Prepared according to the Hazard Communication Standard (CFR ) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

Transcription

1 Date of issue: 04/21/2017 Revision date: 06/08/2017 Version: 2.0 SECTION 1: IDENTIFICATION 1.1. IDENTIFICATION Product form : Mixtures Product name : 1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED AGAINST Recommended use : Non-Destructive Testing DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET Supplier Magnaflux 155 Harlem Ave. Glenview, IL USA T Distributor 1.4. EMERGENCY TELEPHONE NUMBER Emergency number : CHEMTREC SECTION 2: HAZARD IDENTIFICATION 2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE The hazards given in this SDS apply to the product at full concentration. By diluting the product, the hazards will be reduced. It is up to the employer/user to determine the proper personal protection equipment and safety precautions when using diluted product. GHS classification Skin Corr. 1C Eye Dam. 1 Acute Tox. 4 (Inhalation:vapour) (H)HNOC LABEL ELEMENTS GHS labelling Hazard pictograms (GHS) : Signal word (GHS) Hazard statements (GHS) Precautionary statements (GHS) : Danger GHS05 GHS07 : Causes severe skin burns and eye damage. Harmful if inhaled. Causes severe damage to the respiratory tract. : Do not breathe dust/fume/gas/mist/vapours/spray. Wash hands, forearms and face thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. If swallowed: rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. Store locked up. Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation OTHER HAZARDS 2.4. UNKNOWN ACUTE TOXICITY 24.73% of the mixture consists of ingredient(s) of unknown acute toxicity (Inhalation (Vapours)) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. SUBSTANCES 06/08/2017 EN (English) Page 1

2 3.2. MIXTURES Name Product identifier % Sodium xylenesulfonate (CAS-No.) Potassium silicate (CAS-No.) Nonanoic acid (CAS-No.) Potassium hydroxide (CAS-No.) Sodium hydroxide (CAS-No.) SECTION 4: FIRST AID MEASURES 4.1. DESCRIPTION OF FIRST AID MEASURES First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion 4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED Symptoms/effects after inhalation Symptoms/effects after skin contact Symptoms/effects after eye contact Symptoms/effects after ingestion : IF INHALED: remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. Immediately call a POISON CENTER or doctor. : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. : IF SWALLOWED: rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Immediately call a POISON CENTER or doctor. : Harmful if inhaled. Causes severe damage to the respiratory tract. : Causes severe skin burns. Symptoms may include redness, pain, blisters. : Causes serious eye damage. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. May cause burns. : May be harmful if swallowed. May cause burns or irritation of the linings of the mouth, throat, and gastrointestinal tract INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED Symptoms may be delayed. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). SECTION 5: FIRE FIGHTING MEASURES 5.1. EXTINGUISHING MEDIA Suitable extinguishing media Unsuitable extinguishing media 5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE Fire hazard Reactivity : Dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2). : Do not use a solid water stream as it may scatter and spread fire. : Products of combustion may include, and are not limited to: oxides of carbon. : No dangerous reactions known under normal conditions of use ADVICE FOR FIREFIGHTERS Protection during firefighting : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA). SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES General measures FOR NON-EMERGENCY PERSONNEL FOR EMERGENCY RESPONDERS 6.2. ENVIRONMENTAL PRECAUTIONS Prevent entry to sewers and public waters METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP For containment : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Do not get in eyes, on skin, or on clothing. Spilled material may present a slipping hazard. : Absorb and/or contain spill with inert material (sand, vermiculite or other appropriate material), then place in suitable container. Do not flush into surface water or sewer system. Wear recommended personal protective equipment. 06/08/2017 EN (English) 2/7

3 Methods for cleaning up : Sweep or shovel spills into appropriate container for disposal. Provide ventilation REFERENCE TO OTHER SECTIONS For further information refer to section 8: "Exposure controls/personal protection" SECTION 7: HANDLING AND STORAGE 7.1. PRECAUTIONS FOR SAFE HANDLING Precautions for safe handling Hygiene measures 7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES Storage conditions SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. CONTROL PARAMETERS Sodium xylenesulfonate ( ) : Do not get in eyes, on skin, or on clothing. Do not breathe vapours, spray, mist, gas, fume, dust. Do not swallow. When using do not eat, drink or smoke. Use only outdoors or in a wellventilated area. Handle and open container with care. : Wash contaminated clothing before reuse. Always wash hands after handling the product. : Keep out of the reach of children. Keep container tightly closed. Store in a well-ventilated place. Store locked up. ACGIH ACGIH Ceiling (mg/m³) 2 mg/m³ NIOSH NIOSH REL (ceiling) (mg/m³) 2 mg/m³ ACGIH ACGIH Ceiling (mg/m³) 2 mg/m³ OSHA OSHA PEL (TWA) (mg/m³) 2 mg/m³ IDLH US IDLH (mg/m³) 10 mg/m³ NIOSH NIOSH REL (ceiling) (mg/m³) 2 mg/m³ 8.2. EXPOSURE CONTROLS Appropriate engineering controls Hand protection Eye protection Skin and body protection Respiratory protection Environmental exposure controls : Ensure good ventilation of the work station. : Wear suitable gloves resistant to chemical penetration. : Wear approved eye protection (properly fitted dust- or splash-proof chemical safety goggles) and face protection (face shield). : Wear suitable protective clothing. : In case of insufficient ventilation, wear suitable respiratory equipment. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. : Avoid release to the environment. : Handle in accordance with good industrial hygiene and safety procedures. Do not eat, drink or smoke when using this product. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES Physical state : Liquid Appearance : Clear to hazy Colour : Light straw Odour Odour threshold ph : /08/2017 EN (English) 3/7

