MATERIAL SAFETY DATA SHEET

Transcription

1 MATERIAL SAFETY DATA SHEET Section 1 Identification devan Sealants, Inc. Revision Date: 6/25/ Prescott Avenue MSDS ID: Pumpable PO Box St. Louis, Missouri, USA Phone: (314) Fax: (314) hour Emergency Contact: ChemTel (800) Product Number: Description: Pumpable Butyl Sealant - White Section 2 Hazard Identification General Description: Physical Form: Color: Odor: Pumpable butyl polymer based sealant Viscous, tacky liquid White Hydrocarbon when wet, none when dry HMIS: Health: 1 Flammability: 2 Physical Hazard: 0 NFPA: Health: 1 Flammability: 2 Instability: 0 Acute Health Effects: Eye: Direct contact may cause mechanical abrasion or mild irritation. Skin: May cause irritation. Repeated exposure may cause skin dryness or cracking. Inhalation: This product contains mineral spirits. Breathing high concentrations of vapor may cause respiratory irritation, headache, nausea or vomiting. Oxygen depravation is possible if working in confined spaces. Ingestion: Ingestion and subsequent aspiration into the lungs may cause lung damage. Long Term Health Effects: Skin: Repeated skin contact may cause sensitization. Inhalation: None. Ingestion: Ingestion and subsequent aspiration into the lungs may cause lung cavity formation and chronic lung dysfunction. Page 1 of 5

2 Signs and Symptoms of Overexposure: Medical Conditions Aggravated by Exposure: If material enters lungs, signs and symptoms may include coughing, choking, wheezing, difficulty in breathing, chest congestion, shortness of breath and/or fever. Defatting dermatitis signs and symptoms may include a burning sensation and/or a dried cracked appearance. Skin irritation signs and symptoms may include a burning sensation, redness, swelling and/or blisters. Pre-existing medical conditions of the skin may be aggravated by exposure to this material. Section 3 Composition / Information on Ingredients CAS Number Component Name Weight % Limestone 30-40% Magnesium silicate 10-20% Petroleum hydrocarbon solvent 10-20% Hydrated amorphous silica 0-5% Severely refined paraffinic oil 0-5% Section 4 First Aid Measures Eye: Skin: Inhalation: Ingestion: Physicians: Flush with water for 15-minutes. Seek medical attention if mechanical irritation occurs. Remove from skin and wash with soap and water. Difficult to remove material may require the use of mineral spirits to remove residue. Get medical attention if irritation develops. If affected, remove to fresh air. Give oxygen as necessary. Seek medical attention if conditions persist. Do not induce vomiting. If vomiting occurs spontaneously, keep head below hips to prevent aspiration. Get medical attention immediately. Potential for chemical pneumonitis. Treat according to the patient s condition and specifics of exposure. Section 5 Fire Fighting Measures Flash Point: >142 F Auto ignition Temperature: F Flammability Limits in Air: 0.7 6% by volume Extinguishing Media: For small fires use carbon dioxide (CO 2 ), dry chemical or water spray. For large scale fires, use dry chemical, foam or water spray. Fire Fighting Measures: Self-contained breathing apparatus and protective clothing should be worn in fighting large fires. Determine the need to evacuate or isolate the area according to your local emergency plan. Use water spray to keep exposed containers cool. Unusual Fire Hazards: None. Hazardous Decomposition: Thermal breakdown of the product during fire or very high heat conditions may evolve the following: carbon monoxide, carbon dioxide and isobutene. Page 2 of 5

