Copper 15% EDTA. Safety Data Sheet SECTION 1. IDENTIFICATION SECTION 2. HAZARD IDENTIFICATION. Other Means of Identification.

Transcription

1 Safety Data Sheet Copper 15% EDTA SECTION 1. IDENTIFICATION Product Identifier Other Means of Identification Product Family Recommended Use Restrictions on Use Supplier Identifier Emergency Phone No. SDS No. Copper 15% EDTA Chelated Iron 15% SECTION 2. HAZARD IDENTIFICATION Greenhouse Micronutrient Micronutrient fertilizer. Must not be used as a pest control product. TerraLink Horticulture Inc., 464 Riverside Road, Abbotsford, BC, V2S 7M1, CANUTEC, In the event of an emergency involving dangerous goods, call or *666 on a cellular phone Classified according to Canada's Hazardous Products Regulations (WHMIS 2015) and the US Hazard Communication Standard (HCS 2012). Classification Acute toxicity (Oral) - Category 4; Eye irritation - Category 2A Label Elements Warning May form combustible dust concentrations in air. Harmful if swallowed. Causes serious eye irritation. Precautionary Statement(s): Prevention: Wash hands and skin thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves/eye protection/face protection. Response: IF SWALLOWED: Call a POISON CENTRE or doctor if you feel unwell. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If eye irritation persists: Get medical advice/attention. Disposal: Dispose of contents and container in accordance with local, regional, national and international regulations. Other Hazards Page 01 of 07

2 SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No. % Other Identifiers Other Names ((ethylenedinitrilo)tetraacetato)-, disodium Copper 15% EDTA SECTION 4. FIRST-AID MEASURES First-aid Measures Inhalation Move victim to fresh air. Give artificial respiration ONLY if breathing has stopped, assist breathing with oxygen. Obtain medical assistance if necessary. Skin Contact Take off contaminated clothing, shoes and leather goods (e.g. watchbands, belts). Thoroughly wash the affected area with mild soap and water for fifteen (15) minutes. Seek medical attention if irritation persists. Get medical advice or attention if you feel unwell or are concerned. Eye Contact Rinse the contaminated eye(s) with lukewarm, gently flowing water for at least 15 minutes. If wearing contact lens(es), remove after 5 minutes and continue rinsing for at least 10 minutes if irritation persists, repeat flushing. If eye irritation persists, get medical advice or attention. Ingestion Rinse mouth with water. Call a Poison Centre or doctor if you feel unwell. First-aid Comments No specific antidote. Medical staff must contact Poison Control Centre. Most Important Symptoms and Effects, Acute and Delayed Immediate Medical Attention and Special Treatment Target Organs Special Instructions No information available. Medical Conditions Aggravated by Exposure SECTION 5. FIRE-FIGHTING MEASURES Extinguishing Media Suitable Extinguishing Media Water, Fog, Foam, Dry Chemical, CO2. Unsuitable Extinguishing Media Specific Hazards Arising from the Product Does not burn. Nitrous gases may be produced. Special Protective Equipment and Precautions for Fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Fire-fighters should wear appropriate protective equipment and self contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Page 02 of 07

3 face-piece operated in positive pressure mode. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal Precautions, Protective Equipment, and Emergency Procedures Use the personal protective equipment recommended in Section 8 of this safety data sheet. Environmental Precautions It is good practice to prevent releases into the environment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Methods and Materials for Containment and Cleaning Up No special clean-up methods are necessary. Other Information Report spills to local health, safety and environmental authorities, as required. SECTION 7. HANDLING AND STORAGE Precautions for Safe Handling Avoid generating dusts. Avoid breathing in this product. Avoid eye and skin contact. Use containment whenever possible and personal protective equipment where splashing or contact potential exists. Conditions for Safe Storage No special requirements for storage area. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Avoid dust generation. Appropriate Engineering Controls Engineering Controls: Local exhaust ventilation required. Ventilation should be corrosion proof. Vapours should be collected and neutralized in a suitable scrubbing system. Make up air should be supplied to balance air that is removed by local or general exhaust ventilation. Ventilate low lying areas such as sumps or pits where dense vapours may collect. For personnel entry into confined spaces (i.e. bulk storage tanks) a proper procedure must be followed. It must include consideration of, among other things, ventilation, testing of tank atmosphere, provision and maintenance of SCBA, and emergency rescue. Use the "buddy" system. The second person should be in view and trained and equipped to execute a rescue. Individual Protection Measures Eye/Face Protection The usual precautions for handling chemicals should be observed. Skin Protection Hand: For permanent (>480 minutes), full contact use, 100% nitrile gloves conforming to EN 374, e.g. KCL Dermatril 740 are recommended. If used under conditions other than given above it is recommended that a supplier of CE approved gloves is contacted. Nitrile rubber. Respiratory Protection Dust mask. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Basic Physical and Chemical Properties Appearance Blue fine powder. Odour Odourless ( ((ethylenedinitrilo)tetraacetato)-, disodium) Odour Threshold ph Product Identifier: 6-7 (1% solution) Copper 15% EDTA - Ver. 1 Page 03 of 07

