SAFETY DATA SHEET. None. Warning May form combustible dust concentrations in air.

Transcription

1 SAFETY DATA SHEET 1. Identification Product identifier Other means of identification Recommended use Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Manufacturer/Supplier Valero Marketing & Supply Company and Affiliates One Valero Way San Antonio, TX General Assistance Contact Person Industrial Hygienist Emergency Telephone 24 Hour Emergency (CHEMTREC USA) 2. Hazard(s) identification Physical hazards Health hazards OSHA defined hazards Label elements Hazard symbol Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Hazard(s) not otherwise classified (HNOC) Not classified. Not classified. Combustible dust None. Warning May form combustible dust concentrations in air. Observe good industrial hygiene practices. Wash hands after handling. Store away from incompatible materials. Dispose of waste and residues in accordance with local authority requirements. None known. 3. Composition/information on ingredients Mixtures Composition comments All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. 4. First-aid measures Inhalation Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed If symptomatic, move to fresh air. If respiratory problems, administer artificial respiration/oxygen. Get medical attention if symptoms persist. Wash skin with soap and water. Get medical attention promptly if symptoms occur after washing. Any material that contacts the eye should be washed out immediately with water. If easy to do, remove contact lenses. Get medical attention promptly if symptoms occur after washing. Seek medical attention if discomfort persists. Direct contact with eyes may cause temporary irritation. Dust may irritate respiratory system. Treat symptomatically Version #: 01 Revison date: 28-May-2014 Print date: 28-May / 6

2 5. Fire-fighting measures Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire-fighting equipment/instructions Water. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Avoid generating dust; fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Wear appropriate personal protective equipment (See Section 8). Absorb spill with vermiculite or other inert material, then place in a container for chemical waste. Large Spills: Sweep up and place in a clearly labeled container for chemical waste. Dust deposits should not be allowed to accumulate on surfaces, as these may form an explosive mixture if they are released into the atmosphere in sufficient concentration. Avoid dispersal of dust in the air (i.e., clearing dust surfaces with compressed air). Nonsparking tools should be used. Flush area with water. Dike for later disposal. Environmental precautions 7. Handling and storage Precautions for safe handling Conditions for safe storage, including any incompatibilities Small Spills: Prevent runoff from entering drains, sewers, or streams. Nonsparking tools should be used. Environmental manager should be informed of all releases, as necessary. Reporting of releases to appropriate regulatory agencies may be required. Wear protective clothing as described in Section 8 of this safety data sheet. Minimize dust generation and accumulation. Use only with adequate ventilation. Wash thoroughly after handling. Keep container closed. Store away from incompatible materials (See Section 10). Routine housekeeping should be instituted to ensure that dusts do not accumulate on surfaces. Dry powders can build static electricity charges when subjected to the friction of transfer and mixing operations. Provide adequate precautions, such as electrical grounding and bonding, or inert atmospheres. Refer to NFPA 654, Standard for the Prevention of Fire and Dust Explosions from the Manufacturing, Processing, and Handling of Combustible Particulate Solids, for safe handling. 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) Dried Distillers Grains with Solubles (CAS -) US. OSHA Table Z-3 (29 CFR ) Dried Distillers Grains with Solubles (CAS -) US. ACGIH Threshold Limit s Dried Distillers Grains with Solubles (CAS -) PEL 5 mg/m3 Respirable fraction. 15 mg/m3 Total dust. TWA 5 mg/m3 Respirable fraction. 15 mg/m3 Total dust. 50 millions of Total dust. particle 15 millions of Respirable fraction. particle TWA 3 mg/m3 Respirable particles Version #: 01 Revison date: 28-May-2014 Print date: 28-May / 6

3 US. ACGIH Threshold Limit s Biological limit values Appropriate engineering controls No biological exposure limits noted for the ingredient(s). 10 mg/m3 Inhalable particles. Ensure adequate ventilation, especially in confined areas. It is recommended that all dust control equipment such as local exhaust ventilation and material transport systems involved in handling of this product contain explosion relief vents or an explosion suppression system or an oxygen deficient environment. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin protection Hand protection Wear protective gloves. Other Respiratory protection Thermal hazards General hygiene considerations 9. Physical and chemical properties Appearance Brown granular Physical state Solid. Granular. Color Brown. Odor Slightly toasted smell Odor threshold ph Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Explosive limit - lower (%) Explosive limit - upper (%) Vapor pressure Vapor density Relative density Solubility(ies) Solubility (water) Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Wear chemical-resistant gloves, footwear and protective clothing appropriate for risk of exposure. Contact glove manufacturer for specific information. If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. Respirator type: Air-purifying respirator with an appropriate, government approved (where applicable), air-purifying filter, cartridge or canister. Wear appropriate thermal protective clothing, when necessary. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants Version #: 01 Revison date: 28-May-2014 Print date: 28-May / 6