3 Section 6 Accidental Release Measures Containment / Clean-up: Dike with absorbent material. Wipe or scrape up and contain for salvage or disposal in accordance with Federal, State and Local laws. Section 7 Handling and Storage Handling: Storage: Extinguish any open flames. Do not smoke. Remove any ignition sources. Avoid sparks. Avoid contact with skin, eyes and clothing. Wash thoroughly after handling. Normal warehouse conditions are acceptable. Keep away from heat conditions in excess of 120 F. Section 8 Exposure Controls / Personal Protection Exposure Guidelines: CAS Number Component Name Exposure Limits Limestone ACGIH: 10 mg/m³ total dust OSHA: 15 mg/m³ total dust OSHA: 5 mg/m³ respirable dust Magnesium silicate OSHA PEL: 2 mg/m³ Petroleum hydrocarbon solvent OSHA PEL: Not established ACGIH: Not established Hydrated amorphous silica ACGIH: 10 mg/m³ total dust ACGIH: 3 mg/m³ respirable dust OSHA: 6 mg/m³ total dust Severely refined paraffinic oil ACGIH: 5 mg/m³ mist OSHA PEL: 5 mg/m³ mist Engineering Controls: Local and general ventilation are recommended to keep solvent vapors from building up while the product is drying. Personal Protective Equipment: Eyes: Skin: Suitable Gloves: Inhalation: Suitable Respirator: Safety glasses recommended. Gloves recommended. Wash hands at mealtime and end of shift. Cotton, leather, nitrile rubber, natural rubber or neoprene rubber. None required if local ventilation is adequate. Where concentrations are above recommended limits as determined by air sampling or are unknown, appropriate respiratory protection should be worn. Follow OSHA respirator regulations (29 CFR ) and use NIOSH/MSHA approved respirators. Page 3 of 5

4 Section 9 Physical and Chemical Properties Appearance: White, viscous liquid Form: Viscous, tacky liquid Odor: Hydrocarbon when wet, none when dry Specific gravity: 1.36 g/cm 3 Viscosity: ~3 x 10 6 cps Vapor 20 C: < 5-mm Hg Solubility in water: Not soluble ph: Not applicable Volatile content: <16% by weight Section 10 Stability and Reactivity Chemical Stability: Hazardous Polymerization: Conditions to Avoid: Materials to Avoid: Stable under normal storage and conditions of use. Hazardous polymerization will not occur. Avoid heat, sparks, open flames and other ignition sources. Avoid contact with strong oxidizers. Section 11 Toxicological Information Potential Health Effects (Petroleum hydrocarbon solvent, ): Acute dermal, LD50 Rabbit: >2000 mg/kg Acute inhalation, LC50 Rat: >5.2 mg/l, 4-hours Acute oral, LD50 Rat: >5000 mg/kg Section 12 Ecological Information Environmental Fate and Distribution: Environmental Effects: Fate and Effects in Waste Water Treatment Plants: Complete information is not yet available. An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Complete information is not yet available. Section 13 Disposal Considerations RCRA Hazard Class (40 CFR 261) Is the material, as received, classified as a hazardous waste? No. State or local laws may impose additional regulatory requirements regarding disposal. Page 4 of 5

5 Section 14 Transport Information DOT Road Shipment Information (49 CFR ): Ocean Shipment (IMDG): Air shipment (IATA): Not subject to DOT regulations. Not subject to IMDG code. Not subject to IATA regulations. Section 15 Regulatory Information Contents of this MSDS comply with OSHA Hazard Communication Standard 29 CFR TSCA Status: All chemical substances in this product are either listed or exempt from listing on the TSCA Inventory. EPA SARA Title III Chemical Listings: Section 302 Extremely Hazardous Substances: None Section 304 CERCLA Hazardous Substances: None Section 311 Hazardous Chemical: No Section 312 Hazard Class: Acute: No Chronic: No Fire: No Pressure: No Reactive: No Section 313 Toxic Chemicals: None present or none present in regulated quantities. Section 16 Other Information Prepared by: devan Sealants, Inc. Date: June 25, 2012 These data are offered in good faith as typical values and not as product specifications. No warranty, either expressed or implied is made. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable. However, each user should review these recommendations in the specific context of the intended use and determine whether they are appropriate. It is the responsibility of the user to comply with all federal, state and local laws and regulations. Page 5 of 5