MATERIAL SAFETY DATA SHEET 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: COMMON NAME:

Transcription

1 MATERIAL SAFETY DATA SHEET Section 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT ME: BOSS 75W90 FM Gear Lube COMMON ME: Gear Oil 75W-90 CHEMICAL FORMULA: Mixture CHEMICAL ME: Lubricating Oil CHEMICAL FAMILY: Hydrocarbon SUPPLIER: BOSS Lubricants Street SE Suite 112 Calgary, AB T2C 1R ISSUE: February 6, 2015 Section 2: COMPOSITION AND INFORMATION ON INGREDIENTS INGREDIENTS PERCENTAGES PEL (OSHA) TLV (ACGIH) CAS # (by weight) Oil, Solvent Neutral N/A 5 mg/m3 TWA (Oil Mist) Mixture Performance Additives N/A 5 mg/m3 TWA (Oil Mist) Mixture (TWA) - Time Weighted Average is the employee s average airborne exposure in any 8-hour work shift of a 40-hour work week which shall not be exceeded. (STEL) - Short Term Exposure Limit is the employee s 15-minute time weighted average exposure which shall not be exceeded at any time during a work day unless another time limit is specified. Section 3: HAZARDS IDENTIFICATION EMERGENCY OVERVIEW POTENTIAL HEALTH EFFECTS ROUTES OF ENTRY: (Eye Contact, Dermal, Inhalation.) ACUTE EFFECTS OF OVER EXPOSURE: Eyes: Contact with eyes may cause irritation. Skin: Contact with skin may cause irritation. Inhalation: May cause irritation of the nose and throat. Ingestion: May cause nausea and vomiting. Large quantities may affect the central nervous system. CHRONIC EFFECTS OF OVER EXPOSURE: No adverse effects anticipated. Mutagenicity: No data available to indicate product present at greater than 1.0% present a mutagenic or genotoxic hazard. Reproductive Toxicity: No data available to indicate product present at greater than 1.0% a reproductive hazard. Teratogenicity: No data available to indicate product present at greater than 1.0% present a teratogenicity hazard. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Existing dermatitis and respiratory conditions. CARCINOGENICITY: NTP: No IARC: No OSHA: No Section 4: FIRST AID MEASURES EMERGENCY AND FIRST AID PROCEDURES: Eye Contact: If material comes in contact with the eyes, immediately wash the eyes with large amounts of water for 15 minutes, occasionally lifting the lower and upper lids. Get medical attention. 1 P age

