Revision Number: Issue date: 09/05/ PRODUCT AND COMPANY IDENTIFICATION. IDH number: HAZARDS IDENTIFICATION

Transcription

1 Safety Data Sheet Revision Number: Issue date: 09/05/ PRODUCT AND COMPANY IDENTIFICATION Product name: LOCTITE ABLESTIK 3888 PART-H known as 3888 Silver Electrically Cond E Product type: Epoxy Hardener Item number: 29840_209616H Restriction of Use: None identified Region: United States Company address: Henkel Corporation One Henkel Way Rocky Hill, Connecticut Contact information: Telephone: +1 (860) MEDICAL EMERGENCY Phone: Poison Control Center (toll free) or TRANSPORT EMERGENCY Phone: CHEMTREC (toll free) or Internet: 2. HAZARDS IDENTIFICATION DANGER: EMERGENCY OVERVIEW CAUSES SEVERE SKIN BURNS AND EYE DAMAGE. MAY CAUSE AN ALLERGIC SKIN REACTION. CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE. HAZARD CLASS HAZARD CATEGORY SKIN CORROSION 1B SERIOUS EYE DAMAGE 1 SKIN SENSITIZATION 1 SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE 1 PICTOGRAM(S) Precautionary Statements Prevention: Response: Storage: Disposal: Do not breathe vapors, mist, or spray. Wash affected area thoroughly after handling. Do not eat, drink or smoke when using this product. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves, clothing, eye and face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all contaminated clothing. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if you feel unwell. If skin irritation or rash occurs: Get medical attention. Wash contaminated clothing before reuse. Store locked up. Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations. Classification complies with OSHA Hazard Communication Standard (29 CFR ) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS). Page 1 of 6

2 See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Component(s) CAS Number Percentage* 3,3'-Oxybis(ethyleneoxy)bis(propylamine) Triethylenetetramine, propoxylated Triethylenetetramine Monoethanolamine ,4,6-Tris(dimethylaminomethyl)phenol Bis[(dimethylamino)methyl]phenol * Exact percentages may vary or are trade secret. Concentration range is provided to assist users in providing appropriate protections. 4. FIRST AID MEASURES Inhalation: Skin contact: Eye contact: Ingestion: Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Remove contaminated clothing and footwear. Immediately flush skin with plenty of water (using soap, if available). Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention. DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention. Symptoms: See Section FIRE FIGHTING MEASURES Extinguishing media: Special firefighting procedures: Unusual fire or explosion hazards: Hazardous combustion products: Water spray (fog), foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Personnel in vicinity and downwind should be evacuated. Burning produces obnoxious and toxic fumes. Ammonia. Oxides of carbon. Oxides of nitrogen. Nitric acid. Nitrosamines. Toxic fumes. Irritating vapors. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Clean-up methods: Do not allow product to enter sewer or waterways. Ensure adequate ventilation. Wear appropriate personal protective equipment. Refer to Section 8 "Exposure Controls / Personal Protection" prior to clean up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Scrape up spilled material and place in a closed container for disposal. Page 2 of 6

3 7. HANDLING AND STORAGE Handling: Storage: Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Use only with adequate ventilation. Keep container closed. Keep container tightly closed and in a cool, well-ventilated place away from incompatible materials. Keep away from heat, spark and flame. Store in original container until ready to use. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER 3,3'-Oxybis(ethyleneoxy)bis(propylamine) None None None None Triethylenetetramine, propoxylated None None None None 1 ppm (6 mg/m3) Triethylenetetramine None None TWA None (SKIN) Monoethanolamine 6 ppm STEL 3 ppm (6 mg/m3) 3 ppm TWA PEL None None 2,4,6-Tris(dimethylaminomethyl)phenol None None None None Bis[(dimethylamino)methyl]phenol None None None None Engineering controls: Respiratory protection: Eye/face protection: Skin protection: Use local ventilation if general ventilation is insufficient to maintain vapor concentration below established exposure limits. Use NIOSH approved respirator if there is potential to exceed exposure limit(s). Safety goggles or safety glasses with side shields. Full face protection should be used if the potential for splashing or spraying of product exists. Use chemical resistant, impermeable clothing including gloves and either an apron or body suit to prevent skin contact. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Liquid, Paste Color: Tan Odor: Ammoniacal Odor threshold: ph: > 8 Vapor pressure: Boiling point/range: > 100 C (> 212 F)1, hpa Melting point/ range: Specific gravity: 1.01 Vapor density: Flash point: > 93 C (> F) ; Estimated Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Autoignition temperature: Flammability: Not applicable Evaporation rate: Solubility in water: Slightly soluble Partition coefficient (n-octanol/water): VOC content: < 1 % (calculated) Viscosity: Decomposition temperature: Page 3 of 6

