Revision Number: Issue date: 05/22/ PRODUCT AND COMPANY IDENTIFICATION. IDH number: HAZARDS IDENTIFICATION

Transcription

1 Safety Data Sheet Revision Number: Issue date: 05/22/ PRODUCT AND COMPANY IDENTIFICATION Product name: BONDERITE C-SO 263 WIPE SOLVENT CLEANER known as PARCOSOL 263 WIPES Product type: Cleaner Restriction of Use: None identified Region: United States Company address: Henkel Corporation One Henkel Way Rocky Hill, Connecticut Contact information: Telephone: +1 (860) MEDICAL EMERGENCY Phone: Poison Control Center (toll free) or TRANSPORT EMERGENCY Phone: CHEMTREC (toll free) or Internet: 2. HAZARDS IDENTIFICATION WARNING: EMERGENCY OVERVIEW CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION. CAUSES SERIOUS EYE IRRITATION. MAY CAUSE DROWSINESS OR DIZZINESS. HAZARD CLASS HAZARD CATEGORY SKIN IRRITATION 2 EYE IRRITATION 2A SKIN SENSITIZATION 1 SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3 PICTOGRAM(S) Precautionary Statements Prevention: Response: Storage: Disposal: Avoid breathing dust or fumes. Wash affected area thoroughly after handling. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves, eye protection, and face protection. IF ON SKIN: Wash with plenty of water. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation or rash occurs: Get medical attention. If eye irritation persists: Get medical attention. Take off contaminated clothing. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations. Classification complies with OSHA Hazard Communication Standard (29 CFR ) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS). Page 1 of 6

2 See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Component(s) CAS Number Percentage* Naphtha, petroleum, hydrotreated light tert-butyl acetate tert-butyl alcohol * Exact percentages may vary or are trade secret. Concentration range is provided to assist users in providing appropriate protections. 4. FIRST AID MEASURES Inhalation: Skin contact: Eye contact: Ingestion: If inhaled, immediately remove the affected person to fresh air. If symptoms develop and persist, get medical attention. Immediately flush skin with plenty of water (using soap, if available). If symptoms develop and persist, get medical attention. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Get immediate medical attention. DO NOT induce vomiting unless directed to do so by medical personnel. Symptoms: See Section 11. Notes to physician: This material, if aspirated into the lungs, may cause chemical pneumonitis; treat the affected person appropriately. 5. FIRE FIGHTING MEASURES Extinguishing media: Special firefighting procedures: Unusual fire or explosion hazards: Hazardous combustion products: Foam, dry chemical or carbon dioxide. In case of fire, keep containers cool with water spray. Wear full protective clothing. Wear self-contained breathing apparatus. DANGEROUS when exposed to heat or flame. This material can be ignited by flame or spark under all normal atmospheric conditions. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. If product is heated above its flash point it will release flammable vapors which can burn in the open or be explosive in confined spaces if exposed to ignition source. Mists or sprays may be flammable below the normal flash point. Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Clean-up methods: Prevent further leakage or spillage if safe to do so. Wear appropriate protective equipment and clothing during clean-up. Remove all sources of ignition. Scrape up spilled material and place in a closed container for disposal. Dispose of according to Federal, State and local governmental regulations. Page 2 of 6

3 7. HANDLING AND STORAGE Handling: Storage: Avoid contact with eyes, skin and clothing. Avoid breathing vapors or mists of this product. Provide adequate ventilation. Wash thoroughly after handling. Do not take internally. Keep away from heat, spark and flame. Do not pressurize, cut, heat or weld containers. Empty product containers may contain product residue. Do not reuse empty containers. For safe storage, store between 40 F (4.4 C) and 100 F (37.8 C) Keep container tightly closed and in a cool, well-ventilated place away from incompatible materials. Do not pressurize, cut, heat or weld containers. Empty product containers may contain product residue. Do not reuse empty containers. For information on product shelf life, please review labels on container or check the Technical Data Sheet. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER Naphtha, petroleum, hydrotreated light tert-butyl acetate tert-butyl alcohol None 50 ppm TWA 150 ppm STEL 100 ppm TWA 100 ppm (400 mg/m3) PEL None None 200 ppm (950 mg/m3) PEL None None 100 ppm (300 mg/m3) PEL None None Engineering controls: Respiratory protection: Eye/face protection: Skin protection: Ventilation should effectively remove and prevent buildup of any dust generated from the handling of this product. When dusts or thermal processing fumes are generated and ventilation is not sufficient to effectively remove them, appropriate NIOSH/MSHA approved respiratory protection must be provided. Safety goggles or safety glasses with side shields. Wear impervious gloves for prolonged contact. Use of impervious apron and boots are recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Solid Color: White Odor: Solvent Odor threshold: ph: Vapor pressure: Boiling point/range: 99.4 C (210.9 F) Melting point/ range: Specific gravity: 0.74 Vapor density: Flash point: 10.6 C (51.08 F) Closed cup; (value for solvent) Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Autoignition temperature: Flammability: Not applicable Evaporation rate: Solubility in water: Negligible Partition coefficient (n-octanol/water): VOC content: 100 % (calculated) Viscosity: Decomposition temperature: Page 3 of 6