2 Skin Contact: If the material comes in contact with the skin, wash the contaminated skin with soap and water promptly. If the material penetrates through clothing, remove the clothing and wash the skin with soap and water promptly. If irritation persists after washing, get medical attention immediately. Inhalation: If person breathes in large amounts of material, move the exposed person to fresh air at once. If breathing has stopped, perform artificial respiration. Keep the person warm and at rest. Get medical attention as soon as possible. Ingestion: If material has been swallowed, do not induce vomiting. Get medical attention immediately. Section 5: FIRE - FIGHTING MEASURES FLASH POINT: >350 F (>177 C) AUTO IGNITION TEMP: >750 F FLAMMABLE LIMITS IN AIR LOWER UPPER % BY VOLUME N/A N/A EXTINGUISHING MEDIA: Use water spray to cool fire exposed surfaces and to protect personnel. Use foam, dry chemical or water spray (fog) to extinguish fire. SPECIAL FIRE FIGHTING PROCEDURES: When fighting fires wear full turnout gear and self-contained breathing apparatus. Water may cause splattering. Material floats on water. UNUSUAL FIRE AND EXPLOSION HAZARDS: Toxic fumes gases or vapors may evolve on burning. HAZARD RATINGS: NFPA 704: Health- 1 Fire- 1 Reactivity- 0 HMIS: Health- _0 Fire- _1_ Reactivity-_0 Section 6: ACCIDENTAL RELEASE MEASURES STEPS TO TAKE IF MATERIAL IS RELEASED OR SPILLED: Personal protective equipment should be worn. Ventilate area if confined or poorly ventilated. Contain with dikes or absorbent to prevent migration to sewers/streams. Take up small spill with dry chemical absorbent; large spills may require pump or vacuum prior to absorbent. May require excavation of severely contaminated soil. Avoid contact with skin and eyes. Section 7: HANDLING AND STORAGE HANDLING AND STORING: Store in closed container away from all ignition sources. Handling temperatures should not exceed 175 F (80 C). Wash thoroughly after handling. Do not store at temperatures exceeding 113 F (45 C). Odorous and toxic fumes may form from the decomposition of this product if stored at excessive temperatures for extended periods of time. Open containers carefully and only in well ventilated areas or use appropriate respiratory protection. Store in well ventilated area. Section 8: EXPOSURE CONTROL - PERSOL PROTECTION ENGINEERING CONTROLS: Ventilate to control mists and vapors below exposure limits. RESPIRATORY EQUIPMENT: Normally not required, if exposure limits are exceeded use a Niosh approved organic vapor respirator. Self-contained breathing apparatus is recommended for entry into confined spaces or other poorly ventilated areas and for large spill clean-up sites. EYE PROTECTION: Chemical goggles or faceshield recommended to minimize eye contact. PROTECTIVE CLOTHING: Impervious (nitrile) gloves recommended when handling material to minimize exposure. Long sleeve shirts, chemically protective aprons and chemically protective boots are recommended for contact exposure or spill clean-up. Do not wear watches, rings or similar apparel that could entrap the material next to the skin. OTHER (SAFETY SHOWERS, EYE WASH STATIONS, ETC.): Water should be available for flushing and washing when exposure exists. Launder soiled clothes. Discard shoes or other leather articles saturated with the material. 2 P age

3 Section 9: PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Amber liquid ODOR: Mild odor BOILING POINT: N/D SPECIFIC GRAVITY (water=1): VAPOR PRESSURE: <1 mm Hg 68 F VAPOR DENSITY (air=1): N/D SOLUBLE IN WATER: Insoluble EVAPORATION RATE (ether=1): <1 ph: N/D Section 10: STABILITY AND REACTIVITY STABILITY: Stable at room temperature and pressure. See handling and storage section INCOMPATIBILITY CONDITIONS TO AVOID: See handling and storage section. MATERIALS TO AVOID: Acids, oxidizing agents. HAZARDOUS DECOMPOSITION PRODUCTS: Smoke, carbon monoxide, aldehydes, hydrogen sulfide and alkyl mercaptans may be released. Under combustion conditions, oxides of the following elements will be formed: Magnesium, calcium, nitrogen, sulfur, and carbon. HAZARDOUS POLYMERIZATION: Will not occur. Section 11: TOXICOLOGY INFORMATION ORAL TOXICITY: Minimal hazard. Oral toxicity greater than 5,000 mg/kg EYE IRRITATION: May be an eye irritant SKIN IRRITATION: Not expected to be a primary skin irritant, based on data from components or similar material. Prolonged or repeated skin contact as from clothing wet with material may cause dermatitis. Symptoms may include redness, edema, drying, defatting, and cracking of skin. RESPIRATORY IRRITATION: If material is misted or if vapors are generated from heating, exposure may cause irritation of mucous membranes and the upper respiratory tract similar to that observed with mineral oil. Based on data from components or similar materials. Under good industrial hygiene practices where all exposure limits are observed, respiratory irritation should not be a problem OTHER: Unknown TLV: 5 mg/m3 as oil mist Section 12: ECOLOGICAL INFORMATION Note: BOSS LUBRICANTS has not conducted specific ecological tests on this product. Section 13: DISPOSAL CONSIDERATION WASTE DISPOSAL PROCEDURES: Place contaminated materials in a disposable container and dispose of in accordance with Local, State and Federal environmental regulations. Section 14: TRANSPORTATION DOT PROPER SHIPPING ME: N/A DOT IDENTIFICATION NUMBER: N/A TDG REGULATION: N/A DOT HAZARD CLASS: N/A DOT EMER. RESPONSE GUIDE NO.: N/A Section 15: REGULATORY INFORMATION This product does contain toxic chemicals subject to the reporting requirements of SARA Section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 and of 40 CFR P age

