: Anti-Sulphate Solution

Transcription

1 Date of issue: 28/10/2014 Revision date: : Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Trade name : Anti-Sulphate Solution Product code : 47 / 475 Product group : Trade product 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Intended for general public Main use category Industrial/Professional use spec : Consumer use,professional use : Industrial For professional use only Uses advised against 1.3. Details of the supplier of the safety data sheet Kingfisher Building Products Cooper Lane LA12 9RA Ulverston - UK T F craig@kingfisheruk.com Emergency telephone number Emergency number : (8:00-17:00 UK time) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]Show CLP information + DPD classification in section 2.1 Acute Tox. 4 (Oral) H302 Full text of H-phrases: see section 16 Classification according to Directive 67/548/EEC or 1999/45/EC R10 Full text of R-phrases: see section 16 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) : Signal word (CLP) Hazard statements (CLP) Precautionary statements (CLP) GHS07 : Warning : H302 - Harmful if swallowed : P102 - Keep out of reach of children P264 - Wash... thoroughly after handling P270 - Do not eat, drink or smoke when using this product P301 + P312 - IF SWALLOWED: Call a POISON CENTER/doctor/ if you feel unwell P330 - Rinse mouth P501 - Dispose of contents/container to hazardous or special waste collection point 2.3. Other hazards 28/10/2014 EN (English) 1/6

2 SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture This mixture does not contain any substances to be mentioned according to the criteria of section 3.2 of REACH annex II SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Assure fresh air breathing. Allow the victim to rest. : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Most important symptoms and effects, both acute and delayed Symptoms/injuries t expected to present a significant hazard under anticipated conditions of normal use Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream Special hazards arising from the substance or mixture Fire hazard : Heating may cause a fire. Self-heating: may catch fire. Flammable liquid and vapour. Explosion hazard : Risk of explosion if heated under confinement. May form flammable/explosive vapour-air mixture Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Avoid (reject) fire-fighting water to enter environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Remove ignition sources. Use special care to avoid static electric charges. No naked lights. No smoking For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed Precautions for safe handling : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. : Handle empty containers with care because residual vapours are flammable. : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. No naked lights. No smoking. Take precautionary measures against static discharge. Use only non-sparking tools. 28/10/2014 EN (English) 2/6

3 7.2. Conditions for safe storage, including any incompatibilities Technical measures Storage conditions Incompatible products Incompatible materials 7.3. Specific end use(s) : Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. : Keep only in the original container in a cool, well ventilated place away from : Keep container tightly closed. : Strong bases. Strong acids. SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Sources of ignition. Direct sunlight. Heat sources Exposure controls Personal protective equipment Hand protection Eye protection Respiratory protection Other information : Avoid all unnecessary exposure. : Wear protective gloves. : Chemical goggles or safety glasses. : Wear appropriate mask. : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Yellow liquid. Colour : Colourless. Odour : characteristic. Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point : 152 C Flash point : 38 C Auto-ignition temperature Decomposition temperature Flammability (solid, gas) : Flammable liquid and vapour Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Flammable liquid and vapour. May form flammable/explosive vapour-air mixture Possibility of hazardous reactions Not established. 28/10/2014 EN (English) 3/6

4 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat. Sparks Incompatible materials Strong acids. Strong bases Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. May release flammable gases. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity : Harmful if swallowed. Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Potential Adverse human health effects and symptoms :. SECTION 12: Ecological information Toxicity Persistence and degradability Anti-Sulphate Solution Persistence and degradability Bioaccumulative potential Anti-Sulphate Solution Bioaccumulative potential Not established. Not established Mobility in soil Results of PBT and vpvb assessment Other adverse effects : Avoid release to the environment SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations Additional information Ecology - waste materials : Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to... : Handle empty containers with care because residual vapours are flammable. : Avoid release to the environment. 28/10/2014 EN (English) 4/6

5 SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number No dangerous good in sense of transport regulations UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport hazard class(es) ADR Transport hazard class(es) (ADR) IMDG Transport hazard class(es) (IMDG) IATA Transport hazard class(es) (IATA) ADN Transport hazard class(es) (ADN) RID Transport hazard class(es) (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information supplementary information available Special precautions for user Overland transport Transport by sea Air transport Inland waterway transport Not subjected to ADN Rail transport Carriage prohibited (RID) Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations No REACH Annex XVII restrictions Contains no REACH candidate substance 28/10/2014 EN (English) 5/6

6 National regulations Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information Data sources Other information : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixturejs, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. ne. Full text of R-, H- and EUH-phrases: Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 H302 Harmful if swallowed R10 Flammable SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 28/10/2014 EN (English) 6/6