SAFETY DATA SHEET SPRAY POWDER 500 (15 MICRON) / 300 (25 MICRON) / 200 (30 MICRON) / 100 (40 MICRON) / 100 (50 MICRON) INDUSTRIAL GRADE (USA)

Transcription

1 SAFETY DATA SHEET 1. Identification Product identifier Product name SPRAY POWDER 500 (15 MICRON) / 300 (25 MICRON) / 200 (30 MICRON) / 100 (40 MICRON) / 100 Recommended use of the chemical and restrictions on use Application Uses advised against For use as an anti-set off powder in the lithographic printing industry. Spray Powder. No specific uses advised against are identified. Details of the supplier of the safety data sheet Supplier Manufacturer ALLIED PRESSROOM PRODUCTS 2040 Lee Street Hollywood FL USA (09:00-17:00 EST) info@alliedchem.com ABC - ALLIED PRESSROOM PRODUCTS (CHINA) LTD A-2(4) Ind. Area, Bu Chong Village, Sha Jing Town, Baoan, Shenzhen, China (9:00-17:00 CST) info@abcalliedchem.com Emergency telephone number Emergency telephone 24 HR. EMERGENCY TELEPHONE CHEMTREC ABC-Allied (China) (09:00-17:00 CST) Allied Pressroom Products (09:00-17:00 EST) National emergency telephone number Hazard(s) identification Classification of the substance or mixture Physical hazards Not Classified Health hazards Eye Irrit. 2A - H319 Environmental hazards Not Classified Human health Irritating to eyes. Dust may irritate the respiratory system. 1/10

2 Physicochemical Dust may form explosive mixture with air. Not considered to be a significant hazard due to the small quantities used. Label elements Pictogram Signal word Hazard statements Precautionary statements Other hazards Warning H319 Causes serious eye irritation. P280 Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice/attention. This substance is not classified as PBT or vpvb according to current EU criteria. 3. Composition/information on ingredients Mixtures MAIZE STARCH 80-90% CAS number: Classification Not Classified ALUMINIUM SULPHATE 1-5% CAS number: Classification Eye Dam. 1 - H318 The Full Text for all Hazard Statements are Displayed in Section 16. Composition comments 4. First-aid measures Description of first aid measures Inhalation Predominately physically modified vegetable starch. Move affected person to fresh air at once. Get medical attention if any discomfort continues. Ingestion Do not induce vomiting. Rinse mouth thoroughly with water. Give plenty of water to drink. Get medical attention if any discomfort continues. Skin Contact Remove affected person from source of contamination. Wash skin thoroughly with soap and water. Get medical attention if symptoms are severe or persist after washing. Eye contact Remove any contact lenses and open eyelids wide apart. Rinse immediately with plenty of water. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues. 2/10

3 Most important symptoms and effects, both acute and delayed Inhalation Frequent inhalation of dust over a long period of time increases the risk of developing lung diseases. Upper respiratory irritation. Ingestion May cause discomfort if swallowed. Skin contact Prolonged contact may cause redness, irritation and dry skin. Eye contact Dust in the eyes will cause irritation. Indication of immediate medical attention and special treatment needed Notes for the doctor No specific recommendations. 5.Fire-fighting measures Extinguishing media Suitable extinguishing media The product is not flammable. Use fire-extinguishing media suitable for the surrounding fire. Extinguish with the following media: Water spray. Foam. Powder. Special hazards arising from the substance or mixture Specific hazards Dust may form explosive mixture with air. Hazardous combustion products Thermal decomposition or combustion products may include the following substances: Oxides of carbon. Toxic gases or vapors. Advice for firefighters Protective actions during firefighting No specific firefighting precautions known. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Personal precautions For personal protection, see Section 8. Environmental precautions Environmental precautions Not considered to be a significant hazard due to the small quantities used. Methods and material for containment and cleaning up Methods for cleaning up Collect and place in suitable waste disposal containers and seal securely. Label the containers containing waste and contaminated materials and remove from the area as soon as possible. Flush contaminated area with plenty of water. Reference to other sections Wear protective clothing as described in Section 8 of this safety data sheet. 7. Handling and storage Precautions for safe handling Usage precautions Avoid spilling. Avoid contact with skin and eyes. Avoid inhalation of dust. Clean any accumulation of powder from area surrounding point of application or, for example, machine ledges and rafters at regular intervals. 3/10

