Prior Issue Date: 18 March, 2015 Revision Date: 11 June, 2015 Version 2 1. IDENTIFICATION 2. HAZARDS IDENTIFICATION

Transcription

1 Safety Data Sheet Prior Issue Date: 18 March, 2015 Revision Date: 11 June, 2015 Version 2 1. IDENTIFICATION Product Identifier Product Name Other means of identification SDS # Product Code UN/ID No NON SILICA PARTING SDMNONSIL_ MABNONSIL, P1000 Recommended use of the chemical and restrictions on use Recommended Use: Foundry pattern parting compound. Details of the supplier of the safety data sheet Supplier Address REFCOTEC, Inc 542 Collins Blvd Orrville, OH Emergency Telephone Number Company Phone Number Information Calls: Fax Number: Emergency Telephone (24 hr) INFOTRAC (International) (North America) Appearance White powder. Physical State Solid Odor None. Classification Serious eye damage/eye irritation Category 2 Specific target organ toxicity (single exposure) Category 3 Carcinogenic (crystalline silica) Category 1A Hazards Not Otherwise Classified (HNOC) None known. 2. HAZARDS IDENTIFICATION Signal Word Danger Hazard Statements Prolonged or repeated exposure may cause respiratory damage or illness. Causes serious eye irritation May cause respiratory irritation. Page 1 of 7

2 Precautionary Statements- Prevention Wash face, hands and any exposed skin thoroughly after handling Avoid breathing dust/mist/spray Use only outdoors or in a well-ventilated area No smoking, eating, or drinking while using. Keep container tightly closed Wear protective gloves/protective clothing/eye protection/face protection Precautionary Statements - Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF ON SKIN (or hair): Remove contaminated clothing. Rinse skin with water/shower IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. IN CASE OF FIRE: This product will not support combustion. Precautionary Statements - Storage Store in a well-ventilated place. Keep container tightly closed. Precautionary Statements - Disposal This product does not meet the criteria to be classified as hazardous waste. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% Talc (non-asbestiform) **If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.** First Aid Measures Eye Contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin Contact Inhalation Ingestion IF ON SKIN (or hair): Remove and launder contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison center or doctor/physician if you feel unwell. Do not induce vomiting. Seek medical attention/advice. Most important symptoms and effects Symptoms Causes serious eye irritation. May cause respiratory irritation. Overexposure may cause coughing, shortness of breath, dermatitis. Indication of any immediate medical attention and special treatment needed Page 2 of 7

3 Notes to Physician Pre-existing respiratory or dermal conditions may be aggravated by overexposure. Suitable Extinguishing Media Not flammable or combustible. Unsuitable Extinguishing Media. Specific Hazards Arising from the Chemical None known. Hazardous Combustion Products None. 5. FIRE-FIGHTING MEASURES Sensitivity to Static Discharge Protective equipment and precautions for firefighters Personal precautions, protective equipment and emergency procedures Personal Precautions Environmental Precautions Use personal protective equipment as required. Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information. See Section 13: DISPOSAL CONSIDERATIONS. Methods and material for containment and cleaning up Methods for Containment Methods for Clean-Up Precautions for safe handling Advice on Safe Handling Sweep or vacuum up spills. Do not flush spills to watercourse. Place unusable material into lidded containers for disposal. Handle in accordance with good industrial hygiene and safety practice. Avoid contact with or eyes. Wash face, hands, and any exposed skin thoroughly after handling. Avoid breathing dust. Keep container tightly closed when it isn t in use. Wear protective gloves/protective clothing and eye/face protection. Do not reuse this container. Dispose of or send to an approved reconditioner for recycling. Storage Conditions Incompatible Materials No specific storage conditions are recommended, other than keep material dry. Strong acids. Flourine. Exposure Guidelines 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Talc TWA: 2 mg/m 3 respirable TWA: 2 m3/m fraction. Respirable fraction. Page 3 of 7

