Safety Data Sheet CRUDE C4 Revision date : 2015/03/08 Page: 1/10

Transcription

1 Revision date : 2015/03/08 Page: 1/10 1. Identification Product identifier used on the label Recommended use of the chemical and restriction on use Recommended use*: for industrial use only * The Recommended use identified for this product is provided solely to comply with a US Federal requirement and is not part of the seller's published specification. The terms of this Safety Data Sheet (SDS) do not create or infer any warranty, express or implied, including by incorporation into or reference in the seller's sales agreement. Details of the supplier of the safety data sheet Company: BASF CORPORATION 100 Park Avenue Florham Park, NJ 07932, USA Telephone: Emergency telephone number CHEMTREC: BASF HOTLINE: HELP (4357) Other means of identification Chemical family: hydrocarbons Synonyms: INALK Vapor Phase - Stream number Hazards Identification According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part Classification of the product Press. Gas Liquef. Gas Gases under pressure Skin Corr./Irrit. 2 Skin corrosion/irritation Repr. 2 (fertility) Reproductive toxicity STOT SE 3 (Vapours may cause Specific target organ toxicity single exposure drowsiness and dizziness.) Aquatic Acute 1 Hazardous to the aquatic environment - acute Aquatic Chronic 1 Hazardous to the aquatic environment - chronic

2 Revision date : 2015/03/08 Page: 2/10 Flam. Gas 1 Flammable gases Label elements Pictogram: Signal Word: Danger Hazard Statement: H280 H220 H315 H336 H361 H400 H410 Contains gas under pressure; may explode if heated. Extremely flammable gas. Causes skin irritation. May cause drowsiness or dizziness. Suspected of damaging fertility. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Precautionary Statements (Prevention): P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P271 Use only outdoors or in a well-ventilated area. P201 Obtain special instructions before use. P260 Do not breathe dust/gas/mist/vapours. P202 Do not handle until all safety precautions have been read and understood. P264 Wash with plenty of water and soap thoroughly after handling. Precautionary Statements (Response): P312 Call a POISON CENTER or doctor/physician if you feel unwell. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely. P303 + P352 IF ON SKIN (or hair): Wash with plenty of soap and water. P391 Collect spillage. P308 + P311 IF exposed or concerned: Call a POISON CENTER or doctor/physician. P381 Eliminate all ignition sources if safe to do so. P332 + P313 If skin irritation occurs: Get medical advice/attention. P362 + P364 Take off contaminated clothing and wash before reuse. Precautionary Statements (Storage): P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P410 + P403 Protect from sunlight. Store in a well-ventilated place. P405 Store locked up. Precautionary Statements (Disposal): P501 Dispose of contents/container to hazardous or special waste collection point. Hazards not otherwise classified

3 Revision date : 2015/03/08 Page: 3/10 If applicable information is provided in this section on other hazards which do not result in classification but which may contribute to the overall hazards of the substance or mixture. According to Regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part Emergency overview WARNING: FLAMMABLE. Harmful in contact with skin. Harmful if swallowed. FLAMMABLE GAS. MAY CAUSE FLASH FIRE OR EXPLOSION. Avoid all sources of ignition: heat, sparks, open flame. Avoid contact with the skin, eyes and clothing. Wear a NIOSH-certified (or equivalent) organic vapour/particulate respirator. Wear NIOSH-certified chemical goggles. Eye wash fountains and safety showers must be easily accessible. Wear chemical resistant protective gloves. Safety showers must be easily accessible. 3. Composition / Information on Ingredients According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part CAS Number Content (W/W) Chemical name >= < 7.0 % Pentane >= < 75.0 % octane >= < 5.0 % 1-Octene >= < 3.0 % Nonane >= < 3.0 % heptane >= < 0.2 % Nonene >= < 0.2 % Heptene >= < 5.0 % Undecane >= < 1.0 % n-hexane According to Regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part CAS Number Content (W/W) Chemical name % methane % 2-methylpropene % but-1-ene % 2-Butene, (Z) % 2-Butene, (E) % Isobutane (min 90%) % n-butane % Pentane % 1-Pentene % n-hexane % 1-Hexene % heptane % Heptene % octane % 1-Octene % Nonane % Nonene % Undecane