4 Conditions for safe storage, including any incompatibilities Storage precautions Store in tightly-closed, original container in a dry, cool and well-ventilated place. Specific end uses(s) Specific end use(s) The identified uses for this product are detailed in Section 1.2. Usage description There is the slight possibility of explosive risk if some of the powders are present as a dust cloud above certain concentrations. However, in all cases these levels are unlikely to be reached in normal use provided the powders are used as Anti-Set-Off Powders in accordance with the instructions. Spray the minimum powder sufficient to prevent set off. 8. Exposure Controls/personal protection Control parameters Occupational exposure limits MAIZE STARCH Long-term exposure limit (8-hour TWA): ACGIH 10 mg/m³ Long-term exposure limit (8-hour TWA): OSHA 15 mg/m³ total dust Long-term exposure limit (8-hour TWA): OSHA 5 mg/m³ respirable fraction A4 ACGIH = American Conference of Governmental Industrial Hygienists. OSHA = Occupational Safety and Health Administration. A4 = Not Classifiable as a Human Carcinogen. Exposure controls Protective equipment Appropriate engineering controls No specific ventilation requirements. Provide adequate ventilation. Eye/face protection Eyewear complying with an approved standard should be worn if a risk assessment indicates eye contact is possible. The following protection should be worn: Chemical splash goggles. Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn if a risk assessment indicates skin contact is possible. It is recommended that gloves are made of the following material: Nitrile rubber. Other skin and body protection Wear appropriate clothing to prevent any possibility of skin contact. Hygiene measures Wash hands at the end of each work shift and before eating, smoking and using the toilet. Wash promptly if skin becomes contaminated. Promptly remove any clothing that becomes contaminated. Use appropriate skin cream to prevent drying of skin. When using do not eat, drink or smoke. Do not smoke in work area. Respiratory protection No specific recommendations. Respiratory protection must be used if the airborne contamination exceeds the recommended occupational exposure limit. Protection against nuisance dust must be used when the airborne concentration exceeds 10 mg/m3. 9. Physical and Chemical Properties Information on basic physical and chemical properties 4/10

5 Appearance Dusty powder. Color White. Odor No characteristic odor. Odor threshold ph ph (diluted solution): 1% Melting point No information available. Initial boiling point and range Flash point Evaporation rate Upper/lower flammability or explosive limits Not available. : : Vapour pressure Vapour density Relative density Bulk density kg/m³ Solubility(ies) Insoluble in water. Partition coefficient No information available. Auto-ignition temperature No information available. Decomposition Temperature No information available. Viscosity Oxidising properties Comments Information declared as "Not available" or "Not applicable" is not considered to be relevant to the implementation of the proper control measures. Other information Not available. 10. Stability and reactivity 5/10

6 Reactivity There are no known reactivity hazards associated with this product. Stability Stable at normal ambient temperatures. Possibility of hazardous reactions Will not polymerize. Conditions to avoid Avoid excessive heat for prolonged periods of time. Avoid dust close to ignition sources. Materials to avoid No specific material or group of materials is likely to react with the product to produce a hazardous situation. Hazardous decomposition products Fire creates: Carbon monoxide (CO). Carbon dioxide (CO2). 11. Toxicological information Information on toxicological effects Acute toxicity - oral Acute toxicity - dermal Acute toxicity - inhalation Skin corrosion/irritation Animal data Serious eye damage/irritation Causes eye irritation. Respiratory sensitisation Skin sensitisation Germ cell mutagenicity Genotoxicity - in vitro Does not contain any substances known to be mutagenic. Carcinogenicity Does not contain any substances known to be carcinogenic. Reproductive toxicity Reproductive toxicity - fertility Does not contain any substances known to be toxic to reproduction. Specific target organ toxicity - single exposure STOT - single exposure Specific target organ toxicity - repeated exposure STOT - repeated exposure 6/10

