Safety Data Sheet Page 1 of 7 LOCTITE AA 3038 PART A MSDS-No. : V000.0 Date of issue:

Transcription

1 Safety Data Sheet Page 1 of 7 LOCTITE AA 3038 PART A MSDS-No. : V000.0 Date of issue: Section 1. Identification of the substance/preparation and of the company/undertaking Product name: Intended use: LOCTITE AA 3038 PART A Acrylics Supplier: Henkel Australia Pty Ltd Canterbury Road Kilsyth, Victoria, 3137 Australia Phone: +61 (3) Emergency information: 24 HOUR EMERGENCY CONTACT NUMBER: Classification of the substance or mixture Hazardous according to the criteria of Safe Work Australia. GHS Classification: Hazard Class Hazard Category Skin irritation Category 2 Serious eye damage/eye irritation Category 1 Toxic to reproduction Category 1B Skin sensitizer Category 1 Hazard pictogram: Section 2. Hazards identification Signal word: Danger

2 Page 2 of 7 Hazard statement(s): Precautionary Statement(s): Prevention: Response: Storage: Disposal: H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H360 May damage fertility or the unborn child. P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P261 Avoid breathing mist/vapours. P264 Wash hands thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves/protective clothing/eye protection/face protection. P302+P352 IF ON SKIN: Wash with plenty of water. P305+P351+P338+P315 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to remove. Continue rinsing. Get immediate medical advice/attention. P308+P313 IF exposed or concerned: Get medical advice/attention. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P362 Take off contaminated clothing. P363 Wash contaminated clothing before reuse. P405 Store locked up. P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations. Classification of material T - Toxic Risk phrases: R38 Irritating to skin. R41 Risk of serious damage to eyes. R43 May cause sensitisation by skin contact. R60 May impair fertility. R61 May cause harm to the unborn child. Safety phrases: S7/8 Keep container tightly closed and dry. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28 After contact with skin, wash immediately with plenty of water. S46 If swallowed, seek medical advice immediately and show this container or label. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. Dangerous Goods information: Not classified as Dangerous Goods according to the criteria of the Australian Code for the Transport of Dangerous Goods by Road and Rail (ADG Code). Signal word: HAZARDOUS Section 3. Composition / information on ingredients General chemical description: Type of preparation: Mixture Part A of two part adhesive

3 Page 3 of 7 Identity of ingredients: Chemical ingredients Proportion % Borate(1-), hydrotris(1-methylpropyl)-, lithium, (T < 5 % 4)- non hazardous ingredients~ % Section 4. First aid measures Ingestion: Skin: Eyes: Inhalation: First Aid facilities: Most important symptoms caused by exposure: Medical attention and special treatment: Do not induce vomiting. Have victim rinse mouth thoroughly with water. Seek medical attention immediately. Immediately flush skin with plenty of water (using soap, if available). Seek medical advice. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get immediate medical attention. Move to fresh air. Keep warm and in a quiet place. If adverse health effects develop seek medical attention. Eye wash and safety shower Normal washroom facilities Possible risk of irreversible effects. Treat symptomatically. Section 5. Fire fighting measures Suitable extinguishing media: Improper extinguishing media: Decomposition products in case of fire:: Special protective equipment for fire-fighters: Carbon dioxide, foam, powder Water spray jet Thermal decomposition can lead to release of irritating gases and vapors. Carbon monoxide. Carbon dioxide. Oxides of nitrogen. Wear protective equipment. Fire fighters should wear positive pressure self-contained breathing apparatus (SCBA). Section 6. Accidental release measures Personal precautions: Environmental precautions: Clean-up methods: Avoid skin and eye contact. Ensure adequate ventilation. Remove sources of ignition. See advice in section 8 Do not let product enter drains. Wipe up using absorbent material. Store in a partly filled, closed container until disposal. Dispose of contaminated material as waste according to Section 13.

4 Page 4 of 7 Section 7. Handling and storage Precautions for safe handling: Conditions for safe storage: Avoid skin and eye contact. Avoid open flames and sources of ignition. Do not inhale vapors and fumes. Store in sealed original container. Store in a cool, dry place. Ensure that storage and workrooms are adequately ventilated. Keep away from heat and direct sunlight. Section 8. controls / personal protection National exposure standards: None Engineering controls: Eye protection: Skin protection: Ensure adequate ventilation. Tightly fitting safety goggles Use of protective coveralls and long sleeves is recommended. The use of chemical resistant gloves such as Nitrile is recommended. Please note that in practice the working life of chemical resistant gloves may be considerably reduced as a result of many influencing factors (e.g. temperature). Suitable risk assessment should be carried out by the end user. If signs of wear and tear are noticed then the gloves should be replaced. Respiratory protection: If inhalation risk exists, wear a respirator or air supplied mask complying with the requirements of AS/NZS 1715 and AS/NZS Appearance: yellowish gel-like Odor: mild ph: Not applicable Specific gravity: 1.17 Flash point: > 93 C (> F) (Seta closed cup) Density: 1.17 g/cm3 Viscosity (dynamic): 1,500-15,000 mpa.s (Cone and plate; Instrument: Physica MCR300; 25 C (77 F); speed of rotation: 20 min-1; Method: ;; LCT STM 740; cone & plate viscosity) VOC content: < 3 % (2004/42/EC) Section 9. Physical and chemical properties