4 ph Melting Point/Freezing Point Initial Boiling Point/Range Flash Point Evaporation Rate Flammability (solid, gas) Upper/Lower Flammability or Explosive Limit Vapour Pressure Vapour Density (air = 1) Relative Density (water = 1) Solubility Partition Coefficient, n-octanol/water (Log Kow) Auto-ignition Temperature Decomposition Temperature Viscosity Other Information Physical State Bulk Density 6-7 (1% solution) (melting); (freezing) (upper); (lower) ~ 1200 g/l in water; (in other liquids) > 200 ºC (392 ºF) ( ((ethylenedinitrilo)tetraacetato)-, disodium) (kinematic); (dynamic) Solid kg/m3 (37-50 lb/ft3) ( ((ethylenedinitrilo)tetraacetato)-, disodium) SECTION 10. STABILITY AND REACTIVITY Reactivity Strong oxidizer. Chemical Stability Normally stable. Possibility of Hazardous Reactions Conditions to Avoid Reaction with strong oxidizing agents. Incompatible Materials SECTION 11. TOXICOLOGICAL INFORMATION Likely Routes of Exposure Inhalation; skin contact; eye contact; ingestion. Acute Toxicity Chemical Name LC50 LD50 (oral) LD50 (dermal) ((ethylenedinitrilo) tetraacetato)-, disodium Skin Corrosion/Irritation Serious Eye Damage/Irritation 980 mg/kg (rat) Page 04 of 07

5 STOT (Specific Target Organ Toxicity) - Single Exposure Inhalation Dust may cause irritation to the respiratory tract and discomfort. Skin Absorption Not expected to be absorbed. Ingestion Harmful if swallowed. Aspiration Hazard Not known to be an aspiration hazard. STOT (Specific Target Organ Toxicity) - Repeated Exposure Respiratory and/or Skin Sensitization No information was located for respiratory sensitization. Carcinogenicity Not known to cause cancer. Key to Abbreviations ACGIH = American Conference of Governmental Industrial Hygienists. IARC = International Agency for Research on Cancer. NTP = National Toxicology Program. OSHA = US Occupational Safety and Health Administration. Reproductive Toxicity Development of Offspring Sexual Function and Fertility Effects on or via Lactation Germ Cell Mutagenicity Interactive Effects SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Acute Aquatic Toxicity Chemical Name LC50 Fish EC50 Crustacea ((ethylenedinitrilo) tetraacetato)-, disodium Chronic Aquatic Toxicity 555 mg/l (Lepomis macrochirus (bluegill)) mg/l (Daphnia magna (water flea)) ErC50 Aquatic Plants ErC50 Algae mg/l (Desmodesmus subspicatus (algae)) Chemical Name NOEC Fish EC50 Fish NOEC Crustacea EC50 Crustacea ((ethylenedinitrilo) tetraacetato)-, disodium Persistence and Degradability Bioaccumulative Potential 37.2 mg/l (Lepomis macrochirus (bluegill)) 29.5 mg/l (Daphnia magna (water flea)) The product does not show any bioaccumulation phenomena. The product is not expected to harm the environment Page 05 of 07

6 The product does not show any bioaccumulation phenomena. The product is not expected to harm the environment when used properly according to directions. Mobility in Soil If released into the environment, this product can move rapidly through the soil. Other Adverse Effects There is no information available. SECTION 13. DISPOSAL CONSIDERATIONS Disposal Methods Dispose of according to local, provincial and federal government requirements. SECTION 14. TRANSPORT INFORMATION Not regulated under Canadian TDG regulations. Not regulated under US DOT Regulations. Not regulated under IATA Regulations. Special Precautions Transport in Bulk According to Annex II of MARPOL 73/78 and the IBC Code SECTION 15. REGULATORY INFORMATION Safety, Health and Environmental Regulations Canada Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL) Not specifically listed. CEPA - National Pollutant Release Inventory (NPRI) Not specifically listed. Not specifically listed. SECTION 16. OTHER INFORMATION NFPA Rating Health - 2 Flammability - 0 Instability - 0 SDS Prepared By Regulatory and Technical Resources Phone No Date of Preparation Revision Indicators The following SDS content was changed on August 11, 2017: SECTION 12. ECOLOGICAL INFORMATION; Acute Aquatic Toxicity. The following SDS content was changed on August 11, 2017: SECTION 12. ECOLOGICAL INFORMATION; Chronic Aquatic Toxicity. Key to Abbreviations ACGIH = American Conference of Governmental Industrial Hygienists AIHA = AIHA Guideline Foundation HSDB = Hazardous Substances Data Bank IARC = International Agency for Research on Cancer NFPA = National Fire Protection Association NIOSH = National Institute for Occupational Safety and Health NTP = National Toxicology Program OSHA = US Occupational Safety and Health Administration RTECS = Registry of Toxic Effects of Chemical Substances References Registry of Toxic Effects of Chemical Substances (RTECS ) database. Dassault Systèmes/BIOVIA ( BIOVIA ). Available from Canadian Centre for Occupational Health and Safety (CCOHS). CHEMINFO database. Canadian Centre for Occupational Health and Safety (CCOHS). Disclaimer Terralink Horticulture Inc. provides the information contained herein in good faith, but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person Page 06 of 07

7 guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. TERRALINK HORTICULTURE INC. MAKES NO REPRESENTATIONS OR WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, TERRALINK HORTICULTURE INC. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM THE USE OF OR RELIANCE UPON THIS INFORMATION. Page 07 of 07