4 TWA: mg/m 3 respirable fraction (vacated) TWA: 0.1 mg/m 3 respirable dust : (30)/(%SiO2 + 2) mg/m 3 TWA total dust : (250)/(%SiO2 + 5) mppcf TWA respirable fraction : (10)/(%SiO2 + 2) mg/m 3 TWA respirable fraction IDLH: 50 mg/m 3 respirable dust TWA: 0.05 mg/m 3 respirable dust Appropriate engineering controls Engineering Controls Ensure adequate ventilation, especially in confined areas. Local exhaust ventilation recommended. Use mechanical ventilation if TLV(s) for dust is expected to be exceeded. Eyewash stations. Showers. Individual protection measures, such as personal protective equipment Eye/Face Protection Skin and Body Protection Respiratory Protection Safety goggles/glasses. Gloves and aprons. NIOSH approved for mineral dusts. Air purifying or SCBA if TLVs for vapors are exceeded. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Information on basic physical and chemical properties 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Powder Appearance Fine white powder. Odor None Color White Odor Threshold Property ph Melting Point/Freezing Point Boiling Point/Boiling Range Flash Point Evaporation Rate Flammability (Solid, Gas) Upper Flammability Limits Lower Flammability Limit Vapor Pressure Vapor Density Specific Gravity Water Solubility Solubility in strong acids Partition Coefficient Auto-ignition Temperature Decomposition Temperature Kinematic Viscosity Dynamic Viscosity Explosive Properties Oxidizing Properties VOC Content Density Values Liquid-Not Applicable 12 Nil. Not soluble. Partially None. Remarks Method 10. STABILITY AND REACTIVITY Page 4 of 7

5 Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization Hazardous polymerization does not occur. Conditions to Avoid High heat, spark, and open flames. Static discharge. Ignition sources. Keep out of reach of children. Incompatible Materials Strong acids. Fluorine. Hazardous Decomposition Products Oxides of carbon. Information on likely routes of exposure Product Information 11. TOXICOLOGICAL INFORMATION Eye Contact Skin Contact Inhalation Ingestion Causes serious eye irritation. Avoid contact with skin. May cause respiratory irritation. May be harmful if swallowed. Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 = 500 mg/kg ( Rat ) - - Information on physical, chemical and toxicological effects Symptoms Please see section 4 of this SDS for symptoms. Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity Crystalline Silica is considered to be a human carcinogen when in respirable form (dust / powder). Chemical Name ACGIH IARC NTP OSHA A2 Group 1 Known X Legend ACGIH (American Conference of Governmental Industrial Hygienists) A2 - Suspected Human Carcinogen IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans Group 3 IARC components are "not classifiable as human carcinogens" NTP (National Toxicology Program) Known - Known Carcinogen Page 5 of 7

6 OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present STOT - single exposure May cause respiratory irritation. Numerical measures of toxicity Eco toxicity May cause long lasting harmful effects to aquatic life. Component Information None known. Persistence/Degradability. Bioaccumulation. Mobility No known information. Other Adverse Effects Waste Treatment Methods Disposal of Wastes Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. Disposal should be in accordance with applicable regional, national and local laws and regulations. Note DOT UN/ID No 14. TRANSPORT INFORMATION Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances. Not rated. International Inventories Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations Page 6 of 7

7 SARA 311/312 Hazard Categories Acute Health Hazard Chronic Health Hazard Fire Hazard SARA 313 Not listed. Yes Yes No US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals. Chemical Name California Proposition 65 - Carcinogen U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania X X X 16. OTHER INFORMATION Prior Issue Date: 18 March, 2015 Revision Date: 11 June, 2015 Revision Note: Minor editorial changes. Disclaimer The foregoing data has been compiled from sources which REFCOTEC, in good faith, believes to be dependable, accurate, and reliable to the best of our knowledge. However, REFCOTEC cannot make any warranty or representation respecting the accuracy or completeness of the data and assumes no responsibility for any liability or damages relating thereto. REFCOTEC cannot advise you regarding the protection of your employees, customers, or others. Users may consult OSHA. End of Safety Data Sheet Page 7 of 7