4 10. STABILITY AND REACTIVITY Stability: Hazardous reactions: Hazardous decomposition products: Incompatible materials: Reactivity: Conditions to avoid: Stable at normal conditions. None under normal processing. Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. This product may react with strong acids or oxidizing agents. Keep away from heat, ignition sources and incompatible materials. 11. TOXICOLOGICAL INFORMATION Relevant routes of exposure: Potential Health Effects/Symptoms Inhalation: Skin contact: Eye contact: Ingestion: Inhalation of vapors or mists of the product may be irritating to the respiratory system. Inhalation of high vapor concentrations may produce respiratory irritation, and may cause central nervous system (CNS) depression. Excessive inhalation of this material causes headache, dizziness, nausea and incoordination. Prolonged and/or repeated skin contact with this product may cause irritation/dermatitis. Prolonged or repeated contact with this product may dry and/or defat the skin. A single exposure is not likely to result in the product being absorbed through the skin in harmful amounts. This product may be severely irritating to the eyes. Ingestion of this product may cause nausea, vomiting and diarrhea. Small amounts of this product, if aspirated into the lungs, may cause mild to severe pulmonary injury. Ingestion of this product may result in central nervous system effects including headache, sleepiness, dizziness, slurred speech and blurred vision. Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects Naphtha, petroleum, hydrotreated light None Central nervous system, Irritant, Kidney, Lung tert-butyl acetate None Blood, Cardiac, Central nervous system, Gastrointestinal, Irritant tert-butyl alcohol Oral LD50 (Rat) = 3.5 g/kg Allergen, Central nervous system, Irritant, Oral LD50 (Rabbit) = 3.6 g/kg Some evidence of carcinogenicity Hazardous Component(s) NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) Naphtha, petroleum, hydrotreated light No No No tert-butyl acetate No No No tert-butyl alcohol No No No 12. ECOLOGICAL INFORMATION Ecological information: Page 4 of 6

5 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Dispose of according to Federal, State and local governmental regulations. Hazardous waste number: If discarded, this product is considered a RCRA ignitable waste, D TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/configuration. U.S. Department of Transportation Ground (49 CFR) Proper shipping name: Solids containing flammable liquid, n.o.s. (Petroleum naphtha, TERTIARYBUTYL ACETATE) Hazard class or division: 4.1 Identification number: UN 3175 Packing group: II DOT Hazardous Substance(s): tert-butyl acetate International Air Transportation (ICAO/IATA) Proper shipping name: Solids containing flammable liquid, n.o.s. (Petroleum naphtha, TERTIARYBUTYL ACETATE) Hazard class or division: 4.1 Identification number: UN 3175 Packing group: II Water Transportation (IMO/IMDG) Proper shipping name: SOLIDS CONTAINING FLAMMABLE LIQUID, N.O.S. (Petroleum naphtha, TERTIARYBUTYL ACETATE) Hazard class or division: 4.1 Identification number: UN 3175 Packing group: II Marine pollutant: Petroleum naphtha Exceptions: Classified per IMDG Amendment 34; Effective Jan 1, United States Regulatory Information 15. REGULATORY INFORMATION TSCA 8 (b) Inventory Status: TSCA 12 (b) Export Notification: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. None above reporting de minimis CERCLA/SARA Section 302 EHS: CERCLA/SARA Section 311/312: CERCLA/SARA Section 313: CERCLA Reportable quantity: California Proposition 65: None above reporting de minimis. Immediate Health, Delayed Health, Fire None above reporting de minimis. tert-butyl acetate (CAS# ) 5,000 lbs. (2,270 kg) No California Proposition 65 listed chemicals are known to be present. No California Proposition 65 listed chemicals are known to be present. Canada Regulatory Information CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. 16. OTHER INFORMATION This safety data sheet contains changes from the previous version in sections: New Safety Data Sheet format. Page 5 of 6

6 Prepared by: Timothy Pratt, Regulatory Affairs Specialist Issue date: 05/22/2017 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates ( Henkel ) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user s responsibility to determine the suitability of Henkel s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Page 6 of 6