: P38-R. SECTION 1: Identification of the substance/mixture and of the company/undertaking. SECTION 2: Hazards identification Product identifier
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1 Date of issue: 3/18/2015 Revision date: 6/27/2016 Version: 2.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : P38-R Product group : Bodyfiller 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Intended for general public Industrial/Professional use spec Function or use category : Intended for general public : Fillers Uses advised against 1.3. Details of the supplier of the safety data sheet U-POL LIMITED Denington Road, Wellingborough NN8 2QH - UK T +44 (0) F +44 (0) technical.department@u-pol.com Emergency telephone number Emergency number : +44 (0) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Skin corrosion/irritation, Category 2 Serious eye damage/eye irritation, Category 2 Reproductive toxicity, Category 2 H315 H319 H361 Specific target organ toxicity Repeated exposure, Category 1 H372 Full text of hazard classes and H-statements : see section 16 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) : Signal word (CLP) Hazardous ingredients Hazard statements (CLP) Precautionary statements (CLP) : Danger : styrene GHS07 GHS08 : H315 - Causes skin irritation H319 - Causes serious eye irritation H361 - Suspected of damaging the unborn child H372 - Causes damage to organs (hearing organs) through prolonged or repeated exposure (Inhalation) : P102 - Keep out of reach of children P261 - Avoid breathing fume, vapours P263 - Avoid contact during pregnancy/while nursing P264 - Wash hands thoroughly after handling P280 - Wear eye protection, protective clothing, protective gloves P302+P352 - IF ON SKIN: Wash with plenty of water 7/7/2016 EN (English) SDS Ref.: P38-R 1/7
2 P305 - IF IN EYES: Wash with plenty of water and if necessary take medical advice 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] styrene (CAS No) (EC no) (REACH-no) Full text of H-statements: see section Flam. Liq. 3, H226 Acute Tox. 4 (Inhalation:dust,mist), H332 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Repr. 2, H361d STOT RE 1, H372 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. IF exposed or concerned: Get medical advice/attention. : Assure fresh air breathing. Allow the victim to rest. : Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. Get medical advice/attention. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Get medical advice/attention. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Most important symptoms and effects, both acute and delayed Symptoms/injuries Symptoms/injuries after skin contact Symptoms/injuries after eye contact : Suspected of damaging fertility or the unborn child. Causes damage to organs through prolonged or repeated exposure. : Causes skin irritation. : Causes serious eye irritation Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream Special hazards arising from the substance or mixture 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Remove ignition sources For non-emergency personnel Protective equipment Emergency procedures : Safety glasses. Protective clothing. Gloves. : Evacuate unnecessary personnel. 7/7/2016 EN (English) SDS Ref.: P38-R 2/7
3 For emergency responders Protective equipment Emergency procedures : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up For containment Methods for cleaning up 6.4. Reference to other sections : Contain leaking substance. Collect spillage. : On land, sweep or shovel into suitable containers. Minimize generation of dust. Store away from other materials. See Heading 8. Exposure controls and personal protection. For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe dust, fume. : Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials Storage temperature : < 25 C Special rules on packaging 7.3. Specific end use(s) : Keep only in the original container in a cool, well ventilated place away from : Ignition sources, Heat sources. Keep container closed when not in use. : Strong bases. Strong acids. : Sources of ignition. Direct sunlight. : Keep only in original container. SECTION 8: Exposure controls/personal protection 8.1. Control parameters styrene ( ) United Kingdom Local name Styrene United Kingdom WEL TWA (mg/m³) 430 mg/m³ United Kingdom WEL TWA (ppm) 100 ppm United Kingdom WEL STEL (mg/m³) 1080 mg/m³ United Kingdom WEL STEL (ppm) 250 ppm 8.2. Exposure controls Personal protective equipment : Avoid all unnecessary exposure. Materials for protective clothing: Impermeable clothing Hand protection: Wear protective gloves Eye protection: Chemical goggles or safety glasses Skin and body protection: Wear suitable protective clothing Respiratory protection: Wear appropriate mask Other information : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid 7/7/2016 EN (English) SDS Ref.: P38-R 3/7