4 Revision date : 2015/03/08 Page: 4/10 4. First-Aid Measures Description of first aid measures General advice: Immediately remove contaminated clothing. Obtain medical attention. If inhaled: Keep patient calm, remove to fresh air, seek medical attention. If on skin: Immediately wash thoroughly with soap and water, seek medical attention. If in eyes: Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist. If swallowed: Ingestion is not likely in the available physical form. If ingested, seek medical attention. Most important symptoms and effects, both acute and delayed Indication of any immediate medical attention and special treatment needed 5. Fire-Fighting Measures Extinguishing media Suitable extinguishing media: carbon dioxide, foam, dry powder Special hazards arising from the substance or mixture Advice for fire-fighters Protective equipment for fire-fighting: Wear a self-contained breathing apparatus. Further information: Keep containers cool by spraying with water if exposed to fire. Shut off or stop source of fuel if possible. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Sources of ignition should be kept well clear. Ensure adequate ventilation. Environmental precautions Discharge into the environment must be avoided. Methods and material for containment and cleaning up Suppress gases/vapours/mists with water spray jet.

5 Revision date : 2015/03/08 Page: 5/10 7. Handling and Storage Precautions for safe handling Ensure thorough ventilation of stores and work areas. Protection against fire and explosion: Vapours may form explosive mixture with air. Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy. Conditions for safe storage, including any incompatibilities Suitable materials for containers: Stainless steel (V2), Stainless steel Further information on storage conditions: Store containers in a cool, well-ventilated, fire resistant location. Avoid all sources of ignition: heat, sparks, open flame. 8. Exposure Controls/Personal Protection Components with occupational exposure limits Propane, 2-methyl- ACGIH TLV STEL value 1,000 ppm ; n-butane OSHA PEL TWA value 800 ppm 1,900 mg/m3 ; ACGIH TLV STEL value 1,000 ppm ; but-1-ene ACGIH TLV TWA value 250 ppm ; Pentane OSHA PEL PEL 1,000 ppm 2,950 mg/m3 ; STEL value 750 ppm 2,250 mg/m3 ; TWA value 600 ppm 1,800 mg/m3 ; ACGIH TLV TWA value 600 ppm ; TWA value 1,000 ppm ; n-hexane OSHA PEL PEL 500 ppm 1,800 mg/m3 ; TWA value 50 ppm 180 mg/m3 ; ACGIH TLV TWA value 50 ppm ; Skin Designation ; The substance can be absorbed through the skin. octane OSHA PEL PEL 500 ppm 2,350 mg/m3 ; TWA value 300 ppm 1,450 mg/m3 ; STEL value 375 ppm 1,800 mg/m3 ; ACGIH TLV TWA value 300 ppm ; TWA value 300 ppm ; Nonane OSHA PEL TWA value 200 ppm 1,050 mg/m3 ; ACGIH TLV TWA value 200 ppm ; TWA value 200 ppm ; 2-methylpropene ACGIH TLV TWA value 250 ppm ; heptane OSHA PEL PEL 500 ppm 2,000 mg/m3 ; TWA value 400 ppm 1,600 mg/m3 ; STEL value 500 ppm 2,000 mg/m3 ;

6 Revision date : 2015/03/08 Page: 6/10 ACGIH TLV TWA value 400 ppm ; STEL value 500 ppm ; STEL value 500 ppm ; TWA value 400 ppm ; 2-Butene, (Z)- 2-Butene, (E)- ACGIH TLV TWA value 250 ppm ; ACGIH TLV TWA value 250 ppm ; Personal protective equipment Respiratory protection: Self-contained breathing apparatus. Hand protection: Chemical resistant protective gloves Eye protection: Safety glasses/face shield 9. Physical and Chemical Properties Form: Odour: Colour: ph value: Flammability: Solubility in water: gas odourless colourless Flammable. not applicable insoluble 10. Stability and Reactivity Reactivity Oxidizing properties: not fire-propagating (other) Chemical stability Possibility of hazardous reactions Formation of explosive gas/air mixtures. Conditions to avoid Avoid heat. Avoid UV-light and other radiation with high energy. Avoid excess pressure. Incompatible materials strong oxidizing agents, strong bases, strong acids, strong alkalies Hazardous decomposition products 11. Toxicological information Primary routes of exposure

