MATERIAL SAFETY DATA SHEET

Transcription

1 Page : 1 / 6 01 Identification of the substance/preparation and of the company/undertaking Product details Trade name: Article number: Application of the substance / the preparation Coating material Manufacturer/Supplier: VIACOR Polymer GmbH Hohenneuffenstr. 14 D Nürtingen Information in case of emergency: VIACOR Polymer GmbH, Dr. R. Jooss fone: +49 / 7022 / (8 a.m. - 6 p.m.) Toxicity center Berlin fon / fax Hazards identification Hazard description: C Corrosive N Dangerous for the environment Information concerning particular hazards for human and environment: R 62 Possible risk of impaired fertility. R 63 Possible risk of harm to the unborn child. R 22 Harmful if swallowed. R 34 Causes burns. R 37 Irritating to respiratory system. R 43 May cause sensitisation by skin contact. R 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. Classification system: The classification is according to the latest editions of the EU-lists, and extended by company and literature data. 03 Composition/information on ingredients Chemical characterization Description: Mixture of substances listed below with nonhazardous additions. Dangerous components: CAS NO. Description Index R-phrases % tert-butylphenol 25,00-50,00 EINECS: Xi 36/37/ m-phenylenebis(methylamine) 12,50-25,00 EINECS: C Xn 20/ / trimethylhexane-1,6-diamine 12,50-25,00 EINECS: C (continued on page 2)

2 Page : 2 / (continued of page 1) nonylphenol 5,00-12,50 EINECS: C N / ,4,6-tris(dimethylaminomethyl)phenol 0,00-1,25 EINECS: Xn 22-36/38 Additional information: For the wording of the listed risk phrases refer to section First aid measures General information: Immediately remove any clothing soiled by the product. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. After inhalation: Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation. Take affected persons into fresh air and keep quiet. After skin contact: Immediately wash with water and soap and rinse thoroughly. After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor. After swallowing: Do not induce vomiting; call for medical help immediately. Call for a doctor immediately. Drink plenty of water and provide fresh air. Call for a doctor immediately. 05 Fire-fighting measures Suitable extinguishing agents: CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Use fire extinguishing methods suitable to surrounding conditions. For safety reasons unsuitable extinguishing agents: Water with full jet Protective equipment: Wear self-contained respiratory protective device. 06 Accidental release measures Person-related safety precautions: Wear protective equipment. Keep unprotected persons away. Measures for environmental protection: Inform respective authorities in case of seepage into water course or sewage system. Do not allow to enter sewers/ surface or ground water. Measures for cleaning/collecting: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Use neutralizing agent. Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. 07 Handling and storage Handling: Information for safe handling: Ensure good ventilation/exhaustion at the workplace. Information about fire - and explosion protection: No special measures required. (continued on page 3)

3 Page : 3 / 6 Storage: Requirements to be met by storerooms and receptacles: No special requirements. Information about storage in one common storage facility: Not required. Further information about storage conditions: Keep container tightly sealed. Store in cool, dry conditions in well sealed receptacles. Protect from heat and direct sunlight. (continued of page 2) 08 Exposure controls/personal protection Ingredients with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. Additional information: The lists valid during the making were used as basis. Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing Avoid contact with the eyes and skin. Respiratory protection: Not required. Protection of hands: Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Protective gloves Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Butyl rubber, BR Nitrile rubber, NBR Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Tightly sealed goggles 09 Physical and chemical properties General Information Form: Colour: Odour: Change in condition Melting point/melting range: Fluid Yellowish Amine-like Undetermined. Boiling point/boiling range: 200 C Flash point: 130 C DIN Self-igniting: Product is not selfigniting. Danger of explosion: Product does not present an explosion hazard. Vapour pressure: at 20 C 0,0600 hpa Density: 1,0190 g/cm3 Solubility in / Miscibility with water: Not miscible or difficult to mix. ph-value: at 20 C 12 Viscosity: Dynamic: at 20 C mpa.s Solvent content: Solids content: 100,00 % (continued on page 4)

