Safety Data Sheet Iron-Glycinate Revision date : 2017/11/20 Page: 1/10

Transcription

1 Revision date : 2017/11/20 Page: 1/10 1. Identification Product identifier used on the label Recommended use of the chemical and restriction on use Recommended use*: feed additive(s) * The Recommended use identified for this product is provided solely to comply with a Federal requirement and is not part of the seller's published specification. The terms of this Safety Data Sheet (SDS) do not create or infer any warranty, express or implied, including by incorporation into or reference in the seller's sales agreement. Details of the supplier of the safety data sheet Company: BASF Canada Inc. 100 Milverton Drive Mississauga, ON L5R 4H1, CANADA Telephone: Emergency telephone number CANUTEC (reverse charges): (613) BASF HOTLINE: (800) 454-COPE (2673) Other means of identification Synonyms: Iron, bis(glycinato-.kappa.n,.kappa.o)- 2. Hazards Identification According to Hazardous Products Regulations (HPR) (SOR/ ) Classification of the product Skin Corr./Irrit. 2 Skin corrosion/irritation Eye Dam./Irrit. 2A Serious eye damage/eye irritation Combustible Dust Combustible Dust (1) Combustible Dust Label elements Pictogram:

2 Revision date : 2017/11/20 Page: 2/10 Signal Word: Warning Hazard Statement: H319 H315 May form combustible dust concentration in air. Causes serious eye irritation. Causes skin irritation. Precautionary Statements (Prevention): P280 Wear protective gloves and eye/face protection. P264 Wash with plenty of water and soap thoroughly after handling. Precautionary Statements (Response): P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P303 + P352 IF ON SKIN (or hair): Wash with plenty of soap and water. P332 + P313 If skin irritation occurs: Get medical advice/attention. P337 + P313 If eye irritation persists: Get medical advice/attention. P362 + P364 Take off contaminated clothing and wash it before reuse. Hazards not otherwise classified The product is under certain conditions capable of dust explosion. The product does not contain a substance fulfilling the PBT (persistent/bioaccumulative/toxic) criteria or the vpvb (very persistent/very bioaccumulative) criteria. 3. Composition / Information on Ingredients According to Hazardous Products Regulations (HPR) (SOR/ ) CAS Number Weight % Chemical name % Iron, bis(glycinato-.kappa.n,.kappa.o)- 4. First-Aid Measures Description of first aid measures General advice: Immediately remove contaminated clothing. If adverse health effects develop seek medical attention. If inhaled: Keep patient calm, remove to fresh air, seek medical attention. If on skin: Wash thoroughly with soap and water. If in eyes: Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.

3 Revision date : 2017/11/20 Page: 3/10 If swallowed: Immediately rinse mouth and then drink ml of water, seek medical attention. Most important symptoms and effects, both acute and delayed Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further important symptoms and effects are so far not known. Hazards: No applicable information available. Indication of any immediate medical attention and special treatment needed Note to physician Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. 5. Fire-Fighting Measures Extinguishing media Suitable extinguishing media: water spray, foam, dry powder, carbon dioxide Unsuitable extinguishing media for safety reasons: water jet Additional information: Avoid whirling up the material/product because of the danger of dust explosion. Special hazards arising from the substance or mixture Hazards during fire-fighting: harmful vapours, carbon oxides Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of fire. Burning produces harmful and toxic fumes. Dust explosion hazard. Advice for fire-fighters Protective equipment for fire-fighting: Wear a self-contained breathing apparatus. Further information: Dispose of fire debris and contaminated extinguishing water in accordance with official regulations. Cool endangered containers with water-spray. Dusty conditions may ignite explosively in the presence of an ignition source causing flash fire. 6. Accidental release measures Further accidental release measures: Dust can form an explosive mixture with air. Further accidental release measures: Avoid dispersal of dust in the air (i.e., clearing dust surfaces with compressed air). Avoid the formation and build-up of dust - danger of dust explosion. Dust in sufficient concentration can result