7 Aspiration hazard Not relevant. Inhalation Dust may irritate the respiratory system. Ingestion May cause discomfort if swallowed. Skin Contact Powder may irritate skin. Eye contact Dust in the eyes will cause irritation. Acute and chronic health hazards This product is moderately irritating. Route of entry Inhalation Skin and/or eye contact Target Organs Respiratory system, lungs Skin Eyes 12. Ecological Information Ecotoxicity Not regarded as dangerous for the environment. The product components are not classified as environmentally hazardous. However, large or frequent spills may have hazardous effects on the environment. Toxicity Acute toxicity - fish Not known. Acute toxicity - aquatic invertebrates Not known. Acute toxicity - aquatic plants Not known. Persistance and degradability Persistence and degradability There are no data on the degradability of this product. Bioaccumulative potential No data available on bioaccumulation. Partition coefficient No information available. Mobility in soil Mobility The product has poor water-solubility. Results of PBT and vpvb assessment This substance is not classified as PBT or vpvb according to current EU criteria. Other adverse effects Not known. 13. Disposal considerations Waste treatment methods 7/10

8 General information When handling waste, the safety precautions applying to handling of the product should be considered. Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the local Waste Disposal Authority. 14. Transport information General The product is not covered by international regulations on the transport of dangerous goods (IMDG, IATA, DoT). UN Number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards Environmentally Hazardous Substance No. Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information US Federal Regulations SARA Section 302 Extremely Hazardous Substances Tier II Threshold Planning Quantities CERCLA/Superfund, Hazardous Substances/Reportable Quantities (EPA) ALUMINIUM SULPHATE 1-5% SARA Extremely Hazardous Substances EPCRA Reportable Quantities SARA 313 Emission Reporting CAA Accidental Release Prevention FDA - Essential Chemical FDA - Precursor Chemical OSHA Highly Hazardous Chemicals US State Regulations 8/10

9 California Proposition 65 Carcinogens and Reproductive Toxins California Air Toxics "Hot Spots" (A-I) California Air Toxics "Hot Spots" (A-II) California Directors List of Hazardous Substances ALUMINIUM SULPHATE 1-5% Massachusetts "Right To Know" List MAIZE STARCH 80-90% ALUMINIUM SULPHATE 1-5% Rhode Island "Right To Know" List MAIZE STARCH 80-90% Minnesota "Right To Know" List MAIZE STARCH 80-90% New Jersey "Right To Know" List ALUMINIUM SULPHATE 1-5% Pennsylvania "Right To Know" List MAIZE STARCH 80-90% ALUMINIUM SULPHATE 1-5% Inventories Canada - DSL/NDSL All the ingredients are listed or exempt. DSL US - TSCA All the ingredients are listed or exempt. US - TSCA 12(b) Export Notification 16. Other information Key literature references and sources for data Material Safety Data Sheet, Misc. manufacturers. Revision comments NOTE: Lines within the margin indicate significant changes from the previous revision. Issued by J Waterfield Revision date 2/17/2015 9/10

10 Revision 10.0 Supersedes date 3/27/2012 SDS No Hazard statements in full H318 Causes serious eye damage. H319 Causes serious eye irritation. ACA HMIS Health rating. Moderate hazard. (2) ACA HMIS Physical hazard rating. ACA HMIS Personal protection rating. ACA HMIS Flammability rating. Normally stable. (0) C Burns only if pre-heated. (1) Disclaimer This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 10/10