4 Page : 4 / 6 10 Stability and reactivity (continued of page 3) Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Dangerous decomposition products: No dangerous decomposition products known. 11 Toxicological information Acute toxicity: LD/LC50 values relevant for classification: VIASOL EP-P206 Komp. B Oral, LD50: 1,3 mg/kg (rat) tert-butylphenol Oral, LD50: 2951 mg/kg (rat) Dermal, LD50: 2288 mg/kg (Rabbit) m-phenylenebis(methylamine) Oral, LD50: 1040 mg/kg (rat) Inhalative, LC50/4h: 2,4 mg/l (rat) trimethylhexane-1,6-diamine Oral, LD50: 900 mg/kg (rat) nonylphenol Oral, LD50: 1620 mg/kg (rat) Primary irritant effect: on the skin: Caustic effect on skin and mucous membranes. on the eye: Strong caustic effect. Sensitization: Sensitization possible through skin contact. Additional toxicological information: The product shows the following dangers according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version: Harmful Corrosive Irritant The product can cause deformations. Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus and stomach. 12 Ecological information Ecotoxical effects: Remark: Toxic for fish Additional ecological information: General notes: Toxic for aquatic organisms Do not allow product to reach ground water, water course or sewage system, even in small quantities. Do not allow product to reach ground water, water course or sewage system. Must not reach sewage water or drainage ditch undiluted or unneutralized. Danger to drinking water if even extremely small quantities leak into the ground. Also poisonous for fish and plankton in water bodies. 13 Disposal considerations Product: Recommendation Must not be disposed together with household garbage. Do not allow product to reach sewage system. Uncleaned packaging: Recommendation: Disposal must be made according to official regulations. (continued on page 5)

5 Page : 5 / 6 14 Transport information (continued of page 4) Land transport ADR/RID (cross-border) ADR/RID class: Danger code (Kemler): 80 8 (C7) UN-Number: 2735 Packaging group: Hazard label: 8 III Description of goods: 2735 AMINES, LIQUID, CORROSIVE, N.O.S. (M PHENYLENEBIS(METHYLAMINE)) Excepted quantities (EQ): Limited quantities (LQ) Transport category 3 Tunnel restriction code Maritime transport IMDG: IMDG Class: 8 E1 LQ7 UN Number: 2735 Label 8 E Packaging group: EMS Number: Marine pollutant: III F-A,S-B Proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. (M PHENYLENEBIS(METHYLAMINE)) Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: 8 Yes UN/ID Number: 2735 Label 8 Packaging group: Proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. (M PHENYLENEBIS(METHYLAMINE)) III (continued on page 6)

6 Page : 6 / 6 15 Regulatory information (continued of page 5) Labelling according to EU guidelines: The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous Materials. Code letter and hazard designation of product: C Corrosive N Dangerous for the environment Hazard-determining components of labelling: m-phenylenebis(methylamine)/ trimethylhexane-1,6-diamine/ nonylphenol Risk phrases: R 62 R 63 R 22 R 34 R 37 R 43 R 51/53 Safety phrases: S 26 S 36/37/39 S 45 S 57 Possible risk of impaired fertility. Possible risk of harm to the unborn child. Harmful if swallowed. Causes burns. Irritating to respiratory system. May cause sensitisation by skin contact. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Use appropriate container to avoid environmental contamination. National regulations: Classification according to VbF: - Waterhazard class: Water hazard class 3 (Self-assessment): extremely hazardous for water. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Relevant R-phrases R 36/37/38 Irritating to eyes, respiratory system and skin. R 20/22 Harmful by inhalation and if swallowed. R 22 Harmful if swallowed. R 62 Possible risk of impaired fertility. R 36/38 Irritating to eyes and skin. R 34 Causes burns. R 63 Possible risk of harm to the unborn child. R 43 May cause sensitisation by skin contact. R 52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.