4 Revision date : 2017/11/20 Page: 4/10 in an explosive mixture in air. Handle to minimize dusting and eliminate open flame and other sources of ignition. Personal precautions, protective equipment and emergency procedures Use personal protective clothing. Information regarding personal protective measures see, section 8. Avoid dust formation. Ensure adequate ventilation. Do not breathe dust. Wear respiratory protection if ventilation is inadequate. Avoid contact with the skin, eyes and clothing. Environmental precautions Do not discharge into drains/surface waters/groundwater. Methods and material for containment and cleaning up For large amounts: Sweep/shovel up. Collect waste in suitable containers, which can be labeled and sealed. For residues: Sweep/shovel up. Dispose of absorbed material in accordance with regulations. Avoid raising dust. Cleaning operations should be carried out only while wearing breathing apparatus. Nonsparking tools should be used. 7. Handling and Storage Precautions for safe handling Avoid dust formation. Provide exhaust ventilation if dust is formed. Wear suitable protective clothing and eye/face protection. Avoid contact with the skin, eyes and clothing. Protection against fire and explosion: The product is capable of dust explosion. Avoid dust formation. Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy. Use explosion-proof apparatus and fittings. Dust in sufficient concentration can result in an explosive mixture in air. Handle to minimize dusting and eliminate open flame and other sources of ignition. Routine housekeeping should be instituted to ensure that dusts do not accumulate on surfaces. Dry powders can build static electricity charges when subjected to the friction of transfer and mixing operations. Provide adequate precautions, such as electrical grounding and bonding, or inert atmospheres. Refer to NFPA 654, Standard for the Prevention of Fire and Dust Explosions from the Manufacturing, Processing, and Handling of Combustible Particulate Solids (2013 Edition) for safe handling. Conditions for safe storage, including any incompatibilities No applicable information available. Suitable materials for containers: Paper/Fibreboard, High density polyethylene (HDPE), Low density polyethylene (LDPE) Further information on storage conditions: Keep container tightly closed and dry; store in a cool place. Keep only in the original container. 8. Exposure Controls/Personal Protection No occupational exposure limits known.

5 Revision date : 2017/11/20 Page: 5/10 Advice on system design: It is recommended that all dust control equipment such as local exhaust ventilation and material transport systems involved in handling of this product contain explosion relief vents or an explosion suppression system or an oxygen deficient environment. Ensure that dust-handling systems (such as exhaust ducts, dust collectors, vessels, and processing equipment) are designed in a manner to prevent the escape of dust into the work area (i.e., there is no leakage from the equipment). Use only appropriately classified electrical equipment and powered industrial trucks. Personal protective equipment Respiratory protection: Breathing protection if dusts are formed. Wear a NIOSH-certified (or equivalent) respirator as necessary. Hand protection: Wear chemical resistant protective gloves. Eye protection: Wear safety goggles (chemical goggles) if there is potential for airborne dust exposures. Body protection: Body protection must be chosen based on level of activity and exposure. General safety and hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is required additionally to the stated personal protection equipment. Avoid contact with skin and eyes. Do not breathe dust. No eating, drinking, smoking or tobacco use at the place of work. Hands and/or face should be washed before breaks and at the end of the shift. Store work clothing separately. 9. Physical and Chemical Properties Form: free flowing, Microgranule (MG) Odour: odourless Odour threshold: not applicable, odour not perceivable Colour: beige to brown ph value: 3-5 ( 10 %(m), 20 C) decomposition point: approx. 250 C Boiling point: dropped Sublimation point: No applicable information available. Flash point: not applicable, the product is a solid Flammability: not highly flammable (UN Test N.1 (ready combustible solids)) Lower explosion limit: For solids not relevant for classification and labelling. Upper explosion limit: For solids not relevant for classification and labelling. Vapour pressure: negligible Relative density: No applicable information available. Bulk density: 750-1,000 kg/m3 Vapour density: not applicable Partitioning coefficient n- octanol/water (log Pow): not applicable for mixtures

6 Revision date : 2017/11/20 Page: 6/10 Thermal decomposition: >= 200 C (DSC (DIN 51007)) Not a substance liable to self-decomposition according to UN transport regulations, class 4.1. Viscosity, dynamic: not applicable, the product is a solid Solubility in water: ( 20 C) soluble Solubility (quantitative): No applicable information available. Solubility (qualitative): No applicable information available. Evaporation rate: negligible 10. Stability and Reactivity Reactivity Corrosion to metals: No data available. Oxidizing properties: Based on its structural properties the product is not classified as oxidizing. Minimum ignition energy: The product is capable of dust explosion. Chemical stability The product is stable if stored and handled as prescribed/indicated. Possibility of hazardous reactions Dust explosion hazard. Conditions to avoid See MSDS section 7 - Handling and storage. Avoid dust formation. Avoid all sources of ignition: heat, sparks, open flame. Incompatible materials None known during use and storage if used according to instructions. Hazardous decomposition products Decomposition products: Hazardous decomposition products: No hazardous decomposition products known. Thermal decomposition: >= 200 C (DSC (DIN 51007)) Not a substance liable to self-decomposition according to UN transport regulations, class Toxicological information Primary routes of exposure Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or skin contact. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of entry for liquefied gases. Acute Toxicity/Effects

