SAFETY DATA SHEET SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Transcription

1 SAFETY DATA SHEET SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1 Product identifier Product name: Fire Extinguisher Product number: BA24320# Relevant identified uses of the substance or mixture and uses advised against Identified uses: Extinguisher 1.3 Details of the supplier of the safety data sheet Manufacturer: FFE Ltd 9 Hunting Gate Hitchin Hertfordshire SG4 0TJ Emergency telephone number +44-(0) SECTION 2: HAZARDS IDENTIFICATION 2.1 Classification of the substance of mixture Gases under pressure, Liquefied gas Specific target organ toxicity - single exposure, Category 3 H280: Contains gas under pressure; may explode if heated. H336: May cause drowsiness or dizziness. (Central nervous system) Not a hazardous substance or mixture according to EC-directives 67/548/EEC or 1999/45/EC. 2.2 Label elements H280 Contains gas under pressure; may explode if heated. H336 May cause drowsiness or dizziness. Page 1 of 8

2 2.3 Special labelling of certain substances and mixtures; Contains: 1,1,1,3,3,3-Hexafluoropropane / Contains fluorinated greenhouse gas covered by the Kyoto Protocol. P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P233 Keep container tightly closed. P410 + P403 Protect from sunlight. Store in a well-ventilated place. 2.4 Other Hazards This substance is not considered to be persistent, bioaccumulating nor toxic (PBT). This substance is not considered to be very persistent nor very bioaccumulating (vpvb). Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing. Rapid evaporation of the liquid may cause frostbite. May cause cardiac arrhythmia. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1 Mixtures COMPONENTS CAS NUMBER AMOUNT (approx. %) 1,1,1,3,3,3-Hexafluoropropane >= 99 % SECTION 4: FIRST AID MEASURES 4.1 Description of first aid measures Eye: Hold eyelids apart and flush eyes with plenty of water for at least 15 minutes. Get medical attention. Skin: Take off all contaminated clothing immediately. Flush area with lukewarm water. Do not use hot water. If frostbite has occurred, call a physician. Ingestion: Is not considered a potential route of exposure. Inhalation: Remove from exposure, lie down. Move to fresh air. Keep patient warm and at rest. Artificial respiration and/or oxygen may be necessary. Consult a physician. 4.2 Most important symptoms and effects, both acute and delayed Skin contact may provoke the following symptoms: Frostbite, Inhalation may provoke the following symptoms:, Shortness of breath, Dizziness, Weakness, Nausea, Headache, narcosis, Irregular cardiac activity 4.3 Indication of an immediate medical attention and special treatment needed Do not give adrenaline or similar drugs. Page 2 of 8

3 SECTION 5: FIREFIGHTING MEASURES 5.1 Extinguishing media This material is a fire extinguishing agent., Use extinguishing measures that are appropriate to local circumstances and the surrounding environment., such as, Water spray, Foam, Dry chemical, Carbon dioxide (CO2) 5.2 Special hazards arising from the substance or mixture Fire or intense heat may cause violent rupture of packages. Hazardous thermal decomposition products: Carbon oxides Hydrogen fluoride Carbonyl fluoride Fluorocarbons Exposure to decomposition products may be a hazard to health. 5.3 Advice for firefighters In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment. Wear neoprene gloves during cleaning up work after a fire. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Cool containers / tanks with water spray. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures Evacuate personnel to safe areas. Ventilate area, especially low or enclosed places where heavy vapours might collect. Refer to protective measures listed in sections 7 and Environmental precautions Should not be released into the environment. 6.3 Methods and material for containment and cleaning up Evaporates. 6.4 Reference to other sections For disposal instructions see section 13. SECTION 7: HANDLING AND STORAGE 7.1 Precautions for safe handling Avoid breathing vapours or mist. Avoid contact with skin, eyes and clothing. Provide sufficient air exchange and/or exhaust in work rooms. For personal protection see section 8. No special protective measures against fire required. 7.2 Conditions for safe storage, including any incompatibilities Do not drag, slide or roll cylinders. Never attempt to lift cylinder by its cap. Use a check valve or trap in the discharge line to prevent hazardous back flow into the cylinder. Keep at temperature not exceeding 52 C. Keep containers tightly closed in a dry, cool and well-ventilated place. Store in original container. Protect from contamination. Page 3 of 8

