MATERIAL SAFETY DATA SHEET

Transcription

1 MATERIAL SAFETY DATA SHEET SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: BUEHLER MASTERMET 2 IDENTIFICATION NUMBER: & PRODUCT USE/CLASS: Polishing Compound SUPPLIER: BUEHLER, a division of Illinois Tool Works Inc. 41 WAUKEGAN ROAD LAKE BLUFF, IL EMERGENCY: INFORMATION: PREPARER: Technical Department, PREPARE DATE: 03/19/2012, 19 March 2012 SECTION 2 COMPOSITION/INFORMATION ON INGREDIENTS ITEM CHEMICAL NAME CAS NUMBER WT/WT% 1 SiO 2 (amorphous silica) Sodium Dioxide Deionized Water Polyethylene Glycol Page 1 of 8

2 SECTION 2 COMPOSITION/INFORMATION ON INGREDIENTS ITEM ACGIH TLV- ACGIH TLV- OSHA PEL-TWA OSHA PEL COMPANY TLV- SKIN TWA STEL CEILING TWA 1 10 mg/m 3 N.E. 6 mg/m 3 N.E. N.E. No 2 5 mg/m 3 N.E. 10 mg/m 3 N.E. N.E. No 3 none N.E. none N.E. N.E. No 4 N.E. N.E. none N.E. N.E. No (SEE SECTION 16 FOR ABBREVIATION LEGEND) SECTION 3 HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: Not expected to present a hazard in normal industrial use. ACUTE EFFECTS EYE CONTACT: May cause irritation, tearing or blurred vision. ACUTE EFFECTS - SKIN CONTACT: Repeated or prolonged skin contact may cause irritation. It may dry your skin as it absorbs skin moisture. ACUTE EFFECTS INHALATION: Vapor and mist may irritate nose and throat. Prolonged inhalation may cause dizziness. ACUTE EFFECTS - INGESTION: May cause gastrointestinal irritation, dizziness, malaise, uremia, central nervous system depression, and kidney damage which may be fatal. Nausea and vomiting may occur. CHRONIC OVEREXPOSURE EFFECTS: Individuals with pre-existing skin disorders or eye problems or impaired liver or kidney function may be more susceptible to the effects of chemical. OTHER INFORMATION: Target Organs: Respiratory passages at high temperatures, eyes, skin. PRIMARY ROUTE(S) OF ENTRY: Inhalation at high temperatures, eye contact, skin contact. Page 2 of 8

3 SECTION 4 FIRST AID MEASURES EYE CONTACT: Flush thoroughly with water for at least 15 minutes. Get immediate medical attention. SKIN CONTACT: Remove contaminated clothing and shoes. Wash exposed area with soap and water. Get medical attention if symptoms persist. INHALATION: If symptoms develop, remove affected person from source of exposure into fresh air. Get immediate medical attention. If person is not breathing, give artificial respiration. If breathing is difficult, administer oxygen if available. INGESTION: Get immediate medical attention. Do not induce vomiting unless instructed to do so by a physician. Give large quantities of water or milk. NOTES TO PHYSICIAN: No Information. SECTION 5 FIRE FIGHTING MEASURES FLASH POINT: N.A. LOWER EXPLOSIVE LIMIT: N.A. UPPER EXPLOSIVE LIMIT: N.A. AUTOIGNITION TEMPERATURE: No data EXTINGUISHING MEDIA: Co2, Foam, Dry Chemical, Water Spray UNUSUAL FIRE AND EXPLOSION HAZARDS: Does not burn SPECIAL FIREFIGHTING PROCEDURES: Wear a NIOSH approved positive pressure self-contained breathing apparatus with full protective clothing. Do not release runoff from fire control methods to sewers or waterways. This product will not burn. Page 3 of 8

