Safety Data Sheet Zinc-Glycinate Revision date : 2014/12/12 Page: 1/10

Transcription

1 Revision date : 2014/12/12 Page: 1/10 1. Identification Product identifier used on the label Recommended use of the chemical and restriction on use Recommended use*: feed additive(s) * The Recommended use identified for this product is provided solely to comply with a US Federal requirement and is not part of the seller's published specification. The terms of this Safety Data Sheet (SDS) do not create or infer any warranty, express or implied, including by incorporation into or reference in the seller's sales agreement. Details of the supplier of the safety data sheet Company: BASF Mexicana S.A. de C.V. Av. Insurgentes Sur 975 Col. CD. De Los Deportes, C.P , MEXICO Telephone: Emergency telephone number Tel.: or CHEMTREC Int.: Other means of identification Synonyms: Bis(glycinato-N,O)zinc 2. Hazards Identification According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part Classification of the product Acute Tox. 4 (oral) Acute toxicity Eye Dam./Irrit. 1 Serious eye damage/eye irritation Aquatic Acute 1 Hazardous to the aquatic environment - acute Aquatic Chronic 2 Hazardous to the aquatic environment - chronic Label elements Pictogram:

2 Revision date : 2014/12/12 Page: 2/10 Signal Word: Danger Hazard Statement: H318 H302 H411 H400 Causes serious eye damage. Harmful if swallowed. Toxic to aquatic life with long lasting effects. Very toxic to aquatic life. Precautionary Statements (Prevention): P280 Wear eye/face protection. P273 Avoid release to the environment. P270 Do not eat, drink or smoke when using this product. P264 Wash with plenty of water and soap thoroughly after handling. Precautionary Statements (Response): P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/physician. P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P330 Rinse mouth. P391 Collect spillage. Precautionary Statements (Disposal): P501 Dispose of contents/container to hazardous or special waste collection point. Hazards not otherwise classified No specific dangers known, if the regulations/notes for storage and handling are considered. According to Regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part Emergency overview WARNING: Causes serious eye damage. HARMFUL IF SWALLOWED. 3. Composition / Information on Ingredients According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part CAS Number Content (W/W) Chemical name % Zinc sulfate % Zinc, bis(glycinato-.kappa.n,.kappa.o)-, (T-4)- The above ingredients are, in total, below the relevant classification limits. According to Regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part

3 Revision date : 2014/12/12 Page: 3/10 CAS Number Content (W/W) Chemical name % Zinc sulfate % Zinc, bis(glycinato-.kappa.n,.kappa.o)-, (T-4)- 4. First-Aid Measures Description of first aid measures General advice: Immediately remove contaminated clothing. If adverse health effects develop seek medical attention. If inhaled: Keep patient calm, remove to fresh air, seek medical attention. If on skin: Wash thoroughly with soap and water. If in eyes: Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist. If swallowed: Immediately rinse mouth and then drink ml of water, seek medical attention. Most important symptoms and effects, both acute and delayed Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further important symptoms and effects are so far not known. Hazards: No applicable information available. Indication of any immediate medical attention and special treatment needed Note to physician Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. 5. Fire-Fighting Measures Extinguishing media Suitable extinguishing media: water spray, foam, dry powder, carbon dioxide Unsuitable extinguishing media for safety reasons: water jet Special hazards arising from the substance or mixture Hazards during fire-fighting: harmful vapours, carbon oxides Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of fire. Burning produces harmful and toxic fumes. Advice for fire-fighters

