Safety Data Sheet 2-methyl Butanol Revision date : 2015/03/10 Page: 1/11

Transcription

1 Revision date : 2015/03/10 Page: 1/11 1. Identification Product identifier used on the label Recommended use of the chemical and restriction on use Recommended use*: industrial chemicals * The Recommended use identified for this product is provided solely to comply with a Federal requirement and is not part of the seller's published specification. The terms of this Safety Data Sheet (SDS) do not create or infer any warranty, express or implied, including by incorporation into or reference in the seller's sales agreement. Details of the supplier of the safety data sheet Company: BASF CORPORATION 100 Park Avenue Florham Park, NJ 07932, USA Telephone: Emergency telephone number CHEMTREC: BASF HOTLINE: HELP (4357) Other means of identification 2. Hazards Identification According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part Classification of the product Flam. Liq. 3 Flammable liquids Acute Tox. 4 (Inhalation - vapour) Acute toxicity Skin Corr./Irrit. 2 Skin corrosion/irritation Eye Dam./Irrit. 2A Serious eye damage/eye irritation STOT SE 3 (irritating to respiratory system) Specific target organ toxicity single exposure Label elements Pictogram:

2 Revision date : 2015/03/10 Page: 2/11 Signal Word: Warning Hazard Statement: H226 H319 H315 H332 H335 Flammable liquid and vapour. Causes serious eye irritation. Causes skin irritation. Harmful if inhaled. May cause respiratory irritation. Precautionary Statements (Prevention): P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves and eye/face protection. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P260 Do not breathe dust/gas/mist/vapours. P243 Take precautionary measures against static discharge. P241 Use explosion-proof electrical/ventilating/lighting/equipment. P264 Wash with plenty of water and soap thoroughly after handling. P242 Use only non-sparking tools. P240 Ground/bond container and receiving equipment. Precautionary Statements (Response): P312 Call a POISON CENTER or doctor/physician if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P303 + P352 IF ON SKIN (or hair): Wash with plenty of soap and water. P332 + P313 If skin irritation occurs: Get medical advice/attention. P337 + P311 If eye irritation persists: Call a POISON CENTER or doctor/physician. P362 + P364 Take off contaminated clothing and wash before reuse. P370 + P378 In case of fire: Use alcohol-resistant foam, carbon dioxide, dry powder or water spray for extinction. Precautionary Statements (Storage): P403 + P235 Store in a well-ventilated place. Keep cool. P233 Keep container tightly closed. P405 Store locked up. Precautionary Statements (Disposal): P501 Dispose of contents/container to hazardous or special waste collection point. Hazards not otherwise classified If applicable information is provided in this section on other hazards which do not result in classification but which may contribute to the overall hazards of the substance or mixture. According to Regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part

3 Revision date : 2015/03/10 Page: 3/11 Emergency overview WARNING: COMBUSTIBLE LIQUID. MAY BE HARMFUL IF SWALLOWED. HARMFUL IF INHALED. CAUSES EYE, SKIN AND RESPIRATORY TRACT IRRITATION. Prolonged or repeated contact may result in dermatitis. INGESTION MAY CAUSE GASTRIC DISTURBANCES. Overexposure may cause CNS depression including headache, dizziness, nausea and loss of consciousness. Avoid contact with the skin, eyes and clothing. Avoid inhalation of mists/vapours. Use with local exhaust ventilation. Wear a NIOSH-certified (or equivalent) organic vapour/particulate respirator. Wear NIOSH-certified chemical goggles. Wear full face shield if splashing hazard exists. Wear chemical resistant protective gloves. Wear protective clothing. Eye wash fountains and safety showers must be easily accessible. Avoid all sources of ignition: heat, sparks, open flame. 3. Composition / Information on Ingredients According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part CAS Number Content (W/W) Chemical name >= < 3.0 % 3-methylbutan-1-ol >= < 30.0 % pentan-1-ol >= <= methylbutan-1-ol % >= < 4.0 % Nonane, 4-methyl- According to Regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part CAS Number Content (W/W) Chemical name % 2-methylbutan-1-ol % pentan-1-ol % Nonane, 4-methyl % 3-methylbutan-1-ol 4. First-Aid Measures Description of first aid measures General advice: Remove contaminated clothing. If inhaled: Remove the affected individual into fresh air and keep the person calm. Assist in breathing if necessary. Immediate medical attention required. If on skin: Wash affected areas thoroughly with soap and water. If irritation develops, seek medical attention.

