Safety data sheet Na-Methylate Crystals Revision date : 2006/07/05 Page: 1/7

Transcription

1 Revision date : 2006/07/05 Page: 1/7 1. Substance/preparation and company identification Company BASF CORPORATION 100 Campus Drive Florham Park, NJ Hour Emergency Response Information CHEMTREC: BASF HOTLINE: HELP Molecular formula: Chemical family: Synonyms: CH(3)ONa alcohol, sodium salt Sodium Methoxide 2. Composition/information on ingredients CAS Number Content (W/W) Chemical name >= 98.0 % sodium methanolate 3. Hazard identification Emergency overview DANGER: EXTREMELY FLAMMABLE. REACTS VIOLENTLY WITH WATER. CAUSES SEVERE BURNS. Use with local exhaust ventilation. Wear NIOSH-certified chemical goggles. Wear protective clothing. Wear a NIOSH-certified (or equivalent) organic vapour respirator. Wear chemical resistant protective gloves. Eye wash fountains and safety showers must be easily accessible. Potential health effects Primary routes of exposure Routes of entry for solids and liquids include eye and skin contact, ingestion and inhalation. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of entry for liquified gases. Acute toxicity: Toxic by inhalation and if swallowed. Repeated dose toxicity: The substance may cause blindness after repeated ingestion. The substance may cause blindness after repeated inhalation.

2 Revision date : 2006/07/05 Page: 2/7 4. First-aid measures General advice: Avoid contact with the skin, eyes and clothing. Immediately remove contaminated clothing. If inhaled: Remove the affected individual into fresh air and keep the person calm. Assist in breathing if necessary. Immediate medical attention required. If on skin: Wash affected areas with water while removing contaminated clothing. Immediate medical attention required. If in eyes: In case of contact with the eyes, rinse immediately for at least 15 minutes with plenty of water. Immediate medical attention required. If swallowed: Immediately rinse mouth and then drink plenty of water, do not induce vomiting, seek medical attention. Administer 50 ml of pure ethanol in a drinkable concentration. Seek medical attention. Rinse mouth and then drink plenty of water. Do not induce vomiting. Never induce vomiting or give anything by mouth if the victim is unconscious or having convulsions. Immediate medical attention required. 5. Fire-fighting measures Self-ignition temperature: > 50 C (Directive 84/449/EEC, A.16) Suitable extinguishing media: dry extinguishing media, sand Unsuitable extinguishing media for safety reasons: water, foam, carbon dioxide Protective equipment for fire-fighting: Firefighters should be equipped with self-contained breathing apparatus and turn-out gear. Further information: Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems. Dispose of fire debris and contaminated extinguishing water in accordance with official regulations. NFPA Hazard codes: Health : 3 Fire: 3 Reactivity: 2 Special: 6. Accidental release measures Personal precautions: Avoid contact with the skin, eyes and clothing. Use breathing apparatus if exposed to vapours/dust/aerosol. Environmental precautions: Discharge into the environment must be avoided.

3 Revision date : 2006/07/05 Page: 3/7 Substance/product is RCRA hazardous due to its properties. Cleanup: For small amounts: Sweep/shovel up. Correctly dispose of recovered product immediately. For large amounts: Sweep/shovel up. Correctly dispose of recovered product immediately. 7. Handling and storage Handling General advice: Use with local exhaust ventilation. Avoid dust formation. Protect against moisture. Protect from air. Protect from direct sunlight. Containers should be opened carefully in well-ventilated areas to avoid static discharge. Protection against fire and explosion: Take precautionary measures against static discharges. Sources of ignition should be kept well clear. Fire extinguishers should be kept handy. Dust can form an explosive mixture with air. Storage General advice: Keep container tightly closed in a cool, well-ventilated place. Keep under nitrogen. Storage incompatibility: General: Segregate from acids and acid forming substances. Storage stability: Protect against moisture. 8. Exposure controls and personal protection Advice on system design: Provide local exhaust ventilation to control dust. Personal protective equipment Respiratory protection: Wear a NIOSH-certified (or equivalent) particulate respirator. Do not exceed the maximum use concentration for the respirator facepiece/cartridge combination. Hand protection: Chemical resistant protective gloves, Suitable materials, butyl rubber Eye protection: Tightly fitting safety goggles (chemical goggles) and face shield. Body protection: Protective coverall and/or impermeable apron and boots as necessary. General safety and hygiene measures: Avoid contact with the skin, eyes and clothing. Do not breathe dust. Eye wash fountains and safety showers must be easily accessible. Wear protective clothing as necessary to prevent contact. 9. Physical and chemical properties Form: Odour: Colour: powder, crystalline odourless colourless