4 SECTION 6 ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: SMALL SPILLS: Isolate area and deny entry. Ventilate area of leak or spill. Small spill can be picked up with vermiculite or other absorbent, noncombustible material. Properly protected personnel should flush spill with plenty of water, taking care not to splash personnel. LARGE SPILLS: Notify appropriate personnel and implement facility emergency response plan. Evacuate nonessential personnel, isolate area, and provide maximum ventilation. Cleanup personnel should wear fully protective equipment for vapor inhalation and skin and eye contact. CONTAINMENT: For large spills, dike far ahead of liquid spill for later disposal. Wear protective equipment including rubber boots, rubber gloves, rubber apron and self-contained breathing apparatus. Do not release directly into sewers or waterways. Wash walking surfaces thoroughly to reduce slipping hazard. CLEAN UP: Absorb spilled liquid with non-reactive absorbent material. Place clean-up material in appropriate disposal containers and dispose of according to local, state and federal requirements. Regulatory Requirement: Any release to the environment of this product may be subject to federal, state, and/or local reporting requirements. Check with appropriate agencies. SECTION 7 HANDLING AND STORAGE HANDLING: Exercise ordinary care in handling industrial lubricants. Avoid contamination of cigarettes or other tobacco products. Wash hands thoroughly before eating or smoking. Remove contaminated clothing and wash before reuse. Avoid breathing dust and mists. Users should be alert to the possibility that very small percentages of the population may display unexpected allergic reactions to otherwise innocuous industrial lubricants and raw materials. STORAGE: Do not store in open or unlabeled containers. Store in well ventilated, properly drained/contained site, away from heat, out of the sun, and away from combustibles and reactive chemicals. Use only approved containers and protect containers from damage and keep material from freezing. Page 4 of 8

5 SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS: General ventilation usually adequate. RESPIRATORY PROTECTION: Avoid breathing in mist or dried dust. Respiratory protection is generally not necessary under normal conditions of use with adequate general ventilation. SKIN PROTECTION: Avoid skin contact. Wear chemical protective gloves. Depending upon conditions of use, additional protection may be necessary such as a face shield, apron, etc. EYE PROTECTION: Avoid eye contact. Wear safety glasses or chemical goggles. OTHER PROTECTIVE EQUIPMENT: Make emergency eyewash stations, safety/quick-drench showers, and washing facilities available in work area. HYGIENIC PRACTICES: Never eat, drink, or smoke in work areas. Practice good personal hygiene after using this material. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES BOILING RANGE: 100ºC (212 VAPOR DENSITY: Unknown 760mm HG ODOR: slight amine or ammonia ODOR THRESHOLD: No data odor APPEARANCE: White Liquid EVAPORATION RATE: Water SOLUBILITY IN H 2 O: 100 WT% FREEZE POINT: < 32 deg F SPECIFIC GRAVITY: VAPOR PRESSURE: 24 25ºC (77ºF) 0.0%: No data PHYSICAL STATE: Liquid VISCOSITY: Low COEFFICIENT OF WATER/OIL DISTRIBUTION: No data (SEE SECTION 16 FOR ABBREVIATION LEGEND) Page 5 of 8

6 SECTION 10 STABILITY AND REACTIVITY CONDITIONS TO AVOID: Strong acids and bases. Heat source. Freezing conditions. INCOMPATIBILITY: Strong oxidizing materials, hypochlorites, chlorine. HAZARDOUS DECOMPOSITION PRODUCTS: Steam, CO2, CO and unidentified organic compounds in fumes and smoke may be formed during combustion. HAZARDOUS POLYMERIZATION: This product will not undergo hazardous polymerization. STABILITY: Stable at room temperature in closed containers under normal storage and handling conditions. SECTION 11 TOXICOLOGICAL PROPERTIES Eye Effect: Eye Irritant. Moderately irritating to eyes. Skin Effect: May cause moderate irritation. Dries skin. Reproductive: Considered to be secondary to maternal toxicity in animals. Ingestion Effect: Can cause kidney damage. Acute Inhalation Effects: Expected to be low toxicity: LC50 >150 mg/l Rat Acute Oral Effects: Low toxicity: LD50 > 10,000 mg/kg, Rat Chronic Effects: Not established. Carcinogenicity: Not carcinogenic in animal studies Mutagenicity: No evidence of mutagenic activity. Teratogenicity: Not reported ECOLOGICAL TEST DATA: Ecotoxicity: N/A Soil Absorption/Mobility: Disperses in water. Degradability: N/A Environmental Fate and Effects: Not Available SECTION 12 ECOLOGICAL INFORMATION SECTION 13 DISPOSAL CONSIDERATIONS DISPOSAL METHOD: Contact a licensed waste-disposal contractor for detailed recommendations. Follow applicable federal, state, and local regulations. Container Disposal: Rinse three times with an appropriate solvent or water. Dispose or recycle the empty container. Disposal Regulatory Requirements: Many states classify waste lubricants as hazardous, which means disposal only by a licensed firm. Follow applicable federal, state, and local regulations Page 6 of 8