4 Viscosity Other information Weighted solids ~90% 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products Material is stable under normal conditions. Hazardous polymerization does not occur. Heat, sparks, flames, elevated temperatures. Minimize dust generation and accumulation. Strong oxidizing agents. No hazardous decomposition products are known. 11. Toxicological information Information on likely routes of exposure Ingestion Ingestion of dusts generated during working operations may cause nausea and vomiting. Inhalation Dust may irritate respiratory system. Skin contact Direct contact may irritate. Eye contact Direct contact with eyes may cause temporary irritation. Symptoms related to the Direct contact with eyes may cause temporary irritation. Dust may irritate respiratory system. physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity Based on available data, the classification criteria are not met. Skin corrosion/irritation Based on available data, the classification criteria are not met. Serious eye damage/eye Based on available data, the classification criteria are not met. irritation Respiratory or skin sensitization Respiratory sensitization Based on available data, the classification criteria are not met. Skin sensitization Based on available data, the classification criteria are not met. Germ cell mutagenicity Based on available data, the classification criteria are not met. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. Reproductive toxicity Based on available data, the classification criteria are not met. Specific target organ toxicity - Based on available data, the classification criteria are not met. single exposure Specific target organ toxicity - Based on available data, the classification criteria are not met. repeated exposure Aspiration hazard Based on available data, the classification criteria are not met. 12. Ecological information Ecotoxicity Persistence and degradability Bioaccumulative potential Mobility in soil Other adverse effects 13. Disposal considerations Disposal instructions Hazardous waste code Waste from residues / unused products The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. The product is expected to be biodegradable. The product is not expected to bioaccumulate. Dispose of contents/container in accordance with local/regional/national/international regulations. Dispose of in accordance with local regulations Version #: 01 Revison date: 28-May-2014 Print date: 28-May / 6

5 Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport information DOT Not regulated as dangerous goods. IATA Not regulated as dangerous goods. IMDG Not regulated as dangerous goods. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information Not applicable. US federal regulations This product is hazardous according to OSHA 29 CFR TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) US. OSHA Specifically Regulated Substances (29 CFR ) CERCLA Hazardous Substance List (40 CFR 302.4) Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance SARA 311/312 Hazardous Yes chemical SARA 313 (TRI reporting) Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR ) Safe Drinking Water Act (SDWA) US state regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. US. Massachusetts RTK - Substance List US. New Jersey Worker and Community Right-to-Know Act US. Pennsylvania Worker and Community Right-to-Know Law US. Rhode Island RTK US. California Proposition 65 US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance Version #: 01 Revison date: 28-May-2014 Print date: 28-May / 6

6 16. Other information, including date of preparation or last revision Issue date 28-May-2014 Revision date - Version # 01 Further information HMIS is a registered trade and service mark of the NPCA. NFPA Ratings References Disclaimer EPA: AQUIRE database US. IARC Monographs on Occupational Exposures to Chemical Agents HSDB - Hazardous Substances Data Bank National Toxicology Program (NTP) Report on Carcinogens ACGIH Documentation of the Threshold Limit s and Biological Exposure Indices This material Safety Data Sheet (SDS) was prepared in accordance with 29 CFR by Valero Marketing & Supply Co., ("VALERO"). VALERO does not assume any liability arising out of product use by others. The information, recommendations, and suggestions presented in this SDS are based upon test results and data believed to be reliable. The end user of the product has the responsibility for evaluating the adequacy of the data under the conditions of use, determining the safety, toxicity and suitability of the product under these conditions, and obtaining additional or clarifying information where uncertainty exists. No guarantee expressed or implied is made as to the effects of such use, the results to be obtained, or the safety and toxicity of the product in any specific application. Furthermore, the information herein is not represented as absolutely complete, since it is not practicable to provide all the scientific and study information in the format of this document, plus additional information may be necessary under exceptional conditions of use, or because of applicable laws or government regulations Version #: 01 Revison date: 28-May-2014 Print date: 28-May / 6