: Sodium Borate, 40 g/l
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1 Date of issue: 01/10/2014 Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Product name Product code : Mixture : Sodium Borate, 40 g/l : LC Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : For laboratory and manufacturing use only Details of the supplier of the safety data sheet LabChem Inc Jackson's Pointe Commerce Park Building 1000, 1010 Jackson's Pointe Court Zelienople, PA USA T F info@labchem.com Emergency telephone number Emergency number : CHEMTREC: or SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Repr. 1B H Label elements GHS-US labelling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) GHS08 : Danger : H360 - May damage fertility or the unborn child : P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P280 - Wear protective gloves, eye protection P308+P313 - IF exposed or concerned: Get medical advice/attention P405 - Store locked up P501 - Dispose of contents/container to comply with local, state and federal regulations 2.3. Other hazards Other hazards not contributing to the classification 2.4. Unknown acute toxicity (GHS-US) No data available : None under normal conditions. SECTION 3: Composition/information on ingredients 3.1. Substance Full text of H-phrases: see section Mixture Name Product identifier % GHS-US classification Water (CAS No) Not classified Sodium Tetraborate Decahydrate (CAS No) Repr. 1B, H360 01/10/2014 EN (English) Page 1
2 Name Product identifier % GHS-US classification Sodium Hydroxide (CAS No) Acute Tox. 4 (Dermal), H312 Skin Corr. 1A, H314 Eye Dam. 1, H318 Aquatic Acute 3, H402 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. IF exposed or concerned: Get medical advice/attention. : Assure fresh air breathing. Allow the victim to rest. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Most important symptoms and effects, both acute and delayed Symptoms/injuries : May damage fertility or the unborn child Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream Special hazards arising from the substance or mixture 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Avoid (reject) fire-fighting water to enter environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Protective equipment Emergency procedures For emergency responders Protective equipment Emergency procedures : Safety glasses. Gloves. : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Do not handle until all safety precautions have been read and understood. Obtain special instructions before use. 01/10/2014 EN (English) 2/7
3 7.2. Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials 7.3. Specific end use(s) : Keep container closed when not in use. : Strong oxidizers. Strong acids. SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Sources of ignition. Direct sunlight. USA ACGIH ACGIH TWA (mg/m³) 2 mg/m³ USA ACGIH ACGIH STEL (mg/m³) 6 mg/m³ USA ACGIH ACGIH Ceiling (mg/m³) 2 mg/m³ USA OSHA OSHA PEL (TWA) (mg/m³) 2 mg/m³ 8.2. Exposure controls Appropriate engineering controls Personal protective equipment Hand protection Eye protection Respiratory protection : Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Ensure adequate ventilation. : Avoid all unnecessary exposure. : Wear protective gloves. : Chemical goggles or safety glasses. : Wear appropriate mask. : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour : Colourless. Odour : None. Odour threshold ph : 9.5 Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point Self ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Density : 1 g/ml Solubility : Soluble in water. Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 01/10/2014 EN (English) 3/7
4 9.2. SECTION 10: Stability and reactivity Reactivity Chemical stability Stable under normal conditions Possibility of hazardous reactions Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Strong acids. Strong oxidizers Hazardous decomposition products boron. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LD50 oral rat LD50 dermal rabbit LD50 oral rat LD50 dermal rabbit Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) 2660 mg/kg mg/kg mg/kg 1350 mg/kg (Rabbit; Literature,Rabbit; Literature) ph: 9.5 ph: 9.5 : May damage fertility or the unborn child. Specific target organ toxicity (repeated exposure) Aspiration hazard Potential Adverse human health effects and symptoms Likely routes of exposure : Based on available data, the classification criteria are not met. : Skin and eyes contact SECTION 12: Ecological information Toxicity EC50 Daphnia mg/l LC50 fishes mg/l (96 h; Salmo gairdneri (Oncorhynchus mykiss); Solution >=50%) 01/10/2014 EN (English) 4/7
5 EC50 Daphnia 1 LC50 fish 2 TLM fish 1 TLM fish mg/l (48 h; Ceriodaphnia sp.; Nominal concentration) 189 mg/l (48 h; Leuciscus idus) 99 mg/l (48 h; Lepomis macrochirus) 125 ppm (96 h; Gambusia affinis) Sodium Borate, 40 g/l Biochemical oxygen demand (BOD) Chemical oxygen demand (COD) ThOD BOD (% of ThOD) Biodegradability: not applicable. No (test)data on mobility of the substance available Sodium Borate, 40 g/l Bioaccumulation: not applicable Mobility in soil Other adverse effects : Avoid release to the environment. SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations Ecology - waste materials SECTION 14: Transport information : Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to comply with local, state and federal regulations. : Avoid release to the environment. In accordance with DOT No dangerous good in sense of transport regulations Additional information : No supplementary information available. ADR Transport document description : Transport by sea Air transport 01/10/2014 EN (English) 5/7
6 SECTION 15: Regulatory information US Federal regulations Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on the United States TSCA (Toxic Substances Control Act) inventory RQ (Reportable quantity, section 304 of EPA's 1000 lb List of Lists) : SARA Section 311/312 Hazard Classes Immediate (acute) health hazard International regulations CANADA Sodium Borate, 40 g/l Class D Division 2 Subdivision A - Very toxic material causing other toxic effects Listed on the Canadian DSL (Domestic Sustances List) inventory. Class D Division 2 Subdivision A - Very toxic material causing other toxic effects Uncontrolled product according to WHMIS classification criteria Listed on the Canadian DSL (Domestic Sustances List) inventory. Class E - Corrosive Material EU-Regulations Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC or 1999/45/EC Not classified National regulations Listed on the Canadian Ingredient Disclosure List Listed on the Canadian Ingredient Disclosure List US State regulations SECTION 16: : None. Full text of H-phrases: see section 16: Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category Aquatic Acute 3 Hazardous to the aquatic environment AcuteHazard, Category 3 01/10/2014 EN (English) 6/7
7 Eye Dam. 1 Serious eye damage/eye irritation, Category Repr. 1B Reproductive toxicity, Category 1B Skin Corr. 1A Skin corrosion/irritation, Category 1A H312 Harmful in contact with skin H314 Causes severe skin burns and eye damage H318 Causes serious eye damage H360 May damage fertility or the unborn child H402 Harmful to aquatic life NFPA health hazard NFPA fire hazard NFPA reactivity : 2 - Intense or continued exposure could cause temporary incapacitation or possible residual injury unless prompt medical attention is given. : 0 - Materials that will not burn. : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. HMIS III Rating Health Flammability Physical Personal Protection : 2 Moderate Hazard - Temporary or minor injury may occur : 0 Minimal Hazard : 0 Minimal Hazard : B SDS US (GHS HazCom 2012) Information in this SDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc assumes no liability resulting from the use of this SDS. The user must determine suitability of this information for his application. 01/10/2014 EN (English) 7/7
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