5 Page 5 of 7 Section 10. Stability and reactivity Stability: Conditions to avoid: Incompatible materials: Stable under normal conditions of temperature and pressure. Danger of decomposition if exposed to heat. Keep away from open flames, hot surfaces and sources of ignition. Store away from incompatible materials. UV light. Strong oxidizing agents. Hazardous decomposition products: Thermal decomposition can lead to release of irritating gases and vapors. Carbon monoxide. Carbon dioxide. Oxides of nitrogen. Section 11. Toxicological information Health Effects: Ingestion: Skin: Eyes: Inhalation: Toxicity for reproduction: Ingestion can cause gastrointestinal irritation, nausea, vomiting and diarrhea. Irritating to skin. Symptoms may include redness, edema, drying, defatting and cracking of the skin. May cause skin sensitization. Causes serious eye damage. Contact with the eyes may cause moderate to severe eye injury. Eye contact may result in corneal injury. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. Vapors may cause headaches, nausea, dizziness and respiratory tract irritation. Toxic to reproduction, category 1B, May damage fertility or the unborn child. Acute toxicity: Value type Value Route of application Species Method LD50 3,850 mg/kg oral rat OECD Guideline 401 (Acute Oral Toxicity) Skin corrosion/irritation: Result Species Method slightly irritating rabbit OECD Guideline 404 (Acute Dermal Irritation / Corrosion) Serious eye damage/irritation: Result Species Method not irritating rabbit OECD Guideline 405 (Acute Eye Irritation / Corrosion) Section 12. Ecological information

6 Page 6 of 7 General ecological information: Do not empty into drains / surface water / ground water., Cured Loctite products are typical polymers and do not pose any immediate environmental hazards. Toxicity: Borate(1-), hydrotris(1- methylpropyl)-, lithium, (T-4) Borate(1-), hydrotris(1- methylpropyl)-, lithium, (T-4) Value type Value Acute Toxicity Study Species Method EC50 7,467 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) NOEC < 625 mg/l Algae 72 h Pseudokirchnerella subcapitata OECD Guideline 201 (Alga, Growth Inhibition Test) EC50 8,996 mg/l Algae 72 h Pseudokirchnerella subcapitata OECD Guideline 201 (Alga, Growth Inhibition Test) LC50 41 mg/l Fish 96 h Ptychocheilus oregonensis OECD Guideline 203 (Fish, Acute Toxicity Test) EC mg/l Daphnia 48 h Ceriodaphnia sp. OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) Persistence and degradability: Borate(1-), hydrotris(1- methylpropyl)-, lithium, (T-4) Result Route of application Degradability Method aerobic < 20 % OECD 301 A - F Not specified no data 0-60 % OECD 301 A - F Bioaccumulative potential / Mobility in soil: LogKow Bioconcentration factor (BCF) Species Temperature Method C OECD Guideline 107 (Partition Coefficient (noctanol / water), Shake Flask Method) Section 13. Disposal considerations Waste disposal of product: Disposal for uncleaned package: Dispose of in accordance with local and national regulations. After use, tubes, cartons and bottles containing residual product should be disposed of as chemically contaminated waste in an authorised legal land fill site or incinerated. Disposal must be made according to official regulations. Section 14. Transport information

7 Page 7 of 7 Road and Rail Transport: Dangerous Goods information: Not classified as Dangerous Goods according to the criteria of the Australian Code for the Transport of Dangerous Goods by Road and Rail (ADG Code). General information: Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR. Section 15. Regulatory information SUSMP Poisons Schedule None Section 16. Other information Abbreviations/acronyms: ADGC - Australian Dangerous Goods Code IMDG: International Mari Dangerous Goods code IATA-DGR: International Air Transport Association Dangerous Goods Regulations Reason for issue: Reviewed SDS. Reissued with new date. involved chapters: 1-16 Date of previous issue: Disclaimer: The percentage weight (% w/w) of ingredients is not to be taken as a specification guaranteed by Henkel Australia Pty. Limited, but only as an approximate guide to the content of hazardous ingredients in the material. The information contained herein does not constitute a guarantee by Henkel Australia Pty. Limited concerning the properties of the material. The information contained in the Safety Data Sheet is offered in good faith and has been developed from what is believed to be accurate and reliable sources. The information is offered without warranty, representation, inducement or licence and Henkel Australia Pty. Limited assumes no legal responsibility for reliance upon same. Henkel Australia Pty. Limited disclaims any liability for loss, injury or damage incurred in connection with the use of the material or its associated Safety Data Sheet. This information is not to be construed as a representation that the material is suitable for any particular purpose or use except those conditions and warranties implied by either Commonwealth or State statutes. Customers are encouraged to make their own enquiries as to the material s characteristics and, where appropriate, to conduct their own tests in the specific context of the material s intended use.