4 CAS Number Chemical Name Percent by Weight Antimony Compounds 0.2% as Sb SARA SECTION HAZARD CATEGORIES (40 CFR 370.2): FIRE: No SUDDEN RELEASE OF PRESSURE: No REACTIVE: No ACUTE: Yes CHRONIC: No CADA: All components are in compliance with the Canadian Environmental Protection Act. This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. Section 16: OTHER INFORMATION Date: February 6, 2015 Supersedes: January 1, 2012 Revision History: None THE INFORMATION CONTAINED IN THIS MSDS RELATES ONLY TO THE SPECIFIC MATERIAL IDENTIFIED. IT DOES NOT COVER USE OF THAT MATERIAL IN COMBITION WITH ANY OTHER MATERIAL OR IN ANY PARTICULAR PROCESS. IN COMPLIANCE WITH 29 C.F.R (g), BOSS LUBRICANTS HAS PREPARED THIS MSDS IN SEGMENTS, WITH THE INTENT THAT THOSE SEGMENTS BE READ TOGETHER AS A WHOLE WITHOUT TEXTUAL OMISSIONS OR ALTERATIONS. BOSS LUBRICANTS BELIEVES THE INFORMATION CONTAINED HEREIN TO BE ACCURATE, BUT MAKES NO REPRESENTATION, GUARANTEE, OR WARRANTY, EXPRESS OR IMPLIED, ABOUT THE ACCURACY, RELIABILITY, OR COMPLETENESS OF THE INFORMATION OR ABOUT THE FITNESS OF CONTENTS HEREIN FOR EITHER GENERAL OR PARTICULAR PURPOSES. PERSONS REVIEWING THIS MSDS SHOULD MAKE THEIR OWN DETERMITION AS TO THE MATERIAL S SUITABILITY AND COMPLETENESS FOR USE IN THEIR PARTICULAR APPLICATIONS. 4 P age

5 Section 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER(S): BOSS GEAR LUBE 80W-90, 85W-140 COMPANY IDENTIFICATION EMERGENCY TELEPHONE NUMBERS BOSS LUBRICANTS Information: , ST SE Emergency: Calgary, AB T2C 1R4 CHEMTREC EMERGENCY NUMBER (24 hr): (800) Issue Date: January 1, 2015 Supersedes Issue: January 1, 2012 Section 2: COMPOSITION/INFORMATION ON INGREDIENTS COMPONENTS AMOUNT LIMIT/QTY AGENCY/TYPE LUBRICATING BASE OIL > 95.00% 5 mg/m3 (mist) ACGIH TWA SEVERELY REFINED PETROLEUM DISTILLATE* 10 mg/m3 (mist) ACGIH STEL 5 mg/m3 (mist) OSHA PEL ADDITIVES < 5.00% *The BASE OIL may be a mixture of any of the following: CAS , CAS , CAS , CAS , CAS , CAS , CAS , CAS , CAS , CAS , or CAS COMPOSITION COMMENT: All the components of this material are on the Toxic Substances Control Act Chemical Substances Inventory. This product fits the ACGIH definition for mineral oil mist. The ACGIH TLV is 5 mg/m3, the OSHA PEL is 5 mg/m3. Section 3: HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: CAUSES SEVERE EYE IRRITATION AND INJURY SPECIAL HAZARDS INFORMATION FOR MAN AND ENVIRONMENT Section 4: FIRST AID MEASURES EYE: No specific first aid measures are required because this material is not expected to cause eye irritation. As a precaution remove contact lenses, if worn, and flush eyes with water. SKIN: No specific first aid measures are required because this material is not expected to be harmful if it contacts the skin. As a precaution, remove clothing and shoes if contaminated. Use a waterless hand cleaner, mineral oil, or petroleum jelly to remove the material. Then wash skin with soap and water. Wash or clean contaminated clothing and shoes before reuse. INGESTION: No specific first aid measures are required because this material is not expected to be harmful if swallowed. Do not induce vomiting. As a precaution, give the person a glass of water or milk to drink and get medical advice. Section 5: FIRE FIGHTING MEASURES FIRE CLASSIFICATION: Classification (29 CFR ): Not classified by OSHA as flammable or combustible. FLAMMABLE PROPERTIES: FLASH POINT: (COC) F ( C) Min. AUTOIGNITION: FLAMMABILITY LIMITS (% by volume in air): Lower: Upper: EXTINGUISHING MEDIA: CO2, Dry Chemical, Foam, Water Fog NFPA RATINGS: Health 0; Flammability 1; Reactivity 0. FIRE FIGHTING INSTRUCTIONS: This material will burn although it is not easily ignited. 1 P age

