Structural Adhesive-Urethane (45 seconds) Part 2. Chemical Name CAS# Ingredient Percent. Methylene Bisphenyl Isocyanate by weight

Transcription

1 MSDS Name Manufacturer Name Saint-Gobain Abrasives, Inc. Stock No Kit MSDS Revision Date 07/01/2013 Components Part 1 Part 2 Saint-Gobain Abrasives, Inc. Product Code : SECTION 1 : PRODUCT AND COMPANY IDENTIFICATION Product Name: Part 1 Product Code: 97122A SDS Manufacturer 97122A Manufacturer Name: Saint-Gobain Abrasives, Inc. Address: 1 New Bond Street Worcester, MA General Phone Emergency Phone Website: HMIS Health Hazard 2* Fire Hazard 1 Reactivity 1 Personal Protection X * Chronic Health Effects SECTION 2 : COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS# Ingredient Percent Methylene Bisphenyl Isocyanate by weight SECTION 3 : HAZARDS IDENTIFICATION Emergency Overview: Route of Exposure: Potential Health Effects: WARNING! Potential Sensitizer. Irritant. Eyes. Skin. Inhalation. Ingestion. May result in skin irritation. May irritate the respiratory tract, sore throat, choking and tightness of chest. MDI is a respiratory sensitizer. None reported. Not likely a source of entry. SECTION 4 : FIRST AID MEASURES Eye Contact: Skin Contact: Immediately flush eyes with plenty of water for at least 15 to 20 minutes. Hold eyelids open during flushing. Get immediate medical attention. Clean exposed skin with a clean cloth followed by isopropanol, soap and water for 15 to 20 minutes, while removing contaminated clothing and shoes. Get medical attention if irritation develops or persists. If inhaled, remove to fresh air. If not breathing, give artificial respiration or give oxygen by trained personnel. Seek immediate medical attention. If swallowed, do NOT induce vomiting. If victim is alert, rinse mouth and give one glass of water of milk to dilute material (never give anything by mouth to an unconscious person). Call a physician or poison control center immediately. SECTION 5 : FIRE FIGHTING MEASURES 491 F (255 C) Auto Ignition Temperature: 600 C Lower Flammable/Explosive Upper Flammable/Explosive Extinguishing Media: AFFF foam, carbon dioxide, dry chemical and water Hazardous Combustion May produce traces of hydrogen cyanide.

2 Hazardous Combustion Byproducts: May produce traces of hydrogen cyanide. SECTION 6 : ACCIDENTAL RELEASE MEASURES Spill Cleanup Measures: Other Precautions: Cover spills with inert absorbent material. Wear full protective equipment and saturate spill with neutralizing solution (1% ammonia in water + 10% isopropanol in water) and then ventilate the area. Pump or shovel to storage/salvage vessels. SECTION 7 : HANDLING and STORAGE Handling: Storage: Hygiene Practices: General ventilation is adequate; however, local exhaust ventilation is recommended. Store in a cool, dry, well ventilated area away from heat, sparks and flames. Keep container tightly closed when not in use. Wash thoroughly after handling. SECTION 8 : EXPOSURE CONTROLS, PERSONAL PROTECTION - EXPOSURE GUIDELINES Eye/Face Protection: Wear appropriate protective glasses or splash goggles as described by 29 CFR , OSHA eye and face protection regulation, or the European standard EN 166. EXPOSURE GUIDELINES Methylene Bisphenyl Isocyanate: Guideline ACGIH: ACGIH TLV-TWA ppm Guideline OSHA: OSHA PEL-STEL 0.02 ppm Ceiling/Peak SECTION 9 : PHYSICAL and CHEMICAL PROPERTIES Physical State Appearance: clear liquid Color: amber Odor: Odorless. Odor Threshold: 0.005ppm Boiling Point: 473 F(245 C) Melting Point: Specific Gravity: 1.22 g/ml Solubility: negligible. Vapor Density: Vapor Pressure: mm 20 C Evaporation Rate: negligible. Viscosity: cps 491 F (255 C) Auto Ignition Temperature: 600 C VOC Content: SECTION 10 : STABILITY and REACTIVITY Chemical Stability: Hazardous Polymerization: Conditions to Avoid: Stable under normal temperatures and pressures. Not reported. Extreme heat, sparks, and open flame. Incompatible materials, oxidizers and oxidizing conditions. SECTION 11 : TOXICOLOGICAL INFORMATION Methylene Bisphenyl Isocyanate: Eye: Eye - Rabbit Standard Draize test. : 100 mg - [Moderate ](RTECS) Skin - Rabbit Standard Draize test. : 500 mg/24h(rtecs) Inhalation - Rat LC50: 178 mg/m3 - [Details of toxic effects not reported other than lethal dose value] (RTECS) Oral - Rat LD50: 9200 mg/kg - [oral - Somnolence (general depressed activity) oral - Ataxia Nutritional and Gross Metabolic - body rat decrease ] (RTECS) Oral - Mouse LD50: 2200 mg/kg - [Details of toxic effects not reported other than lethal dose value ] (RTECS) LD50: (Dermal, rabbit) = 9g/kg LD50: (Oral, rat) = 5803mg/kg SECTION 12 : ECOLOGICAL INFORMATION

