inland waterway transport Carriage prohibited (ADN) Not subject to ADN Rail transport Carriage prohibited (RID) Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no substances with Annex XVII restrictions S2000 is not on the REACH Candidate List Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances VOC content Seveso Information : This product is not subject to the Seveso Directive National regulations Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information Data sources Other information : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. ne. Full text of R-, H- and EUH-phrases: Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4 Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Flam. Liq. 2 Flammable liquids, Category 2 STOT SE 3 Specific target organ toxicity Single exposure, Category 3, Narcosis H225 H302 H319 H332 H336 R11 Highly flammable liquid and vapour Harmful if swallowed Causes serious eye irritation Harmful if inhaled May cause drowsiness or dizziness Highly flammable R20/21 Harmful by inhalation and in contact with skin R36 Irritating to eyes R67 F Xi Xn Vapours may cause drowsiness and dizziness Highly flammable Irritant Harmful 17/03/2015 EN (English) SDS Ref.: S2000 6/7

7 UPOL SDS EU (no product code) For professional use only. The information contained within this (SDS) is believed to be correct as of the date issued however it is subject to change from time to time. It does not purport to be all inclusive or exhaustive and shall only be used as a guide. U-POL makes no warranties, expressed or implied, including but not limited to, any implied warranty of fitness for a given purpose or usage. It is the Buyers responsibility to ensure the suitability of the products for their own use and to check the information is up to date. U-POL cannot be held responsible for the suitability of use for any of its products, considering the wide range of factors such as application, substrates and handling methods. Since these conditions of use are outside of our control, the company shall not be held liable for any damage resulting from handling or from contact with the product detailed. Moreover, addition of reducers, hardeners or other additives over and above U-POL s recommendations for use, may substantially alter the composition and hazards of the product. U-POL data sheets are available via the U-POL website at 17/03/2015 EN (English) SDS Ref.: S2000 7/7