6 COMBUSTION PRODUCTS: Normal combustion forms carbon dioxide and water vapor; incomplete combustion can produce carbon monoxide. Section 6: ACCIDENTAL RELEASE MEASURES CHEMTREC EMERGENCY NUMBER (24 hr): (800) or (202) ACCIDENTAL RELEASE MEASURES: This material may be toxic to aquatic organism and should be kept out of sewage and drainage systems and all bodies of water. Stop the source of the leak or release. Clean up releases as soon as possible. Contain liquid to prevent further contamination of soil, surface water or groundwater. Clean up small spills using appropriate techniques such as sorbent materials or pumping. Where feasible and appropriate, remove contaminated soil. Follow prescribed procedures for reporting and responding to larger releases. Section 7: HANDLING AND STORAGE Do not use pressure to empty drum or drum may rupture with explosive force. Empty containers retain product residue (solid, liquid, and/or vapor) and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, static electricity, or other sources of ignition. They may explode and cause injury or death. Empty drums should be completely drained, properly bunged, and promptly returned to a drum reconditioner, or properly disposed of. Avoid contaminating soil or releasing this material into sewage and drainage systems and bodies of water. Do not breathe oil mist at concentrations above the recommended exposure limits. Section 8: EXPOSURE CONTROLS/PERSOL PROTECTION ENGINEERING CONTROLS: Use in a well-ventilated area. If user operations generate an oil mist, use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below the recommended exposure limits. PERSOL PROTECTIVE EQUIPMENT EYE/FACE PROTECTION: No special eye protection is normally required. Where splashing is possible, wear safety glasses with side shields as a good safety practice. SKIN PROTECTION: No special protective clothing is normally required. Where splashing is possible, select protective clothing depending on operations conducted, physical requirements and other substances. Suggested materials for protective gloves include: Nitrile, Silver Shield, Viton, and/or 4H RESPIRATORY PROTECTION: No special respiratory protection is normally required. If user operations generate an oil mist, determine if airborne concentrations are below the recommended exposure limits. If not, select a NIOSH/MSHA approved respirator that provides adequate protection from concentrations of this material. Use the following elements for air-purifying respirators: particulate. Avoid prolonged and/or repeated contact with skin. Section 9: PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL DESCRIPTION: ph: VAPOR PRESSURE: VAPOR DENSITY (AIR=1): BOILING POINT: FREEZING POINT: MELTING POINT: SOLUBILITY: SPECIFIC GRAVITY: VOLATILE ORGANIC COMPOUNDS (VOC): EVAPORATION RATE: Light to dark amber liquid Soluble in hydrocarbon solvents; insoluble in water. 60 F 2 P age