4 Appearance Colour Odour Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point : Paste. : Light grey. : aromatic. Flash point : 32 C Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density : Non flammable Density : Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits : insoluble in water. soluble in most organic solvents Other information VOC content : 236 g/l SECTION 10: Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Strong acids. Strong bases Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) : Causes skin irritation. : Causes serious eye irritation. Based on available data, the classification criteria are not met : Suspected of damaging the unborn child. 7/7/2016 EN (English) SDS Ref.: P38-R 4/7
5 Specific target organ toxicity (repeated exposure) Aspiration hazard Potential adverse human health effects and symptoms : Causes damage to organs (hearing organs) through prolonged or repeated exposure (Inhalation).. SECTION 12: Ecological information Toxicity Persistence and degradability P38-R Persistence and degradability Bioaccumulative potential P38-R Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects : Avoid release to the environment SECTION 13: Disposal considerations Waste treatment methods Regional legislation (waste) Waste disposal recommendations Ecology - waste materials SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN : Disposal must be done according to official regulations. : Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to Remove waste in accordance with local and/or national regulations. : Avoid release to the environment UN number UN-No. (ADR) UN-No. (IMDG) UN-No. (IATA) UN-No. (ADN) UN-No. (RID) UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport hazard class(es) ADR Transport hazard class(es) (ADR) IMDG Transport hazard class(es) (IMDG) IATA Transport hazard class(es) (IATA) 7/7/2016 EN (English) SDS Ref.: P38-R 5/7
6 ADN Transport hazard class(es) (ADN) RID Transport hazard class(es) (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information : No : No : No supplementary information available Special precautions for user - Overland transport - Transport by sea - Air transport - Inland waterway transport - Rail transport Transport in bulk according to Annex II of MARPOL and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances VOC content : 236 g/l National regulations Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information Data sources Other information : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. : None. Full text of H- and EUH-statements: Acute Tox. 4 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category 4 7/7/2016 EN (English) SDS Ref.: P38-R 6/7
7 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Flam. Liq. 3 Flammable liquids, Category 3 Repr. 2 Reproductive toxicity, Category 2 Repr. 2 Reproductive toxicity, Category 2 Skin Irrit. 2 Skin corrosion/irritation, Category 2 STOT RE 1 Specific target organ toxicity Repeated exposure, Category 1 H226 Flammable liquid and vapour H315 H319 H332 H361 H361d H372 Causes skin irritation Causes serious eye irritation Harmful if inhaled Suspected of damaging fertility or the unborn child Suspected of damaging the unborn child Causes damage to organs through prolonged or repeated exposure Skin Irrit. 2 H315 Calculation method Eye Irrit. 2 H319 Calculation method Repr. 2 H361 Calculation method STOT RE 1 H372 Calculation method UPOL SDS EU (no product code) The information contained within this (SDS) is believed to be correct as of the date issued however it is subject to change from time to time. It does not purport to be all inclusive or exhaustive and shall only be used as a guide. U-POL makes no warranties, expressed or implied, including but not limited to, any implied warranty of fitness for a given purpose or usage. It is the Buyers responsibility to ensure the suitability of the products for their own use and to check the information is up to date. U-POL cannot be held responsible for the suitability of use for any of its products, considering the wide range of factors such as application, substrates and handling methods. Since these conditions of use are outside of our control, the company shall not be held liable for any damage resulting from handling or from contact with the product detailed. Moreover, addition of reducers, hardeners or other additives over and above U-POL s recommendations for use, may substantially alter the composition and hazards of the product. U-POL data sheets are available via the U-POL website at 7/7/2016 EN (English) SDS Ref.: P38-R 7/7
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