7 Revision date : 2015/03/08 Page: 7/10 Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or skin contact. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of entry for liquefied gases. Acute Toxicity/Effects Acute toxicity Information on: Methane Information on: Butane Assessment of acute toxicity:virtually nontoxic by inhalation. Information on: 1-Butene Information on: Isobutylene Information on: Trans-2-butene Irritation / corrosion Information on: Methane Information on: Butane Assessment of irritating effects: Not irritating to the eyes. Not irritating to the skin. The product has not been tested. The statement has been derived from the structure of the product. Information on: 1-Butene Information on: Isobutylene Information on: Trans-2-butene Chronic Toxicity/Effects Repeated dose toxicity Information on: Methane Information on: Butane Assessment of repeated dose toxicity: No adverse effects were observed after repeated inhalative exposure in animal studies. Information on: 1-Butene Information on: Isobutylene Information on: Trans-2-butene Symptoms of Exposure

8 Revision date : 2015/03/08 Page: 8/ Ecological Information Toxicity Aquatic toxicity Assessment of aquatic toxicity: There is a high probability that the product is not acutely harmful to aquatic invertebrates. Persistence and degradability Assessment biodegradation and elimination (H2O) not applicable Additional information Other ecotoxicological advice: Do not discharge product into the environment without control. 13. Disposal considerations Waste disposal of substance: Dispose of in accordance with national, state and local regulations. Container disposal: WARNING: Empty containers may still contain hazardous residue. Dispose of in a licensed facility. RCRA: D Transport Information Land transport USDOT Hazard class: 2.1 ID number: UN 1965 Hazard label: 2.1 Proper shipping name: HYDROCARBON GAS MIXTURE, LIQUEFIED, N.O.S. (contains BUTENE/BUTANE) Sea transport IMDG Hazard class: 2.1 ID number: UN 1965 Hazard label: 2.1 Marine pollutant: Proper shipping name: NO HYDROCARBON GAS MIXTURE, LIQUEFIED, N.O.S. (contains BUTENE/BUTANE) Air transport IATA/ICAO Hazard class: 2.1 ID number: UN 1965

9 Revision date : 2015/03/08 Page: 9/10 Hazard label: 2.1 Proper shipping name: HYDROCARBON GAS MIXTURE, LIQUEFIED, N.O.S. (contains BUTENE/BUTANE) 15. Regulatory Information Federal Regulations Registration status: Chemical TSCA, US released / listed EPCRA 311/312 (Hazard categories): Acute; Chronic CERCLA RQ CAS Number Chemical name 5000 LBS n-hexane 100 LBS ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; Heptene; methane; but-1-ene; Pentane; 1-Pentene; Nonene; octane; 1-Octene; Nonane; 2-methylpropene; heptane; 2-Butene, (Z)-; 1-Hexene; 2-Butene, (E)-; Propane, 2-methyl-; n-butane State regulations State RTK CAS Number Chemical name MA, NJ, PA methane MA, NJ, PA methylpropene MA, NJ, PA but-1-ene MA, NJ, PA Butene, (Z)- MA, NJ, PA Butene, (E)- MA, PA n-butane MA, PA Pentane MA, NJ, PA Pentene MA, NJ, PA n-hexane MA, NJ, PA Hexene MA, NJ, PA heptane MA, NJ, PA Heptene MA, NJ, PA octane MA, NJ, PA Octene MA, PA Nonane MA, NJ, PA Nonene NJ Undecane NFPA Hazard codes: Health : 2 Fire: 4 Reactivity: 0 Special: HMIS III rating Health: 2 Flammability: 4 Physical hazard: 0

10 Revision date : 2015/03/08 Page: 10/ Other Information SDS Prepared by: BASF NA Product Regulations SDS Prepared on: 2015/03/08 We support worldwide Responsible Care initiatives. We value the health and safety of our employees, customers, suppliers and neighbors, and the protection of the environment. Our commitment to Responsible Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring the safe and environmentally sound handling of our products, and minimizing the impact of our operations on society and the environment during production, storage, transport, use and disposal of our products. IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY UNDERSTAND AND AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY OUR COMPANY HEREUNDER ARE GIVEN GRATIS AND WE ASSUME NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. END OF DATA SHEET