4 Melting point Freezing point Boiling point : ~ 100 C (~212 F) Flash point Relative evaporation rate (butylacetate=1) Flammability (solid, gas) : Not flammable. Vapour pressure Relative vapour density at 20 C Relative density : Solubility Partition coefficient n-octanol/water Auto-ignition temperature Decomposition temperature Viscosity, kinematic Viscosity, dynamic Explosive limits Explosive properties Oxidising properties 9.2. OTHER INFORMATION SECTION 10: STABILITY AND REACTIVITY REACTIVITY No dangerous reactions known under normal conditions of use CHEMICAL STABILITY Stable under normal conditions POSSIBILITY OF HAZARDOUS REACTIONS No dangerous reactions known under normal conditions of use CONDITIONS TO AVOID Heat. Incompatible materials INCOMPATIBLE MATERIALS Strong oxidizing agents HAZARDOUS DECOMPOSITION PRODUCTS May include, and are not limited to: oxides of carbon. SECTION 11: TOXICOLOGICAL INFORMATION INFORMATION ON TOXICOLOGICAL EFFECTS Acute toxicity (oral) Acute toxicity (dermal) Acute toxicity (inhalation) : Inhalation:vapour: Harmful if inhaled. ATE CA (vapours) Unknown acute toxicity (GHS-CA)Unknown acute toxicity (GHS UN) Sodium xylenesulfonate ( ) mg/l/4h 24.73% of the mixture consists of ingredient(s) of unknown acute toxicity (Inhalation (Vapours)) 1000 mg/kg 5700 mg/kg > 2 g/kg 06/08/2017 EN (English) 4/7

5 LC50 inhalation rat LD50 dermal rabbit Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT-single exposure STOT-repeated exposure Aspiration hazard Symptoms/effects after inhalation Symptoms/effects after skin contact Symptoms/effects after eye contact Symptoms/effects after ingestion mg/l/4h 284 mg/kg 1350 mg/kg : Causes severe skin burns. ph: : Causes serious eye damage. ph: : Harmful if inhaled. Causes severe damage to the respiratory tract. : Causes severe skin burns. Symptoms may include redness, pain, blisters. : Causes serious eye damage. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. May cause burns. : May be harmful if swallowed. May cause burns or irritation of the linings of the mouth, throat, and gastrointestinal tract. : Likely routes of exposure: ingestion, inhalation, skin and eye. SECTION 12: ECOLOGICAL INFORMATION TOXICITY Ecology - general : May cause long-term adverse effects in the aquatic environment. LC50 fish 1 LC50 fish 2 LC50 fish 1 LC50 fish 2 LC50 fish mg/l (Exposure time: 96 h - Species: Lepomis macrochirus) 3185 mg/l (Exposure time: 96 h - Species: Brachydanio rerio [semi-static]) mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through]) mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [static]) 45.4 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [static]) PERSISTENCE AND DEGRADABILITY Persistence and degradability Not established BIOACCUMULATIVE POTENTIAL Bioaccumulative potential BCF fish 1 Not established. (no bioaccumulation expected) Partition coefficient n-octanol/water MOBILITY IN SOIL 06/08/2017 EN (English) 5/7

6 12.5. OTHER ADVERSE EFFECTS Effect on the global warming : No known effects from this product. : No other effects known. SECTION 13: DISPOSAL CONSIDERATIONS WASTE TREATMENT METHODS Product/Packaging disposal recommendations SECTION 14: TRANSPORT INFORMATION In accordance with DOT/TDG/IATA/IMDG DOT Transportation of Dangerous Goods IATA IMDG : This material must be disposed of in accordance with all local, state, provincial, and federal regulations. The generation of waste should be avoided or minimized wherever possible. : UN1760 Corrosive liquids, n.o.s., (Nonanoic acid, Potassium hydroxide), 8, III : UN1760 Corrosive liquids, n.o.s., (Nonanoic acid, Potassium hydroxide), 8, III : Prohibited SECTION 15: REGULATORY INFORMATION FEDERAL REGULATIONS : UN1760 Corrosive liquids, n.o.s., (Nonanoic acid, Potassium hydroxide), 8, III All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory. All components of this product are listed, or excluded from listing, on the Canadian DSL (Domestic Substances List) and NDSL (Non-Domestic Substances List) inventories. CERCLA RQ CERCLA RQ 1000 lb 1000 lb NFPA health hazard : 3 NFPA fire hazard : 0 NFPA reactivity : INTERNATIONAL REGULATIONS US STATE REGULATIONS California Proposition 65 - This product contains, or may contain, trace quantities of a substance(s) known to the state of California to cause cancer, developmental and/or reproductive harm U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List U.S. - Pennsylvania - RTK (Right to Know) List 06/08/2017 EN (English) 6/7

7 U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List U.S. - Pennsylvania - RTK (Right to Know) List SECTION 16: OTHER INFORMATION Revision date : 06/08/2017 Prepared by : None. : Nexreg Compliance Inc. Safety Data Sheet SDS HazCom WHMIS 2015 (Nexreg_MAGNAFLUX) Disclaimer: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user s responsibility to satisfy oneself as to the suitability and completeness of this information for the user s own particular use. 06/08/2017 EN (English) 7/7