4 Revision date : 2014/12/12 Page: 4/10 Protective equipment for fire-fighting: Wear self-contained breathing apparatus and chemical-protective clothing. Further information: Dispose of fire debris and contaminated extinguishing water in accordance with official regulations. Cool endangered containers with water-spray. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Use personal protective clothing. Information regarding personal protective measures see, section 8. Avoid dust formation. Ensure adequate ventilation. Do not breathe dust. Wear respiratory protection if ventilation is inadequate. Avoid contact with the skin, eyes and clothing. Environmental precautions Do not discharge into drains/surface waters/groundwater. Inform authorities in the event of product spillage to water courses or sewage systems. Methods and material for containment and cleaning up For large amounts: Sweep/shovel up. Collect waste in suitable containers, which can be labeled and sealed. For residues: Sweep/shovel up. Dispose of absorbed material in accordance with regulations. Avoid raising dust. Cleaning operations should be carried out only while wearing breathing apparatus. 7. Handling and Storage Precautions for safe handling Ensure thorough ventilation of stores and work areas. Wear suitable protective clothing and eye/face protection. Avoid contact with the skin, eyes and clothing. Keep container tightly sealed. Protection against fire and explosion: Take precautionary measures against static discharges. Avoid all sources of ignition: heat, sparks, open flame. Conditions for safe storage, including any incompatibilities No applicable information available. Suitable materials for containers: cardboard with PE/PA composite film, polyethylene (PE), Paper/Fibreboard Further information on storage conditions: Keep container tightly closed and dry; store in a cool place. Keep only in the original container. Storage stability: Storage temperature: <= 30 C 8. Exposure Controls/Personal Protection Advice on system design: No applicable information available.

5 Revision date : 2014/12/12 Page: 5/10 Personal protective equipment Respiratory protection: Breathing protection if dusts are formed. Wear a NIOSH-certified (or equivalent) respirator as necessary. Hand protection: Wear chemical resistant protective gloves. Eye protection: Wear safety goggles (chemical goggles) if there is potential for airborne dust exposures. Body protection: Body protection must be chosen based on level of activity and exposure. General safety and hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is recommended. Do not breathe dust. Avoid contact with eyes. No eating, drinking, smoking or tobacco use at the place of work. Hands and/or face should be washed before breaks and at the end of the shift. Store work clothing separately. 9. Physical and Chemical Properties Form: free flowing, Microgranule (MG) Odour: odourless Odour threshold: Not determined due to potential health hazard by inhalation. Colour: white to beige ph value: 4-5 ( 10 %(m), 20 C) decomposition point: approx. 200 C Boiling point: dropped Sublimation point: No applicable information available. Flash point: not applicable, the product is a solid Flammability: not highly flammable Lower explosion limit: For solids not relevant for classification and labelling. Upper explosion limit: For solids not relevant for classification and labelling. Vapour pressure: negligible Bulk density: 800-1,100 kg/m3 Vapour density: negligible Partitioning coefficient n- octanol/water (log Pow): No data available. Thermal decomposition: 395 C (DSC (DIN 51007)) Viscosity, dynamic: not applicable, the product is a solid Solubility in water: soluble Solubility (quantitative): No applicable information available. Solubility (qualitative): No applicable information available. Molar mass: g/mol Evaporation rate: negligible 10. Stability and Reactivity Reactivity No hazardous reactions if stored and handled as prescribed/indicated.

6 Revision date : 2014/12/12 Page: 6/10 Corrosion to metals: Corrosive effects to metal are not anticipated. Oxidizing properties: Based on its structural properties the product is not classified as oxidizing. Minimum ignition energy: The product is not capable of a dust explosion. Chemical stability The product is stable if stored and handled as prescribed/indicated. Possibility of hazardous reactions No hazardous reactions if stored and handled as prescribed/indicated. Conditions to avoid See MSDS section 7 - Handling and storage. Incompatible materials None known during use and storage if used according to instructions. Hazardous decomposition products Decomposition products: Hazardous decomposition products: No hazardous decomposition products known. Thermal decomposition: 395 C (DSC (DIN 51007)) 11. Toxicological information Primary routes of exposure Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or skin contact. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of entry for liquefied gases. Acute Toxicity/Effects Acute toxicity Assessment of acute toxicity: Of moderate toxicity after single ingestion. Oral Type of value: LD50 Species: rat Value: 1,000-2,000 mg/kg (OECD Guideline 423) The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Inhalation No applicable information available. Dermal Type of value: ATE

