SAFETY DATA SHEET. Very toxic to aquatic life with long lasting effects.

Transcription

1 SAFETY DATA SHEET SECTION 1 : IDENTIFICATION Product identifier used on the label: Product Name: LTL Product Code: SDS Manufacturer Number: Other means of identification: Synonyms: Not applicable Recommended use of the chemical and restrictions on use: Product Use/Restriction: Printing Plate Chemical manufacturer address and telephone number: Manufacturer Name: MacDermid Printing Solutions Address: 5210 Phillip Lee Drive Atlanta, GA USA General Phone Number: Emergency phone number: Emergency Phone Number: SECTION 2 : HAZARD(S) IDENTIFICATION Classification of the chemical in accordance with CFR (d)(f ): GHS Pictograms: Signal Word: WARNING. GHS Class: Skin Sensitization. Category 1. Hazardous to the aquatic environment, long-term, chronic,. Category 1. Hazard Statements: Precautionary Statements: May cause an allergic skin reaction. Very toxic to aquatic life with long lasting effects. Avoid breathing dust/fume/gas/mist/vapours/spray. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of water. If skin irritation or rash occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. Collect spillage. Dispose of contents/container in accordance with Local, State, Federal and Provincial regulations. Hazards not otherwise classified that have been identified during the classification process: Potential Health Effects: Aggravation of Pre-Existing Conditions: Dusts and particles from this product may cause irritation. May cause an allergic skin reaction. May aggravate pre-existing allergy, eczema, or skin conditions. SECTION 3 : COMPOSITION/INFORMATION ON INGREDIENTS Mixtures: Chemical Name CAS# Ingredient Percent EC Num. Polyurethane methacrylate oligomer Proprietary by weight Methacrylic esters Proprietary by weight Polyunsaturated carboxylic acid ester Proprietary 1-5 by weight Revision: 05/28/2015 Page 1 of 5

2 Note: The specific chemical identify is being withheld as a Trade Secret. In the event of a medical emergency, specific chemical composition will be provided upon request by a physician or other health related personnel. SECTION 4 : FIRST AID MEASURES Description of necessary measures: Eye Contact: Skin Contact: Inhalation: Ingestion: Immediately flush eyes with plenty of water for at least 15 to 20 minutes. Ensure adequate flushing of the eyes by separating the eyelids with fingers. Get immediate medical attention. Immediately wash skin with plenty of soap and water for 15 to 20 minutes, while removing contaminated clothing and shoes. Get medical attention if irritation develops or persists. If inhaled, remove to fresh air. If not breathing, give artificial respiration or give oxygen by trained personnel. Seek immediate medical attention. If swallowed, do NOT induce vomiting. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. Most important symptoms/effects, acute and delayed: Other First Aid: First Responders should provide for their own safety prior to rendering assistance. SECTION 5 : FIRE FIGHTING MEASURES Suitable and unsuitable extinguishing media: Suitable Extinguishing Media: Unsuitable extinguishing media: Unusual Fire Hazards: Use carbon dioxide (CO2) or dry chemical when fighting fires involving this material. Water may cause frothing. Sealed containers at elevated temperatures may rupture explosively and spread fire due to polymerization. When heated to decomposition, toxic fumes are emitted. Special protective equipment and precautions for fire-fighters: Protective Equipment: Fire Fighting Instructions: As in any fire, wear Self-Contained Breathing Apparatus (SCBA), MSHA/NIOSH (approved or equivalent) and full protective gear. Evacuate area of unprotected personnel. Use cold water spray to cool fire exposed containers to minimize risk of rupture. Do not enter confined fire space without full protective gear. If possible, contain fire run-off water. NFPA Ratings: NFPA Health: 2 NFPA Flammability: 1 NFPA Reactivity: SECTION 6 : ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures: Personnel Precautions: Evacuate area and keep unnecessary and unprotected personnel from entering the spill area. Environmental precautions: Environmental Precautions: Avoid runoff into storm sewers, ditches, and waterways. Methods and materials for containment and cleaning up: Spill Cleanup Measures: Absorb spill with inert material (e,g., dry sand or earth), then place in a chemical waste container. Provide ventilation. Clean up spills immediately observing precautions in the protective equipment section. Neutralize residue with appropriate neutralizer. Do not attempt to neutralize large quantities of material unless measures to control reactivity and heat generation have been taken. After removal, flush spill area with soap and water to remove trace residue. Avoid personal contact and breathing vapors or mists. SECTION 7 : HANDLING and STORAGE Precautions for safe handling: Handling: Hygiene Practices: Use with adequate ventilation. Avoid breathing vapor, aerosol or mist. Wash thoroughly after handling. Special Handling Procedures: Provide appropriate ventilation/respiratory protection against decomposition products (see Section 10) during welding/flame cutting operations and to protect against dust during sanding/grinding of cured Revision: 05/28/2015 Page 2 of 5