4 Storage Temperature: < 52 C 7.3 Specific end use(s) No information available at present. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 Control Parameters If sub-section is empty then no values are applicable. Type of Application (Use): Workers Exposure routes: Inhalation Health Effect: Acute - systemic effects Value: mg/m3 : Type of Application (Use): Consumer use Exposure routes: Inhalation Health Effect: Chronic effects, Systemic effects Value: 1240 mg/m3 : Type of Application (Use): Workers Exposure routes: Inhalation Health Effect: Chronic effects, Systemic effects Value: 4984 mg/m3 8.2 Exposure controls Eye/Face Protection: Safety glasses with side-shields, additionally wear a face shield where the possibility exists for face contact due to splashing, spraying or airborne contact with this material. Skin Protection: Impervious clothing. Heat insulating gloves Respiratory Protection: For rescue and maintenance work in storage tanks use self-contained breathing apparatus. Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on basic physical and chemical properties Form : Liquefied gas Colour : colourless Odour : slight, ether-like Freezing point : -103 C at hpa Boiling point : -2 C at hpa Explosive properties : Not explosive Lower explosion limit/ lower flammability limit : not applicable Upper explosion limit/ upper flammability limit : not applicable Vapour pressure : hpa at 22 C Density : 0,0061-0,0062 g/cm3 at 22,4 C Water solubility : 0,724 g/l at 20 C Partition coefficient: noctanol/water : log Pow: 1,12 at: 20 C, (calculated) Relative vapour density : 6,18 at 20 C 9.2 Other information No other information available. Page 4 of 8

5 SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity Decomposes on heating Chemical stability The product is chemically stable Possibility of hazardous reactions Stable at normal temperatures and storage conditions Conditions to avoid The product is not flammable in air under ambient conditions of temperature and pressure. When pressurised with air or oxygen, the mixture may become flammable. Certain mixtures of HCFCs or HFCs with chlorine may become flammable or reactive under certain conditions Incompatible materials Alkali metals Alkaline earth metals Powdered metals Powdered metal salts 10.6 Hazardous decomposition products Hazardous thermal decomposition products may include: Carbon oxides, Hydrogen fluoride, Carbonyl fluoride, Fluorocarbons. SECTION 11: TOXICOLOGICAL INFORMATION 11.1 Information on toxicological effects Acute oral toxicity not applicable Acute inhalation toxicity LC50 / 4 h rat :> ppm LC50 / 4 h rat :> ppm Narcotic effects Central nervous system effects / dog Cardiac sensitization Acute dermal toxicity Page 5 of 8

6 not applicable Skin irritation Not tested on animals Classification: Not classified as irritant Result: No skin irritation Not expected to cause skin irritation based on expert review of the properties of the substance. Eye irritation Not tested on animals Classification: Not classified as irritant Result: No eye irritation Not expected to cause eye irritation based on expert review of the properties of the substance. Sensitisation Not tested on animals Classification: Not a skin sensitizer. Result: Does not cause skin sensitization. Not expected to cause sensitization based on expert review of the properties of the substance. There are no reports of human respiratory sensitization. Repeated dose toxicity Inhalation rat No toxicologically significant effects were found. Mutagenicity assessment Animal testing did not show any mutagenic effects. Tests on bacterial or mammalian cell cultures did not show mutagenic effects. Carcinogenicity assessment Carcinogenicity classification not possible from current data. Page 6 of 8

7 Toxicity to reproduction assessment No toxicity to reproduction Assessment teratogenicity No toxicity to reproduction Human experience Excessive exposures may affect human health, as follows: Inhalation Severe shortness of breath, narcosis, Irregular cardiac activity Further information Rapid evaporation of the liquid may cause frostbite. Inhalation of decomposition products in high concentration may cause shortness of breath (lung oedema). SECTION 12: ECOLOGICAL INFORMATION 12.1 Toxicity Toxicity to fish LC50 / 96 h / Zebra fish: 292 mg/l Toxicity to aquatic plants ErC50 / 96 h / Pseudokirchneriella subcapitata: > 186 mg/l Toxicity to aquatic invertebrates EC50 / 48 h / Daphnia magna (Water flea): 299 mg/l 12.2 Persistence and degradability Biodegradability / 28 d Biodegradation: 16 % According to the results of tests of biodegradability this product is not readily biodegradable Bioaccumulative potential no data available 12.4 Mobility in soil no data available Page 7 of 8

8 12.5 Results of PBT and vpvb assessment This substance is not considered to be persistent, bioaccumulating nor toxic (PBT). / This substance is not considered to be very persistent nor very bioaccumulating (vpvb) Other adverse effects Ozone depletion potential 0 Global warming potential (GWP) 9500 SECTION 13: DISPOSAL CONSIDERATIONS 13.1 Waste treatment methods Can be used after re-conditioning. In accordance with local and national regulations. Empty pressure vessels should be returned to the supplier. SECTION 14: TRANSPORT INFORMATION 14.1 UN number UN proper shipping name Fire extinguishers containing compressed or liquefied gas Transport hazard class(es) Class 2.2 non-flammable compressed or liquefied gas Packing Group ICAO and IMDG - not applicable Other Information ADR Exempt Special Provision 594 SECTION 15: REGULATORY INFORMATION 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture no data available SECTION 16: OTHER INFORMATION Revision: 1 Safety Data Sheet Approved Date: 24/09/2015 Page 8 of 8