4 Revision date : 2015/03/10 Page: 4/11 If in eyes: In case of contact with the eyes, rinse immediately for at least 15 minutes with plenty of water. Immediate medical attention required. If swallowed: Rinse mouth and then drink plenty of water. Induce vomiting. Never induce vomiting or give anything by mouth if the victim is unconscious or having convulsions. Immediate medical attention required. Most important symptoms and effects, both acute and delayed Indication of any immediate medical attention and special treatment needed 5. Fire-Fighting Measures Extinguishing media Suitable extinguishing media: water spray, alcohol-resistant foam, dry powder, carbon dioxide Special hazards arising from the substance or mixture Hazards during fire-fighting: No particular hazards known. Advice for fire-fighters Protective equipment for fire-fighting: Firefighters should be equipped with self-contained breathing apparatus and turn-out gear. Further information: Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Breathing protection required. Environmental precautions Substance/product is RCRA hazardous due to its properties. Methods and material for containment and cleaning up Spills should be contained, solidified, and placed in suitable containers for disposal. 7. Handling and Storage Precautions for safe handling Ensure thorough ventilation of stores and work areas. Containers should be opened carefully in well-ventilated areas to avoid static discharge. Ground and/or bond all equipment to prevent electrostatic charges. Avoid all sources of ignition: heat, sparks, open flame.

5 Revision date : 2015/03/10 Page: 5/11 Protection against fire and explosion: Take precautionary measures against static discharges. Sources of ignition should be kept well clear. Vapours are heavier than air and may accumulate in low areas and travel a considerable distance up to the source of ignition. Keep away from sources of ignition - No smoking. Conditions for safe storage, including any incompatibilities Further information on storage conditions: Keep away from sources of ignition - No smoking. Keep container tightly closed and dry; store in a cool place. 8. Exposure Controls/Personal Protection Components with occupational exposure limits 3-methylbutan-1-ol OSHA PEL PEL 100 ppm 360 mg/m3 ; TWA value 100 ppm 360 mg/m3 ; STEL value 125 ppm 450 mg/m3 ; ACGIH TLV TWA value 100 ppm ; STEL value 125 ppm ; Advice on system design: Provide local exhaust ventilation to control vapours/mists. Personal protective equipment Respiratory protection: Wear a NIOSH-certified (or equivalent) organic vapour/particulate respirator. Do not exceed the maximum use concentration for the respirator facepiece/cartridge combination. For emergency or non-routine, high exposure situations, use a NIOSH-certified full facepiece pressure demand selfcontained breathing apparatus (SCBA) or a full facepiece pressure demand supplied-air respirator (SAR) with escape provisions. Observe OSHA regulations for respirator use (29 CFR ). Hand protection: Chemical resistant protective gloves, Consult with glove manufacturer for testing data. Eye protection: Tightly fitting safety goggles (chemical goggles). Body protection: light protective clothing General safety and hygiene measures: No special measures necessary if stored and handled correctly. Wear protective clothing as necessary to prevent contact. Avoid inhalation of vapours/mists. Wash soiled clothing immediately. 9. Physical and Chemical Properties Form: liquid Odour: alcohol-like Colour: colourless ph value: approx. 7 Melting point: < -70 C (other) Literature data. Boiling range: C (DIN 51751)

6 Revision date : 2015/03/10 Page: 6/11 Boiling point: 138 C ( 1, hpa) (other) Information on: 2-methylbutan-1-ol Boiling point: 128 C ( 1, hpa) (measured) Flash point: 42.5 C (DIN 51755, closed cup) Flammability: Flammable. (other) Lower explosion limit: 1.2 %(V) ( 37 C) (air) Upper explosion limit: 10.3 %(V) ( 74.5 C) (air) Autoignition: 340 C (DIN 51794) Vapour pressure: 4.3 mbar ( 20 C) 27.4 mbar ( 50 C) Density: g/cm3 ( 20 C) (DIN 51757) Partitioning coefficient n- octanol/water (log Pow): 1.26 ( 25 C) (other) Viscosity, dynamic: mpa.s ( 19.3 C) Literature data. Solubility in water: approx. 28 g/l ( 20 C) Literature data. 10. Stability and Reactivity Reactivity Corrosion to metals: No corrosive effect on metal. Oxidizing properties: Based on its structural properties the product is not classified as oxidizing. (other) Chemical stability Possibility of hazardous reactions The product is chemically stable. Conditions to avoid Avoid all sources of ignition: heat, sparks, open flame. Incompatible materials strong oxidizing agents, strong acids, strong bases Hazardous decomposition products Decomposition products: carbon monoxide, carbon dioxide 11. Toxicological information Primary routes of exposure Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or skin contact. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of entry for liquefied gases. Acute Toxicity/Effects Acute toxicity Assessment of acute toxicity: Ingestion may cause gastrointestinal disturbances.

7 Revision date : 2015/03/10 Page: 7/11 Of moderate toxicity after short-term inhalation. Of low toxicity after single ingestion. Of low toxicity after short-term skin contact. The product has not been tested. The statement has been derived from the properties of the individual components. Oral Information on: 2-methylbutan-1-ol Type of value: LD50 Species: rat Value: 4,172 mg/kg (BASF-Test) Type of value: LD50 Species: rat Value: approx. 3,645 mg/kg (BASF-Test) Inhalation The product has not been tested. The statement has been derived from the properties of the individual components. Information on: 2-methylbutan-1-ol Type of value: LC0 Species: rat Value: > 12.8 mg/l (other) Exposure time: 7 h The vapour was tested. Type of value: LC0 Species: rat Value: 8.29 mg/l (IRT) Exposure time: 8 h The vapour was tested. No mortality within the stated exposition time as shown in animal studies. The European Union (EU) has classified this substance as 'harmful'. Dermal Information on: 2-methylbutan-1-ol Type of value: LD50 Value: 2,889 mg/kg (other) Type of value: LD50 Value: 2,292 mg/kg (similar to OECD guideline 402) Irritation / corrosion Assessment of irritating effects: Skin contact causes irritation. May cause severe damage to the eyes. Skin Result: Irritant.

