A07730 TM BABY POWDER 30 DAY 12n5.3 Version 2.0 Revision Date 03/03/2017 Print Date 02/10/2018

Transcription

1 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Material name : Material number : Manufacturer or supplier's details Company : Zep Inc. Address : 1310 Seaboard Industrial Blvd., NW Atlanta, GA Telephone : Emergency telephone numbers For SDS Information : Compliance Services For a Medical Emergency : Toll Free - All Calls Recorded For a Transportation Emergency : CHEMTREC: All Calls Recorded. In the District of Columbia Recommended use of the chemical and restrictions on use Recommended use : Air Care SECTION 2. HAZARDS IDENTIFICATION Emergency Overview Appearance Colour Odour Aerosol containing a liquefied gas colourless characteristic GHS Classification Flammable aerosols : Category 1 Gases under pressure : Liquefied gas Eye irritation : Category 2A Skin sensitisation : Category 1 Specific target organ toxicity - : Category 3 (Central nervous system) single exposure GHS label elements Hazard pictograms : Signal word Hazard statements : Danger : H222 Extremely flammable aerosol. H280 Contains gas under pressure; may explode if heated. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness. 1 / 13

2 Precautionary statements : Prevention: P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P211 Do not spray on an open flame or other ignition source. P251 Pressurized container: Do not pierce or burn, even after use. P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P264 Wash skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves/ eye protection/ face protection. Response: P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention. P337 + P313 If eye irritation persists: Get medical advice/ attention. P363 Wash contaminated clothing before reuse. Storage: P403 Store in a well-ventilated place. P410 + P412 Protect from sunlight. Do not expose to temperatures exceeding 50 C/ 122 F. Disposal: Dispose of contents/container in accordance with local regulation. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components Chemical name CAS-No. Concentration [%] acetone >= 70 - < 90 propane >= 20 - < 30 citronellol >= < 1 geraniol >= < 1 2-benzylideneheptanal >= < 1 The exact percentages of disclosed substances are withheld as trade secrets. SECTION 4. FIRST AID MEASURES General advice If inhaled : Move out of dangerous area. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. : Consult a physician after significant exposure. If unconscious place in recovery position and seek medical advice. 2 / 13

3 In case of skin contact In case of eye contact If swallowed Most important symptoms and effects, both acute and delayed Notes to physician : If skin irritation persists, call a physician. Wash off immediately with plenty of water for at least 15 minutes. If on clothes, remove clothes. : Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. Rinse immediately with plenty of water for at least 15 minutes. : Keep respiratory tract clear. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. DO NOT induce vomiting unless directed to do so by a physician or poison control center. Take victim immediately to hospital. : Effects are immediate and delayed. Symptoms may include irritation, redness, pain, and rash. Symptoms may include central nervous system depression, resulting in headache, nausea and/or dizziness. Effects are dependent on exposure (dose, concentration, contact time). May cause drowsiness or dizziness. Causes serious eye irritation. May cause an allergic skin reaction. Review section 2 of SDS to see all potential hazards. : Treat symptomatically. Symptoms may be delayed. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media Unsuitable extinguishing media Hazardous combustion products Specific extinguishing methods Further information Special protective equipment for firefighters : Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical Water spray jet : High volume water jet : Carbon dioxide (CO2) Carbon monoxide Smoke : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. : Standard procedure for chemical fires. : Wear self-contained breathing apparatus for firefighting if necessary. 3 / 13

4 SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up : Use personal protective equipment. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Sweep up or vacuum up spillage and collect in suitable container for disposal. SECTION 7. HANDLING AND STORAGE Advice on safe handling Conditions for safe storage Materials to avoid : Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Do not breathe vapours or spray mist. Take precautionary measures against static discharges. Provide sufficient air exchange and/or exhaust in work rooms. Dispose of rinse water in accordance with local and national regulations. Always replace cap after use. : BEWARE: Aerosol is pressurized. Keep away from direct sun exposure and temperatures over 50 C. Do not open by force or throw into fire even after use. Do not spray on flames or red-hot objects. No smoking. Observe label precautions. Keep in a dry, cool and well-ventilated place. Electrical installations / working materials must comply with the technological safety standards. : Store and keep away from, oxidizing agents and acids. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis 4 / 13