3 Ecotoxicity: Environmental Fate: No ecotoxicity data was found for the product. No environmental information found for this product. SECTION 13 : DISPOSAL CONSIDERATIONS Waste Disposal: RCRA In accordance with local, provincial and federal regulations. None. SECTION 14 : TRANSPORT INFORMATION DOT Shipping Name: DOT UN Non regulated. Non regulated. SECTION 15 : REGULATORY INFORMATION Methylene Bisphenyl Isocyanate : TSCA Inventory Status: Listed SARA: EPCRA - 40 CFR Part (SARA Title III) Section 313 Listed Chemical. State Regulations: Listed in the State of Massachusetts Hazardous Substance List. Listed in the New Jersey State Right to Know List. Listed in the Pennsylvania State Hazardous Substances List. EC Canada WHMIS: D-1A, D-2A, D-2B SECTION 16 : ADDITIONAL INFORMATION HMIS Fire Hazard: 1 HMIS Health Hazard: 2* HMIS Reactivity: 1 HMIS Personal Protection: X Copyrightï ½ Actio Software Corporation. All Rights Reserved. SECTION 1 : PRODUCT AND COMPANY IDENTIFICATION Product Name: Part 2 Product Code: 97122B SDS Manufacturer 97122B Manufacturer Name: Saint-Gobain Abrasives, Inc. Address: 1 New Bond Street Worcester, MA General Phone Emergency Phone Website: HMIS Health Hazard 3 Fire Hazard 1 Reactivity 1 Personal Protection X * Chronic Health Effects SECTION 2 : COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS# Ingredient Percent Modified Polyaliphatic Amine PROPRIETARY by weight Diethyltoluene diamine by weight Dimethyl thio-toluene diamine (DMTDA) by weight SECTION 3 : HAZARDS IDENTIFICATION Emergency Overview: Route of Exposure: Potential Health Effects: WARNING! Potential Sensitizer. Irritant. Eyes. Skin. Inhalation. Ingestion. Causes severe irritation and defatting of the skin.