7 Revision date : 2014/12/12 Page: 7/10 Value: > 5,000 mg/kg Assessment other acute effects No data available. Irritation / corrosion Assessment of irritating effects: Causes serious eye damage. Not irritating to the skin. Sensitization Assessment of sensitization: Skin sensitizing effects were not observed in animal studies. Aspiration Hazard No data available. Chronic Toxicity/Effects Repeated dose toxicity Assessment of repeated dose toxicity: Repeated exposure to large quantities may affect certain organs. Genetic toxicity Assessment of mutagenicity: Most of the results from the available studies show no evidence of a mutagenic effect. Carcinogenicity Assessment of carcinogenicity: Not classified, due to lack of data. Reproductive toxicity Assessment of reproduction toxicity: No reliable data are available concerning reproduction toxicity. Other Information The product has not been tested. The statements on toxicology have been derived from the structure of the product. Symptoms of Exposure The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further important symptoms and effects are so far not known. 12. Ecological Information Toxicity Aquatic toxicity Assessment of aquatic toxicity: Very toxic (acute effect) to aquatic organisms. Toxicity to fish LC50 (96 h) mg/l equivalent to 0,169 mg/l Zn2+, Oncorhynchus mykiss (Fish test acute, static) The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. The details of the toxic effect relate to the nominal concentration. Aquatic invertebrates LC50 (48 h) mg/l equivalent to 0,068 mg/l Zn, Daphnia magna (Daphnia test acute, static)

8 Revision date : 2014/12/12 Page: 8/10 The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. The details of the toxic effect relate to the nominal concentration. Aquatic plants EC50 (72 h) mg/l equivalent to 0,136 mg/l Zn2+ (growth rate), Pseudokirchneriella subcapitata (Growth Inhibition Test, static) The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. The statement of the toxic effect relates to the analytically determined concentration. Persistence and degradability Assessment biodegradation and elimination (H2O) The organic component of the product is biodegradable. Inorganic product which cannot be eliminated from water by biological purification processes. Bioaccumulative potential Assessment bioaccumulation potential Significant accumulation in organisms is not to be expected. Mobility in soil Assessment transport between environmental compartments No data available. Additional information Other ecotoxicological advice: The product has not been tested. The statements on ecotoxicology have been derived from the structure of the product. 13. Disposal considerations Waste disposal of substance: Observe national and local legal requirements. Container disposal: Dispose of in accordance with national, state and local regulations. 14. Transport Information Land transport TDG Hazard class: 9 Packing group: III ID number: UN 3077 Hazard label: Proper shipping name: 9, EHSM ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains BIS(GLYCINATO-N,O)ZINC) Sea transport IMDG

9 Revision date : 2014/12/12 Page: 9/10 Hazard class: 9 Packing group: III ID number: UN 3077 Hazard label: 9, EHSM Marine pollutant: YES Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains BIS(GLYCINATO-N,O)ZINC) Air transport IATA/ICAO Hazard class: 9 Packing group: III ID number: UN 3077 Hazard label: Proper shipping name: 9, EHSM ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains BIS(GLYCINATO-N,O)ZINC) 15. Regulatory Information Federal Regulations Not applicable NFPA Hazard codes: Health : 2 Fire: 2 Reactivity: 0 Special: HMIS III rating Health: 2 Flammability: 1 Physical hazard: 0 Assessment of the hazard classes according to UN GHS criteria (most recent version): Aquatic Acute 1 Hazardous to the aquatic environment - acute Acute Tox. 4 (oral) Acute toxicity Eye Dam./Irrit. 1 Serious eye damage/eye irritation 16. Other Information SDS Prepared by: BASF NA Product Regulations SDS Prepared on: 2014/12/12 We support worldwide Responsible Care initiatives. We value the health and safety of our employees, customers, suppliers and neighbors, and the protection of the environment. Our commitment to Responsible Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring the safe and environmentally sound handling of our products, and minimizing the impact of our operations on society and the environment during production, storage, transport, use and disposal of our products.

10 Revision date : 2014/12/12 Page: 10/10 IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY UNDERSTAND AND AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY OUR COMPANY HEREUNDER ARE GIVEN GRATIS AND WE ASSUME NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. Attention - The product has not yet been fully tested. END OF DATA SHEET