4 10. STABILITY AND REACTIVITY Stability: Hazardous reactions: Hazardous decomposition products: Incompatible materials: Reactivity: Conditions to avoid: Stable under normal conditions of storage and use. None under normal processing. Ammonia. Oxides of carbon. Oxides of nitrogen. Nitric acid. Nitrosamines. Toxic fumes. Irritating vapors. Oxidizing agents. Organic acids. Mineral acids. Nitrous acid and other nitrosating agents. Strong bases. Acrylates. copper Halogenated compounds. Ketones. Organic anhydrides. This product slowly corrodes copper, aluminum, zinc and galvanized surfaces. CAUTION! N- nitrosamines (many of which are known to be potent carcinogens) may be formed when the product comes in contact with nitrous acid, nitrites or atmospheres with high nitrous oxide concentrations. Keep away from heat, ignition sources and incompatible materials. 11. TOXICOLOGICAL INFORMATION Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion Potential Health Effects/Symptoms Inhalation: Skin contact: Eye contact: Ingestion: Mists, vapors or liquid may cause severe irritation or burns. Causes skin burns. May cause allergic skin reaction. Causes serious eye damage. If ingested, severe burns of the mouth and throat may occur, as well as perforation of the esophagus and the stomach. Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects 3,3'-Oxybis(ethyleneoxy)bis(propylamine) None Corrosive Triethylenetetramine, propoxylated None No Records Triethylenetetramine Monoethanolamine None Oral LD50 (Rat) = 10.2 g/kg Oral LD50 (Mouse) = 700 mg/kg Dermal LD50 (Rabbit) = 1,025 mg/kg Allergen, Corrosive, Developmental, Irritant, Mutagen Irritant, Kidney, Liver, Corrosive, Respiratory, Developmental 2,4,6-Tris(dimethylaminomethyl)phenol None Irritant, Allergen Bis[(dimethylamino)methyl]phenol None No Records Hazardous Component(s) NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) 3,3'-Oxybis(ethyleneoxy)bis(propylamine) No No No Triethylenetetramine, propoxylated No No No Triethylenetetramine No No No Monoethanolamine No No No 2,4,6-Tris(dimethylaminomethyl)phenol No No No Bis[(dimethylamino)methyl]phenol No No No 12. ECOLOGICAL INFORMATION Ecological information: Page 4 of 6

5 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Hazardous waste number: Follow all local, state, federal and provincial regulations for disposal. It is the responsibility of the user to determine if an item is hazardous as defined in the Resource Conservation and Recovery Act (RCRA) at the time of disposal. Product uses, transformations, mixtures, processes, etc., may render the resulting material hazardous, under the criteria of ignitability, corrosivity, reactivity and toxicity characteristics of the Toxicity Characteristics Leaching Procedure (TCLP) 40 CFR TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/configuration. U.S. Department of Transportation Ground (49 CFR) Proper shipping name: Amines, liquid, corrosive, n.o.s. (Polyglycol diamine, Triethylenetetramine) Hazard class or division: 8 Identification number: UN 2735 Packing group: II International Air Transportation (ICAO/IATA) Proper shipping name: Amines, liquid, corrosive, n.o.s. (Polyglycol diamine, Triethylenetetramine) Hazard class or division: 8 Identification number: UN 2735 Packing group: II Water Transportation (IMO/IMDG) Proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. (Polyglycol diamine, Triethylenetetramine) Hazard class or division: 8 Identification number: UN 2735 Packing group: II United States Regulatory Information 15. REGULATORY INFORMATION TSCA 8 (b) Inventory Status: TSCA 12 (b) Export Notification: CERCLA/SARA Section 302 EHS: CERCLA/SARA Section 311/312: CERCLA/SARA Section 313: California Proposition 65: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. None above reporting de minimis None above reporting de minimis. Immediate Health, Delayed Health None above reporting de minimis. This product contains a chemical known in the State of California to cause cancer. Canada Regulatory Information CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. 16. OTHER INFORMATION This safety data sheet contains changes from the previous version in sections: Prepared by: Product Safety and Regulatory Affairs Issue date: 09/05/2017 Page 5 of 6

6 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates ( Henkel ) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user s responsibility to determine the suitability of Henkel s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Page 6 of 6