Braking Health & Safety

Transcription

1 01. Identification of the substance / preparation and of the company Product: Use: Company: Phone: Fax: Emergency phone: Lucas Brake Fluid TRW KFZ Ausrüstung GmbH, RudolfDieselStr. 7, D56566 Neuwied (+49) (+49) (+44) NHS Composition / Information on ingredients Substance EINECS CAS Range [%] Symbol / Rphr. 2(2(2Butoxyethoxy)ethoxy)ethanol <40 Xi 36 2(2Methoxyethoxy)ethanol < = 1 Xn 63 22'Oxydiethanole <25 Xn 22 Tributylamine ,1<1 T 2223/ Hazards identification 04. First aid measures General information Inhalation Skin contact Eye contact Ingestion Advice to doctor 05. Firefighting measures 06. Accidental release measures Change soaked clothing. Ensure supply of fresh air. In the event of symptoms refer for medical treatment. When in contact with the skin, clean with soap and water. Consult a doctor if skin irritation persists. In case of contact with eyes rinse thoroughly with plenty of water and seek medical advice. Do not induce vomiting. Rinse out mouth and give plenty of water to drink. Refer for medical treatment. If swallowed or in the event of vomiting, risk of product entering the lungs. Suitable extinguishing media Water spray jet. Dry powder. Foam. Carbon dioxide. Extinguishing media that Full water jet. must not be used Special exposure hazards Risk of formation of toxic pyrolysis products. arising from the substance or preparation itself or combustion products Special protective Use selfcontained breathing apparatus. equipment for firefighters Additional information Fire residues and contaminated firefighting water must be disposed of in accordance with the local regulations. Personal precautions Environmental precautions Methods for cleaning up/taking up High risk of slipping due to leakage/spillage of product. Keep away sources of ignition. Do not discharge into the drains/ surface waters/ groundwater. Take up with absorbent material (e.g. sand, sawdust, generalpurpose binder). Dispose of absorbed material in accordance with the regulations. 07. Handling and storage Advice on safe handling Advice on protection against fire and explosion Requirements for storage rooms and vessels Use only in wellventilated areas. Keep away from sources of ignition. Prevent penetration into the ground.

2 08. Exposure controls / personal protection Additional advice on system design Ensure adequate ventillation on workstation. Ingredients with occupational exposure limits to be monitored Substance CAS Value: 22'Oxydiethanole MAK: 10 ppm Y, 2000 Respiratory protection Breathing apparatus in the event of high concentrations. Short term: filter apparatus, Filter A. Hand protection Suitable protective gloves: Butyl rubber, >480 min (EN 374) Eye protection Safety glasses. Skin protection General protective measures Avoid contact with eyes and skin. Do not inhale gases/vapours/aerosols. Hygiene measures Wash hands before breaks and after work. Use barrier skin cream. At work do not eat, drink, smoke or take drugs. Limitation and controlling of the environment pollution 09. Physical and chemical properties Form: Colour: Odour: phvalue: Boiling point [ C]: Flash point [ C]: Flammability: Lower explosion limit: Upper explosion limit: Combustible properties: 10. Stability and reactivity Hazardous reactions Hazardous decomposition products 11. Toxicological information Acute oral toxicity Acute dermal toxicity Acute inhalational toxicity Irritant effect on eye Sensitization / Validation Chronic toxicity / Validation Mutagenicity / validation Reproduction toxicity / Validation Carcinogenicity / Validation Experiences made in practice General remarks Liquid. Clear. Perceptible. 710,5 260 >80 No Reactions with strong oxidizing agents. Vapour pressure [kpa]: Density [g/ml]: Solubility in water: Partition coefficient: noctanol / water: Viscosity: Relative vapour density determined in air Speed of evaporation: Melting point [ C]: No hazardous decomposition products known. LD50 Rat : >5000 mg/kg LD50 Rabbit : LC50 Rat : None. Autoignition temperature: < 2 mbar (20 C) 1,05 Partially miscible cst (20 C) <50 >300 The product was classified on the basis of the calculation procedure of the preparation directive.

3 12. Ecological information Biodegradable Fish toxicity Behaviour in environment compartments Behaviour in sewage plant AOXadvice General information Contains compounds of 76/464/EC 13. Disposal considerations Disposal / Product Waste no. (recommended) * Disposal / Contaminated packaging 14. Transport information 14.1 Classification according to ADR: ADR: Factor, ADR : Hazardno: 14.2 Classification according to IMDG: IMDGCode: 14.3 Classification according to IATA: IATADGR: No dangerous components. Do not allow to enter soil, waterways or waste water. Dispose of as hazardous waste. Disposal in an incineration plant in accordance with the regulations of the local authorities. Uncontaminated packaging may be taken for recycling. Packaging that cannot be cleaned should be disposed of as for product. ADRConditions for limited quantities(lq): Inner packing, max.: Total gross mass of a package: Inner packing, max.: Total gross mass of a package: IMDGConditions for limited quantities(lq): trw00018 Page 3 of 4

4 15. Regulatory information The product is classified and labelled in accordance with EC directives Hazard symbols Irritant S2: Keep out of the reach of children. S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S46: If swallowed, seek medical advice immediately and show this container or label. Special labelling for certain preparations National regulations 16. Other informations R phrases (Substance) R22: Harmful if swallowed. R23/24: Toxic by inhalation and in contact with skin. R38: Irritating to skin. R63: Possible risk of harm to the unborn child. * 91/155 (2001/58) * 67/548 (2001/59) * 1999/45 (2001/60) * 91/689 (2001/118) * 89/542 * ADR ( ) * IMDGCode (30.Amdt.) * IATADGR (2002) * Classification according to VbF * Water hazard class Modified position:

5 KennzeichnungsVorlage für private Anwender gb / en Irritant S2: Keep out of the reach of children. S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S46: If swallowed, seek medical advice immediately and show this container or label. [Verpackungsgröße(n)] TRW KFZ Ausrüstung GmbH D56566 Neuwied RudolfDieselStr. 7 Telefon: (+49) Verpackungs Größe 5l(XRB236D(D)) 5l(XRB236D(EN)) mindest Kennzeichnungsformat Ausführungshinweise zur Kennzeichnung gem. EU RL Symbolgröße kinderges. Verschluss ertastbarer Warnhinweis 74mm x 105mm nicht relevant keiner keiner 74mm x 105mm 27,9mm x 27,9mm (777mm²) keiner keiner 74mm x 105mm 27,9mm x 27,9mm (777mm²) keiner keiner Kostenfreie Hotline bei Rückfragen zur Etikettengestaltung Telefon Druckdatum: Aktualisierungsstand: ChemieBüro D.G.Schröder St.Kassiansplatz 6 D93047 Regensburg Tel. (0049) Fax. (0049) , info@chemiebuero.de #Name? Seite 1 von 1 trw00018