SECTION 1: Identification of the substance/mixture and of the company/undertaking. H229 - Pressurised container: May burst if heated
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1 MSDS Version: E03.01 Date of issue: 24/09/2014 Blend Version: 2 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : Tyre Fix (Aerosol) Product code : W Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Use of the substance/mixture Function or use category : Fixing and inflating punctured tyres : Aerosol propellants Uses advised against 1.3. Details of the supplier of the safety data sheet Wynn's Belgium Industriepark-West Sint-Niklaas - Belgium T F msds@wynns.eu Emergency telephone number Emergency number : BIG: +32(0)14/ SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Aerosol 1 Full text of H-phrases: see section 16 H222;H229 Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] F+; R12 Full text of R-phrases: see section 16 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) : Signal word (CLP) Hazard statements (CLP) Precautionary statements (CLP) GHS02 : Danger : H222 - Extremely flammable aerosol H229 - Pressurised container: May burst if heated : P102 - Keep out of reach of children P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P211 - Do not spray on an open flame or other ignition source P251 - Do not pierce or burn, even after use P410+P412 - Protect from sunlight. Do not expose to temperatures exceeding 50 C/122 F 2.3. Other hazards 01/12/2014 EN (English) 1/7
2 SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification according to Directive 67/548/EEC Propane (CAS No) (EC no) (EC index no) (REACH-no) Butane n- (CAS No) (EC no) (REACH-no) isobutane (CAS No) (EC no) F+; R F+; R F+; R12 Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Propane (CAS No) (EC no) (EC index no) (REACH-no) Butane n- (CAS No) (EC no) (REACH-no) isobutane (CAS No) (EC no) Full text of R- and H-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion Flam. Gas 1, H Flam. Gas 1, H Flam. Gas 1, H220 : Check the vital functions. Unconscious: maintain adequate airway and respiration. Respiratory arrest: artificial respiration or oxygen. Cardiac arrest: perform resuscitation. Victim conscious with laboured breathing: half-seated. Vomiting: prevent asphyxia/aspiration pneumonia. Victim in shock: on his back with legs slightly raised. Prevent cooling by covering the victim (no warming up). Keep watching the victim. Give psychological aid. Keep the victim calm, avoid physical strain. Depending on the victim's condition: doctor/hospital. : If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER/doctor/physician if you feel unwell. : After contact with skin, take off immediately all contaminated clothing, and wash immediately with plenty of water and soap. Take victim to a doctor if irritation persists. : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Contact ophthalmologist immediately. : As it is a spray can packaging it is most unlikely that large quantities will be swallowed. Rinse mouth. Drink plenty of water. Call a POISON CENTER/doctor/physician if you feel unwell Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : powder, alcohol-resistant foam, carbon dioxide (CO2), water spray or hazy water. : Do not use a heavy water stream. 01/12/2014 EN (English) 2/7
3 5.2. Special hazards arising from the substance or mixture Fire hazard Explosion hazard Reactivity : Extremely flammable aerosol. : Risk of explosion if heated under confinement. : On burning: release of carbon monoxide - carbon dioxide Advice for firefighters Firefighting instructions Protection during firefighting : In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. Use water spray or fog for cooling exposed containers. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Protective equipment Emergency procedures For emergency responders Emergency procedures : Gloves. protective clothing. Protective goggles. Large spills/in enclosed spaces: compressed air apparatus. : Mark the danger area. Large spills/in confined spaces: consider evacuation. Close doors and windows of adjacent premises. Seal off low-lying areas. No naked flames, sparks, and do not smoke. Stop engines and no smoking. Use spark- /explosionproof appliances and lighting system. Exposure to fire/heat: keep upwind. Wash contaminated clothes. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures 7.2. Conditions for safe storage, including any incompatibilities Storage temperature : 45 C Heat and ignition sources Prohibitions on mixed storage Storage area Special rules on packaging Packaging materials 7.3. Specific end use(s) See product bulletin for detailed information. : Take up liquid spill into inert absorbent material. Small quantities of liquid spill: take up in non-combustible absorbent material and shovel into container for disposal. Clean contaminated surfaces with an excess of water. Wash clothing and equipment after handling. : Meet the legal requirements. Keep away from naked flames/heat. Keep away from sources of ignition - No smoking. : Observe normal hygiene standards. Wash contaminated clothing before reuse. : Keep away from sources of ignition - No smoking. : Keep away from: strong oxidants and strong acids. : Fireproof storeroom. Meet the legal requirements. Protect from heat and direct sunlight. Keep container tightly closed in a cool, well-ventilated place. Store in a dry place. : meet the legal requirements. correctly labelled. : Pressurised small gas containers (aerosol cans). SECTION 8: Exposure controls/personal protection 8.1. Control parameters Propane ( ) Belgium Limit value (ppm) 1000 ppm isobutane ( ) Belgium Limit value (ppm) 1000 ppm 01/12/2014 EN (English) 3/7
4 Butane n- ( ) Belgium Limit value (ppm) 1000 ppm 8.2. Exposure controls Personal protective equipment : Protective goggles. Hand protection : PVC (Polyvinyl chloride). nitrile. Neoprene. Choosing the proper glove is a decision that depends not only on the type of material, but also on other quality features, which differ for each manufacturer. Time of penetration is to be checked with the glove producer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Appearance Colour Odour Odour threshold ph : Relative evaporation rate (butylacetate=1) refraction index : Melting point Freezing point Boiling point : Liquid : Aerosol. : white. : Characteristic odour. Flash point : < 0 C Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density C Solubility Log Pow Log Kow Viscosity, C Viscosity, C Viscosity : Viscosity Index : Explosive properties Oxidising properties Explosive limits : 3500 C : 711 kg/m³ : Soluble in water Other information Additional information : The physical and chemical data in this section are typical values for this product and are not intended as product specifications. SECTION 10: Stability and reactivity Reactivity On burning: release of carbon monoxide - carbon dioxide Chemical stability Stable under normal conditions. 01/12/2014 EN (English) 4/7
5 10.3. Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard SECTION 12: Ecological information Toxicity Ecology - general Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN-No. (ADR) : 1950 : Container under pressure. Do not drill or burn even after use. Remove to an authorized waste treatment plant UN proper shipping name Proper Shipping Name (ADR) Transport document description (ADR) : AEROSOLS : UN 1950 AEROSOLS, 2.1, (D) 01/12/2014 EN (English) 5/7
6 14.3. Transport hazard class(es) Class (ADR) : 2 Subsidiary risk (IMDG) : 2.1 Subsidiary risk (IATA) : 2.1 Danger labels (ADR) : Packing group Not applicable Environmental hazards Other information : No supplementary information available Special precautions for user Overland transport Classification code (ADR) : 5F Special provisions (ADR) : 190, 327, 344, 625 Transport category (ADR) : 2 Tunnel restriction code (ADR) : D Limited quantities (ADR) : 1l Transport by sea EmS-No. (1) : F-D, S-U Air transport Instruction "cargo" (ICAO) : 203 Instruction "passenger" (ICAO) : 203/Y Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no substances with Annex XVII restrictions Tyre Fix (Aerosol) is not on the REACH Candidate List Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances National regulations Water hazard class (WGK) : 3 - severe hazard to waters Chemical safety assessment SECTION 16: Other information Full text of R-, H- and EUH-phrases: Aerosol 1 Aerosol, Category 1 Flam. Gas 1 Flammable gases, Category 1 H220 Extremely flammable gas H222 Extremely flammable aerosol H229 Pressurised container: May burst if heated R12 Extremely flammable 01/12/2014 EN (English) 6/7
7 F+ Extremely flammable This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 01/12/2014 EN (English) 7/7
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