7 DOT PROPER SHIPPING NAME: Not regulated SECTION 14 TRANSPORTATION INFORMATION DOT TECHNICAL NAME: N.A. DOT HAZARD CLASS: N.A. DOT UN/NA CLASS: N.A. HAZARD SUBCLASS: N.A. PACKAGING GROUP: N.A. RESP. GUIDE PAGE: INTERNATIONAL SHIPPING NAME: Not regulated INTERNATIONAL ID NUMBER: N.A. IMDG CLASS (1, 2 ): N.A. IMDG EMS: N.A. IMDG PAGE NUMBER: N.A. IATA CLASS (1, 2 ): N.A. SECTION 15 REGULATORY INFORMATION OSHA: Non-hazardous by definition of Hazard Communication Standard (29 CFR ) CERCLA SARA HAZARD CATEGORY: THIS PRODUCT HAS BEEN REVIEWED, AND IS CONSIDERED, UNDER APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES: NONE SARA SECTION 313: THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 AND 40 CFR PART 372: CHEMICAL NAME CAS NUMBER WT/WT % IS LESS THAN No SARA Section 313 components exist in this product. TOXIC SUBSTANCE CONTROL ACT: THE CHEMICAL SUBSTANCES IN THIS PRODUCT ARE ON THE TSCA SECTION 8 INVENTORY. THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL SUBSTANCES SUBJECT TO THE REPORTING REQUIREMENTS OF TSCA 12(B) IF EXPORTED FROM THE UNITED STATES: CHEMICAL NAME CAS NUMBER No components found. NEW JERSEY RIGHT-TO-KNOW: THE FOLLOWING MATERIALS ARE NON-HAZARDOUS, BUT ARE AMONG THE TOP 5 COMPONENTS IN THIS PRODUCT: CHEMICAL NAME CAS NUMBER Water Amorphous silicon dioxide Page 7 of 8

8 SECTION 15 REGULATORY INFORMATION PENNSYLVANIA RIGHT-TO-KNOW: THE FOLLOWING NON-HAZARDOUS INGREDIENTS ARE PRESENT IN THE PRODUCT AT GREATER THAN 3%: CHEMICAL NAME CAS NUMBER Water Amorphous silicon dioxide CALIFORNIA PROPOSTION 65: No Proposition 65 chemicals known to exist in this product. CANADIAN WHMIS: THIS MSDS HAS BEEN PREPARED IN COMPLIANCE WITH CONTROLLED PRODUCT REGULATIONS EXCEPT FOR USE OF THE 16 HEADINGS. CANADIAN WHMIS CLASS: None COMPONENT RCRA CLASSIFICATIONS: No information COMPONENT RCRA CODES: No information CERCLA RQ VALUE (MINIMUM): No information SECTION 16 OTHER INFORMATION HMIS RATINGS HEALTH: 0 FLAMMABILITY: 0 REACTIVITY: 0 PREVIOUS MSDS REVISION DATE: 03/23/2009, 23 March 2009 REASON FOR REVISION: Administrative change for new format. Revised section(s):2,3,4,5,6,7,8,9,10,11,12,13 VOLATILE ORGANIC COMPOUNDS: 0 grams/ltr LEGEND: N.A. NO INFORMATION N.E. NOT ESTABLISHED N.D. NOT DETERMINED ABBREVIATIONS: ACGIH = AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS; OSHA = OCCUPATIONAL HEALTH AND SAFETY ADMINISTRATION; TLV-TWA = THRESHOLD LIMIT VALUE TIME WEIGHTED AVERAGE (8 HOURS); STEL = SHORT-TERM EXPOSURE LIMIT (15 MINUTES); C = CEILING VALUE; PEL = PERMISSIBLE EXPOSURE LIMIT DISCLAIMER: TO THE BEST OF OUR KNOWLEDGE, THE INFORMATION CONTAINED IN THIS MSDS IS ACCURATE OR IS OBTAINED FROM SOURCES BELIEVED TO BE ACCURATE. HOWEVER, NO LIABILITY, EXPRESSED OR IMPLIED, IS ASSUMED FOR THE ACCURACY OR COMPLETENESS OF THE INFORMATION CONTAINED HEREIN. BUYER ASSUMES LIABILITY IN ITS USE OF THE MATERIAL. Page 8 of 8