7 VISCOSITY: PERCENT VOLATILE (VOL): F 10. STABILITY AND REACTIVITY No instability 11: TOXICOLOGICAL INFORMATION EYE EFFECTS: The eye irritation hazard is based on an evaluation of the data for the components. SKIN EFFECTS: The skin irritation hazard is based on an evaluation of the data for the components. ACUTE ORAL EFFECTS: The acute oral toxicity is based on an evaluation of the data for the components. ACUTE INHALATION EFFECTS: The acute respiratory toxicity is based on an evaluation of the data for the components. ADDITIOL TOXICOLOGY INFORMATION: This product contains petroleum base oils which may be refined by various processes including severe solvent extraction, severe hydrocracking, or severe hydrotreating. None of the oils requires a cancer warning under the OSHA Hazard Communication Standard (29 CFR ). These oils have not been listed in the National Toxicology Program (NTP) Annual Report nor have they been classified by the International Agency for Research on Cancer (IARC) as; carcinogenic to humans (Group 1), probably carcinogenic to humans (Group 2A), or possibly carcinogenic to humans (Group 2B). 12. ECOLOGICAL INFORMATION ECOTOXICITY: The 96-hour LC50 in rainbow trout (Oncorhynchus mykiss) is >5000 mg/l. ENVIRONMENTAL FATE: This material is not expected to be readily biodegradable. 13. DISPOSAL CONSIDERATIONS Oil collection services are available for used oil recycling or disposal. Place contaminated materials in containers and dispose of in a manner consistent with applicable regulations. Contact your sales representative or local environmental or health authorities for approved disposal or recycling methods. 14. TRANSPORT INFORMATION The description shown may not apply to all shipping situations. Consult 49CFR, or appropriate Dangerous Goods Regulations, for additional description requirements (e.g., technical name) and mode-specific or quantity-specific shipping requirements. DOT SHIPPING ME: NOT DESIGTED AS A HAZARDOUS MATERIAL BY THE FEDERAL DOT DOT HAZARD CLASS: NOT APPLICABLE DOT IDENTIFICATION NUMBER: NOT APPLICABLE DOT PACKING GROUP: NOT APPLICABLE 15. REGULATORY INFORMATION SARA 311 CATEGORIES: 1. Immediate (Acute) Health Effects: No 2. Delayed (Chronic) Health Effects: No 3. Fire Hazard: No 4. Sudden Release of Pressure Hazard: No 5. Reactivity Hazard: No EEC RISK AND SAFETY STATEMENTS: May cause long-term adverse effects in the aquatic environment. 3 P age

8 NEW JERSEY RTK CLASSIFICATION: Under the New Jersey Right-to-Know Act L Chapter 315 N.J.S.A. 34:5A-1 et. seq., the product is to be identified as follows: PETROLEUM OIL WHMIS CLASSIFICATION: This product is not considered a controlled product according to the criteria of the Canadian Controlled Products Regulations. 16. OTHER INFORMATION NFPA RATINGS: Health 0; Flammability 1; Reactivity 0; HMIS RATINGS: Health 1; Flammability 1; Reactivity 0; (0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme, PPE: Personal Protection Equipment Index recommendation, *- Chronic Effect Indicator). These values are obtained using the guidelines or published evaluations prepared by the National Fire Protection Association (NFPA) or the National Paint and Coating Association (for HMIS ratings). REVISION STATEMENT: This is a revised Material Safety Data Sheet. ABBREVIATIONS THAT MAY HAVE BEEN USED IN THIS DOCUMENT: TLV - Threshold Limit Value TWA - Time Weighted Average STEL - Short-term Exposure Limit TPQ - Threshold Planning Quantity RQ - Reportable Quantity PEL - Permissible Exposure Limit C - Ceiling Limit CAS - Chemical Abstract Service Number A1-5 - Appendix A Categories () - Change Has Been Proposed - No Data Available - Not Applicable Prepared according to the OSHA Hazard Communication Standard (29 CFR ) and the ANSI MSDS Standard (Z400.1). The above information is based on the data of which we are aware and is believed to be correct as of the date hereof. Since this information may be applied under conditions beyond our control and with which we may be unfamiliar and since data made available subsequent to the date hereof may suggest modification of the information, we do not assume any responsibility for the results of its use. This information is furnished upon condition that the person receiving it shall make his own determination of the suitability of the material for his particular purpose. 4 P age