5 acetone TWA 250 ppm ACGIH STEL 500 ppm ACGIH TWA 250 ppm NIOSH REL 590 mg/m3 TWA 1,000 ppm OSHA Z-1 2,400 mg/m3 TWA 750 ppm OSHA P0 1,800 mg/m3 STEL 1,000 ppm OSHA P0 2,400 mg/m3 STEL 750 ppm CAL PEL 1,780 mg/m3 C 3,000 ppm CAL PEL PEL 500 ppm CAL PEL 1,200 mg/m3 propane TWA 1,000 ppm ACGIH TWA 1,000 ppm NIOSH REL 1,800 mg/m3 TWA 1,000 ppm OSHA Z-1 1,800 mg/m3 TWA 1,000 ppm OSHA P0 1,800 mg/m3 PEL 1,000 ppm 1,800 mg/m3 CAL PEL Biological occupational exposure limits Component CAS-No. Control parameters Biological specimen Sampling time 2-PROPANONE Acetone Urine End of shift (As soon as possible after exposure ceases) Permissible Basis concentration 25 mg/l ACGIH BEI Engineering measures : effective ventilation in all processing areas Personal protective equipment Respiratory protection : Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines. Hand protection Material Remarks Eye protection Skin and body protection : Gloves : The suitability for a specific workplace should be discussed with the producers of the protective gloves. : Ensure that eyewash stations and safety showers are close to the workstation location. Safety glasses : Impervious clothing Choose body protection according to the amount and concentration of the dangerous substance at the work place. 5 / 13

6 Hygiene measures : When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : Aerosol containing a liquefied gas Colour : colourless Odour : characteristic Odour Threshold ph Melting point/freezing point Boiling point Flash point : Not applicable Evaporation rate Flammability (solid, gas) : Extremely flammable aerosol. Upper explosion limit Lower explosion limit Vapour pressure Relative vapour density Density Solubility(ies) Water solubility Partition coefficient: n- octanol/water Auto-ignition temperature Thermal decomposition Heat of combustion : 5,515.8 hpa : partly soluble : not determined : kj/g SECTION 10. STABILITY AND REACTIVITY Reactivity Chemical stability Possibility of hazardous reactions : Stable : Stable under normal conditions. : No decomposition if stored and applied as directed. Vapours may form explosive mixture with air. 6 / 13

7 Conditions to avoid Incompatible materials Hazardous decomposition products : Heat, flames and sparks. Extremes of temperature and direct sunlight. : Oxidizing agents Acids : Carbon oxides SECTION 11. TOXICOLOGICAL INFORMATION Potential Health Effects Aggravated Medical Condition Symptoms of Overexposure : None known. : Effects are immediate and delayed. Symptoms may include irritation, redness, pain, and rash. Symptoms may include central nervous system depression, resulting in headache, nausea and/or dizziness. Effects are dependent on exposure (dose, concentration, contact time). Carcinogenicity: IARC ACGIH OSHA NTP Acute toxicity Acute oral toxicity No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. : Acute toxicity estimate : > 5,000 mg/kg Method: Calculation method Acute dermal toxicity : Acute toxicity estimate : > 5,000 mg/kg Method: Calculation method Components: acetone: Acute oral toxicity : LD50 Rat: 5,800 mg/kg 7 / 13

8 Acute inhalation toxicity : LC50 Rat: 132 mg/l Exposure time: 3 h LC50 Rat: 50.1 mg/l Acute dermal toxicity : LD50 Guinea pig: > 7,426 mg/kg LD50 Rabbit: > 7,426 mg/kg propane: Acute inhalation toxicity : LC50 Mouse: 1,237 mg/l Exposure time: 2 h LC50 Rat: 658 mg/l Exposure time: 4 h LC50 Rat: 1,355 mg/l 2-benzylideneheptanal: Acute oral toxicity Acute dermal toxicity : LD50 Oral Rat: 3,730 mg/kg : LD50 Dermal Rabbit: > 2,000 mg/kg Skin corrosion/irritation Remarks: May cause skin irritation in susceptible persons. Serious eye damage/eye irritation Remarks: Irritating to eyes. Respiratory or skin sensitisation Classification: May cause sensitisation by skin contact. Germ cell mutagenicity Carcinogenicity Reproductive toxicity acetone: propane: citronellol: geraniol: 8 / 13