8 Revision date : 2015/03/10 Page: 8/11 Method: Draize test The product has not been tested. The statement has been derived from the properties of the individual components. Result: Irritant. Method: BASF-Test Eye Information on: 2-methylbutan-1-ol Result: Irritant. Method: Draize test Result: Irritant. Method: BASF-Test Sensitization Assessment of sensitization: No sensitizing effect. Chronic Toxicity/Effects Genetic toxicity Assessment of mutagenicity: No data available concerning mutagenic effects. The chemical structure does not suggest a specific alert for such an effect. Carcinogenicity Assessment of carcinogenicity: None of the components in this product at concentrations greater than 0.1% are listed by IARC; NTP, OSHA or ACGIH as a carcinogen. Reproductive toxicity Assessment of reproduction toxicity: No reproductive toxic effects reported. Teratogenicity Assessment of teratogenicity: No teratogenic effects reported. Symptoms of Exposure Medical conditions aggravated by overexposure Data available do not indicate that there are medical conditions that are generally recognized as being aggravated by exposure to this substance/product. See MSDS section 11 - Toxicological information. 12. Ecological Information Toxicity Aquatic toxicity Assessment of aquatic toxicity:

9 Revision date : 2015/03/10 Page: 9/11 There is a high probability that the product is not acutely harmful to aquatic organisms. The inhibition of the degradation activity of activated sludge is not anticipated when introduced to biological treatment plants in appropriate low concentrations. Toxicity to fish LC mg/l, Leuciscus idus (DIN Part 15) Nominal concentration. Persistence and degradability Assessment biodegradation and elimination (H2O) Readily biodegradable (according to OECD criteria). Elimination information 84 % BOD of COD (27 d) (OECD 301F; ISO 9408; 92/69/EEC, C.4-D) (aerobic, activated sludge, domestic) Biodegradable. The product has not been tested. The statement has been derived from the properties of the individual components. Bioaccumulative potential Bioaccumulation potential No significant accumulation in organisms is expected as a result of the distribution coefficient of n- octanol/water (log Pow). Additional information Other ecotoxicological advice: Inhibition of degradation activity in activated sludge is not to be anticipated during correct introduction of low concentrations. 13. Disposal considerations Waste disposal of substance: Dispose of in a RCRA-licensed facility. Do not discharge into waterways or sewer systems without proper authorization. Dispose of in accordance with national, state and local regulations. Container disposal: Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned. Empty containers with less than 1 inch of residue may be landfilled at a licensed facility. Recommend crushing, puncturing or other means to prevent unauthorized use of used containers. If containers are not empty, they must be disposed of in a RCRA-licensed facility. Flammable vapors may exist in containers in which residues of this product remain. RCRA: D Transport Information Land transport USDOT Hazard class: 3 Packing group: III ID number: UN 1105 Hazard label: 3

10 Revision date : 2015/03/10 Page: 10/11 Proper shipping name: PENTANOLS Sea transport IMDG Hazard class: 3 Packing group: III ID number: UN 1105 Hazard label: 3 Marine pollutant: NO Proper shipping name: PENTANOLS (contains 2-METHYLBUTAN-1-OL) Air transport IATA/ICAO Hazard class: 3 Packing group: III ID number: UN 1105 Hazard label: 3 Proper shipping name: PENTANOLS (contains 2-METHYLBUTAN-1-OL) 15. Regulatory Information Federal Regulations Registration status: Chemical TSCA, US released / listed EPCRA 311/312 (Hazard categories): Acute; Fire CERCLA RQ CAS Number Chemical name 100 LBS pentan-1-ol State regulations State RTK CAS Number Chemical name MA methylbutan-1-ol MA, NJ, PA pentan-1-ol MA, NJ, PA methylbutan-1-ol NFPA Hazard codes: Health : 2 Fire: 2 Reactivity: 0 Special: HMIS III rating Health: 2 Flammability: 2 Physical hazard: Other Information SDS Prepared by: BASF NA Product Regulations SDS Prepared on: 2015/03/10

11 Revision date : 2015/03/10 Page: 11/11 We support worldwide Responsible Care initiatives. We value the health and safety of our employees, customers, suppliers and neighbors, and the protection of the environment. Our commitment to Responsible Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring the safe and environmentally sound handling of our products, and minimizing the impact of our operations on society and the environment during production, storage, transport, use and disposal of our products. IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY UNDERSTAND AND AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY OUR COMPANY HEREUNDER ARE GIVEN GRATIS AND WE ASSUME NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. END OF DATA SHEET