3 product. Conditions for safe storage, including any incompatibilities: Storage: Specific end use(s): Work Practices: Store in a cool, dry, well ventilated area away from sources of heat and incompatible materials. Keep container tightly closed when not in use. Store away from direct heat or sunlight, sources of UV radiation, peroxides, or free radicals. Do not store in temperatures above 49 C (120 F) or below 9 C (48 F). Handle in accordance with good industrial hygiene and safety practices. SECTION 8: EXPOSURE CONTROLS, PERSONAL PROTECTION EXPOSURE GUIDELINES: Appropriate engineering controls: Engineering Controls: Individual protection measures: Eye/Face Protection: Skin Protection Description: Hand Protection Description: Respiratory Protection: Other Protective: Use appropriate engineering control such as process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Good general ventilation should be sufficient to control airborne levels. Where such systems are not effective wear suitable personal protective equipment, which performs satisfactorily and meets OSHA or other recognized standards. Consult with local procedures for selection, training, inspection and maintenance of the personal protective equipment. Wear appropriate protective glasses or splash goggles as described by 29 CFR , OSHA eye and face protection regulation, or the European standard EN 166. Wear appropriate protective gloves and other protective apparel to prevent skin contact. Consult manufacturer's data for permeability data. Neoprene gloves. A NIOSH approved air-purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air purifying respirators may not provide adequate protection. Facilities storing or utilizing this material should be equipped with an eyewash and a deluge shower safety station. PPE Pictograms: Notes : Only established PEL and TLV values for the ingredients are listed. SECTION 9 : PHYSICAL and CHEMICAL PROPERTIES PHYSICAL AND CHEMICAL PROPERTIES: Physical State Appearance: Liquid. Color: Red Odor: Mild. Odor Threshold: Boiling Point: Melting Point: Specific Gravity: Solubility: Negligible solubility in water. Vapor Pressure: Percent Volatile: Not applicable. ph: 6.7 Molecular Formula: Mixture Molecular Weight: Mixture Flash Point: >200 F (>93.3 C) Flash Point Method: Setaflash Lower Flammable/Explosive Limit: Upper Flammable/Explosive Limit: VOC Content: SECTION 10 : STABILITY and REACTIVITY Chemical Stability: Chemical Stability: Possibility of hazardous reactions: Hazardous Polymerization: Stable under recommended handling and storage conditions. Polymerization may occur under certain conditions. Revision: 05/28/2015 Page 3 of 5

4 Hazardous Polymerization: Conditions To Avoid: Conditions to Avoid: Incompatible Materials: Incompatible Materials: Hazardous Decomposition Products: Special Decomposition Products: Polymerization may occur under certain conditions. Extreme heat, sparks, and open flame. Incompatible materials, oxidizers and oxidizing conditions. Extended exposure over 110 F (38 C). Protect from light, heat, and freezing. Oxidizers, acids, bases, isocyanates. Thermal decomposition can lead to release irritant fumes and toxic gases. SECTION 11 : TOXICOLOGICAL INFORMATION TOXICOLOGICAL INFORMATION: Polyunsaturated carboxylic acid ester : Skin: Ingestion: Administration onto the skin - Rabbit Standard Draize test.: 0.1 ml/24h Administration onto the skin - Rabbit Standard Draize test.: 0.5 ml/21d (Intermittent)[RTECS] Oral - Mouse LD50: >8000 mg/kg [Behavioral - Ataxia] Oral - Rat LD50: 2100 mg/kg [Details of toxic effects not reported other than lethal dose value] Oral - Mouse LD50: >8 gm/kg [Peripheral Nerve and Sensation - Flaccid paralysis without anesthesia (usually neuromuscular blockage) Behavioral - Ataxia] [RTECS] SECTION 12 : ECOLOGICAL INFORMATION Ecotoxicity: Ecotoxicity: Environmental Fate: May cause long-term adverse effects in the aquatic environment. No environmental information found for this product. SECTION 13 : DISPOSAL CONSIDERATIONS Description of waste: Waste Disposal: RCRA Number: Dispose of in accordance with Local, State, Federal and Provincial regulations. SECTION 14 : TRANSPORT INFORMATION UN number: UN proper shipping name: Not regulated as hazardous material for transportation. Not regulated as hazardous material for transportation. SECTION 15 : REGULATORY INFORMATION Safety, health and environmental regulations specific for the product: SARA: California PROP 65: Canada WHMIS: Polyunsaturated carboxylic acid ester : TSCA Inventory Status: New Jersey: Pennsylvania: Canada DSL: WHMIS Pictograms: This product does not contain any chemicals which are subject to the reporting requirements of the Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III (40CFR, Part 372). The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This product does not contain any Proposition 65 chemicals. Controlled - Class: D2B Toxic Listed Not listed Not listed Listed SECTION 16 : ADDITIONAL INFORMATION HMIS Ratings: HMIS Health Hazard: 2 HMIS Fire Hazard: 1 HMIS Reactivity: 1 Health Hazard 2 Fire Hazard 1 Reactivity 1 Revision: 05/28/2015 Page 4 of 5

5 HMIS Personal Protection: X Personal Protection X SDS Creation Date: December 28, 2011 SDS Revision Date: May 28, 2015 MSDS Revision Notes: SDS Format: Disclaimer: Formula and GHS update To the best of our knowledge the information contained herein is accurate. However, neither the abovenamed supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information containewd herein. Fianl determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used within caution. Although certain hazards are described herein, we cannot guarantee that these are th eonly hazards that exist. Copyright Actio Corporation. All Rights Reserved. Revision: 05/28/2015 Page 5 of 5