9 2-benzylideneheptanal: STOT - single exposure STOT - repeated exposure Aspiration toxicity Further information Remarks: Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting., Concentrations substantially above the TLV value may cause narcotic effects., Solvents may degrease the skin. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Persistence and degradability Bioaccumulative potential Partition coefficient: n- octanol/water Components: citronellol : Partition coefficient: n- octanol/water geraniol : Partition coefficient: n- octanol/water 2-benzylideneheptanal : Partition coefficient: n- octanol/water Mobility in soil Other adverse effects Regulation : Remarks : Pow: 3.6 : Pow: 2.6 : log Pow: CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances 9 / 13

10 Remarks Additional ecological information This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues Contaminated packaging : Dispose of in accordance with local regulations. : Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum. SECTION 14. TRANSPORT INFORMATION Transportation Regulation: 49 CFR (USA): ORM-D, CONSUMER COMMODITY Transportation Regulation: IMDG (Vessel): UN1950, AEROSOLS, FLAMMABLE, 2.1, - Limited quantity Transportation Regulation: IATA (Cargo Air): UN1950, Aerosols, flammable, 2.1, - Limited quantity Transportation Regulation: IATA (Passenger Air): UN1950, Aerosols, flammable, 2.1, - Limited quantity Transportation Regulation: TDG (Canada): UN1950, AEROSOLS, FLAMMABLE, 2.1, - Limited quantity The product as delivered to the customer conforms to packaging requirements for shipment by road under US Department of Transportation (DOT) regulations. Additional transportation classifications noted above are for reference only, and not a certification or warranty of the suitability of the packaging for shipment under these alternative transport regulations. SECTION 15. REGULATORY INFORMATION TSCA list : No substances are subject to a Significant New Use Rule. No substances are subject to TSCA 12(b) export notification requirements. 10 / 13

11 EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity Components CAS-No. Component RQ Calculated product RQ (lbs) (lbs) acetone * *: Calculated RQ exceeds reasonably attainable upper limit. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : Fire Hazard Sudden Release of Pressure Hazard Acute Health Hazard SARA 302 SARA 313 : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. California Prop 65 This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. The components of this product are reported in the following inventories: TSCA DSL On TSCA Inventory All components of this product are on the Canadian DSL For information on the country notification status for other regions please contact the manufacturer s regulatory group. Inventory Acronym and Validity Area Legend: TSCA (USA), DSL (Canada), NDSL (Canada) SECTION 16. OTHER INFORMATION 11 / 13

12 Health Instability SAFETY DATA SHEET Further information NFPA: Flammability HMIS III: HEALTH FLAMMABILITY 3 4 PHYSICAL HAZARD 2 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic OSHA - GHS Label Information: Hazard pictograms : Signal w ord : Danger: Hazard statements : Extremely flammable aerosol. Contains gas under pressure; may explode if heated. May cause an allergic skin reaction. Causes serious eye irritation. May cause drow siness or dizziness. Precautionary statements : Prevention: Keep aw ay from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. Wash skin thoroughly after handling. Use only outdoors or in a w ell-ventilated area. Contaminated w ork clothing should not be allow ed out of the w orkplace. Wear protective gloves/ eye protection/ face protection. Response: IF ON SKIN: Wash w ith plenty of soap and w ater. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unw ell. IF IN EYES: Rinse cautiously w ith water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation or rash occurs: Get medical advice/ attention. If eye irritation persists: Get medical advice/ attention. Wash contaminated clothing before reuse. Storage: Store in a w ell-ventilated place. Protect from sunlight. Do not expose to temperatures exceeding 50 C/ 122 F. Disposal: Dispose of contents/container in accordance with local regulation. Version: 2.0 Revision Date: 03/03/2017 Print Date: 02/10/2018 We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. Users should make their own investigations to determine the suitability and applicability of the information for their particular purposes. This SDS has been prepared by the Compliance Services organization supporting this manufacturer, supplier or distributor. Zep Inc. markets products under well recognized and established brand names such as Zep, Zep Commercial,Zep Professional, Enforcer, National Chemical, Selig, Mis ty, Next 12 / 13

13 Dimension, Petro, i-chem, TimeMist, TimeWick, MicrobeMax, Country Vet, Konk, Original Bike Spirits, Blue Coral, Black Magic, Rain-X, Niagara National, FC Forward Chemicals,Rexodan, Mykal, and a number of private labeled brands. 13 / 13