4 May cause irritation to the respiratory tract and mucous membranes of the mouth, nose and throat. Coughing, nausea, vomiting and chest pain may result. May result in irritation of the mouth, throat, esophagus and stomach. SECTION 4 : FIRST AID MEASURES Eye Contact: Immediately flush eyes with plenty of water for at least 15 to 20 minutes. Hold eyelids open during flushing. Get immediate medical attention. Skin Contact: Immediately wash skin with plenty of soap and water for 15 to 20 minutes, while removing contaminated clothing and shoes. Get medical attention if irritation develops or persists. If inhaled, remove to fresh air. If not breathing, give artificial respiration or give oxygen by trained personnel. Seek immediate medical attention. Give two glasses of water and do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician or poison control center immediately. SECTION 5 : FIRE FIGHTING MEASURES Auto Ignition Temperature: Lower Flammable/Explosive Upper Flammable/Explosive Fire Fighting Instructions: Extinguishing Media: Unsuitable Media: Protective Equipment: Hazardous Combustion Byproducts: 365 F (185 C) Evacuate area of unprotected personnel. Use cold water spray to cool fire exposed containers to minimize risk of rupture. Do not enter confined fire space without full protective gear. If possible, contain fire run-off water. Use carbon dioxide (CO2) or dry chemical when fighting fires involving this material. Oxidizing materials, halogens, isocyanates and acids. As in any fire, wear Self-Contained Breathing Apparatus (SCBA), MSHA/NIOSH (approved or equivalent) and full protective gear. Carbon monoxide, carbon dioxide, oxides of nitrogens and amines. SECTION 6 : ACCIDENTAL RELEASE MEASURES Personnel Precautions: Environmental Precautions: Evacuate area and keep unnecessary and unprotected personnel from entering the spill area. Avoid runoff into storm sewers, ditches, and waterways. SECTION 7 : HANDLING and STORAGE Handling: Storage: Use with local exhaust ventilation. Avoid breathing vapor, aerosol or mist. Store at room temperature in a cool, dry, well ventilated area away from sources of heat and incompatible materials. Keep container tightly closed when not in use. SECTION 8 : EXPOSURE CONTROLS, PERSONAL PROTECTION - EXPOSURE GUIDELINES Engineering Controls: Use appropriate engineering control such as process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Good general ventilation should be sufficient to control airborne levels. Where such systems are not effective wear suitable personal protective equipment, which performs satisfactorily and meets OSHA or other recognized standards. Consult with local procedures for selection, training, inspection and maintenance of the personal protective equipment. Eye/Face Protection: Wear appropriate protective glasses or splash goggles as described by 29 CFR , OSHA eye and face protection regulation, or the European standard EN 166. Skin Protection Description: Wear appropriate protective gloves and other protective apparel to prevent skin contact. Consult manufacturer's data for permeability data. Respiratory Protection: A NIOSH approved air-purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air purifying respirators may not provide adequate protection. Other Protective: Facilities storing or utilizing this material should be equipped with an eyewash and a deluge shower safety station. EXPOSURE GUIDELINES

5 SECTION 9 : PHYSICAL and CHEMICAL PROPERTIES Physical State Appearance: Odor: Odor Threshold: Boiling Point: Melting Point: Specific Gravity: Solubility: Vapor Density: Vapor Pressure: Evaporation Rate: Viscosity: Auto Ignition Temperature: VOC Content: clear liquid Amine odor g/ml negligible. 700 cps 365 F (185 C) SECTION 10 : STABILITY and REACTIVITY Chemical Stability: Hazardous Polymerization: Conditions to Avoid: Incompatible Materials: Stable under normal temperatures and pressures. Not reported. Extreme heat, sparks, and open flame. Incompatible materials, oxidizers and oxidizing conditions. Oxidizers, acids, and chlorinated organic compounds. Reactive metals (e.g. sodium, calcium, zinc). Sodium/calcium hypochlorite. Nitrous acid/ oxide, nitrites. Peroxides. Materials reactive with hydroxyl compounds. SECTION 11 : TOXICOLOGICAL INFORMATION SECTION 12 : ECOLOGICAL INFORMATION Ecotoxicity: Environmental Fate: No ecotoxicity data was found for the product. No environmental information found for this product. SECTION 13 : DISPOSAL CONSIDERATIONS Waste Disposal: RCRA Consult with the US EPA Guidelines listed in 40 CFR Part for the classifications of hazardous waste prior to disposal. Furthermore, consult with your state and local waste requirements or guidelines, if applicable, to ensure compliance. Arrange disposal in accordance to the EPA and/or state and local guidelines. None. SECTION 14 : TRANSPORT INFORMATION DOT Shipping Name: Amines, liquid, corrosive n.o.s. DOT UN UN2735 DOT Hazard Class: 8 DOT Packing Group: III TDG Classification: P.I.N.: UN2735 Class:8 Amines, liquids, corrosive n.o.s. (polyosypropylene diamine) PKG:III SECTION 15 : REGULATORY INFORMATION Canada WHMIS: Classification: D-2B, E corrosive liquid SECTION 16 : ADDITIONAL INFORMATION HMIS Fire Hazard: 1 HMIS Health Hazard: 3 HMIS Reactivity: 1 HMIS Personal Protection: X

6 Copyrightï ½ Actio Software Corporation. All Rights Reserved.