7 Revision date : 2017/11/20 Page: 7/10 Acute toxicity Assessment of acute toxicity: Virtually nontoxic after a single ingestion. Oral Information on: Iron, bis(glycinato-.kappa.n,.kappa.o)- Type of value: LD50 Species: rat Value: 2,800 mg/kg Assessment other acute effects Assessment of STOT single: Based on the available information there is no specific target organ toxicity to be expected after a single exposure. Irritation / corrosion Assessment of irritating effects: Irritating to eyes and skin. Sensitization Assessment of sensitization: Skin sensitizing effects were not observed in animal studies. Aspiration Hazard not applicable Chronic Toxicity/Effects Repeated dose toxicity Assessment of repeated dose toxicity: No adverse effects were observed after repeated exposure in animal studies. Genetic toxicity Assessment of mutagenicity: Most of the results from the available studies show no evidence of a mutagenic effect. The product has not been tested. The statement has been derived from the properties of the individual components. Carcinogenicity Assessment of carcinogenicity: No data available. Reproductive toxicity Assessment of reproduction toxicity: No data available. Teratogenicity Assessment of teratogenicity: No indications of a developmental toxic / teratogenic effect were seen in animal studies. Other Information The product has not been tested. The statements on toxicology have been derived from the properties of the individual components. Symptoms of Exposure The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further important symptoms and effects are so far not known.

8 Revision date : 2017/11/20 Page: 8/ Ecological Information Toxicity Aquatic toxicity Assessment of aquatic toxicity: There is a high probability that the product is not acutely harmful to aquatic organisms. The inhibition of the degradation activity of activated sludge is not anticipated when introduced to biological treatment plants in appropriate low concentrations. Toxicity to fish LC0 (96 h) > 50,000 mg/l, Brachydanio rerio (static) Tested above maximum solubility. The details of the toxic effect relate to the nominal concentration. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Aquatic invertebrates LC50 (48 h) > 100 mg/l, Daphnia magna (OECD Guideline 202, part 1, static) The details of the toxic effect relate to the nominal concentration. Tested above maximum solubility. Analogous: Assessment derived from products with similar chemical character. Persistence and degradability Assessment biodegradation and elimination (H2O) Readily biodegradable (according to OECD criteria). The product has not been tested. The statement has been derived from the structure of the product. Bioaccumulative potential Assessment bioaccumulation potential Significant accumulation in organisms is not to be expected. The product has not been tested. The statement has been derived from the structure of the product. Mobility in soil Assessment transport between environmental compartments not determined Additional information Other ecotoxicological advice: The product has not been tested. The statements on ecotoxicology have been derived from the properties of the individual components. 13. Disposal considerations Waste disposal of substance: Observe national and local legal requirements. Container disposal: Dispose of in accordance with national, state and local regulations.

9 Revision date : 2017/11/20 Page: 9/ Transport Information Land transport TDG Not classified as a dangerous good under transport regulations Sea transport IMDG Not classified as a dangerous good under transport regulations Air transport IATA/ICAO Not classified as a dangerous good under transport regulations 15. Regulatory Information Federal Regulations Registration status: Feed DSL, CA released; restriction on quantity / not listed Chemical DSL, CA released; restriction on quantity / not listed NFPA Hazard codes: Health: 2 Fire: 1 Reactivity: 0 Special: Assessment of the hazard classes according to UN GHS criteria (most recent version): Skin Corr./Irrit. 2 Skin corrosion/irritation Eye Dam./Irrit. 2A Serious eye damage/eye irritation Acute Tox. 5 (oral) Acute toxicity 16. Other Information SDS Prepared by: BASF NA Product Regulations SDS Prepared on: 2017/11/20 We support worldwide Responsible Care initiatives. We value the health and safety of our employees, customers, suppliers and neighbors, and the protection of the environment. Our commitment to Responsible Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring the safe and environmentally sound handling of our products, and minimizing the impact of our operations on society and the environment during production, storage, transport, use and disposal of our products.

10 Revision date : 2017/11/20 Page: 10/10 Attention - The product has not yet been fully tested. END OF DATA SHEET