4 Revision date : 2006/07/05 Page: 4/7 ph value: 12.8 ( 10 g/l, 20 C) Bulk density: kg/m3 ( < 40 C) (DIN 53466) Partitioning coefficient n ( 25 C) octanol/water (log Pow): Solubility in water: hydrolyzes, spontaneous decomposition Solubility (qualitative): soluble solvent(s): alcohols, 10. Stability and reactivity Conditions to avoid: Avoid all sources of ignition: heat, sparks, open flame. Avoid moisture. Avoid electro-static charge. Avoid heat. Substances to avoid: water, acids Hazardous reactions: Exothermic reaction. Reacts with water and acids. Reacts with substances which contain active hydrogen. Self heating possible in the presence of air. Accumulation of fine dust may entail the risk of a dust explosion in the presence of air. Decomposition products: Hazardous decomposition products: Methanol, Sodium Hydroxide Thermal decomposition: > 280 C (DTA) Thermal decomposition above the indicated temperature is possible. The indicated value is for inert gas atmosphere. > 50 C (VDI 2263, sheet 1, 1.4.1) Risk of spontaneous ignition when exposed to air. 11. Toxicological information Acute toxicity Oral: LD50/rat: 800 mg/kg Inhalation: rat: / 7 h(irt) Inhalation-risk test (IRT): No mortality within 7 hours as shown in animal studies. The inhalation of a highly saturated vapor-air mixture represents no acute hazard. Dermal: LD50/rat: > 2,000 mg/kg Skin irritation: rabbit: strongly corrosive (BASF-Test) Eye irritation : As the product corrodes the skin, it can be expected to have a similar effect on the eyes also. Chronic toxicity

5 Revision date : 2006/07/05 Page: 5/7 Other information: The toxicity of the product is based on its corrosivity. The data given refers to the decomposition or transformation products. 12. Ecological information Test method: OECD 301D; EEC 92/69, C.4-E (aerobic), Method of analysis: BOD of the ThOD Degree of elimination: 95 % (20 d) Evaluation: Readily biodegradable (according to OECD criteria). Readily biodegradable (according to OECD criteria). Information on: Sodium Hydroxide Accumulation in organisms is not to be expected. No significant accumulation in organisms is expected as a result of the distribution coefficient of n- octanol/water (log Pow). Adsorbable organically-bound halogen (AOX): This product contains no organically-bound halogen. Environmental toxicity Information on: Sodium Hydroxide Acute and prolonged toxicity to fish: other static Rainbow trout/lc50 (96 h): 45.4 mg/l The product will cause changes in the ph value of the test system. The result refers to an unneutralized sample. Acute and prolonged toxicity to fish: other Flow through. sunfish, bluegill/lc50 (96 h): 15,400 mg/l Information on: Sodium Hydroxide Acute toxicity to aquatic invertebrates: other static Ceriodaphnia sp./ec50 (48 h): 40.4 mg/l The product will cause changes in the ph value of the test system. The result refers to an unneutralized sample. Acute toxicity to aquatic invertebrates: DIN Part 11 static Daphnia magna/ec50 (48 h): > 10,000 mg/l Toxicity to aquatic plants: other static

6 Revision date : 2006/07/05 Page: 6/7 green algae/toxic limit concentration (192 h): 8,000 mg/l Toxicity to microorganisms: other aquatic Bacteria/Toxic limit concentration (16 h): 6,600 mg/l Other ecotoxicological advice: Do not release untreated into natural waters. Due to the ph-value of the product, neutralization is generally required before discharging sewage into treatment plants. Inhibition of degradation activity in activated sludge is not to be anticipated during correct introduction of low concentrations. The local regulations on waste-water treatment must be followed. 13. Disposal considerations Container disposal: Dispose of in accordance with national, state and local regulations. Recommend crushing, puncturing or other means to prevent unauthorized use of used containers. RCRA: D Transport information Land transport USDOT Proper shipping name: SODIUM METHYLATE Hazard class: 4.2 ID number: UN 1431 Packing group: II Sea transport IMDG Proper shipping name: SODIUM METHYLATE Hazard class: 4.2 ID number: UN 1431 Packing group: II Marine pollutant: NO Air transport IATA/ICAO Proper shipping name: SODIUM METHYLATE Hazard class: 4.2 ID number: UN 1431 Packing group: II Further information

7 Revision date : 2006/07/05 Page: 7/7 Specific national features of transport regulations must be observed. They are to be found in the shipping documents. 15. Regulatory information Federal Regulations Registration status: TSCA, US released / listed OSHA hazard category: Chronic target organ effects reported, Acute target organ effects reported, Flammable Liquid, OSHA PEL established, Corrosive to skin and/or eyes, ACGIH TLV established CERCLA RQ CAS Number Chemical name 1,000 LBS ; sodium methanolate; Sodium Hydroxide 5,000 LBS Methanol SARA hazard categories (EPCRA 311/312): Chronic, Fire, Acute State regulations State RTK CAS Number Chemical name State RTK sodium methanolate MA, NJ, PA 16. Other information HMIS III rating Health: 3 Flammability: 3 Physical hazard: 2 HMIS uses a numbering scale ranging from 0 to 4 to indicate the degree of hazard. A value of zero means that the substance possesses essentially no hazard; a rating of four indicates high hazard. Local contact information prod_reg@basf.com IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY UNDERSTAND AND AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY BASF HEREUNDER ARE GIVEN GRATIS AND BASF ASSUMES NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. END OF DATA SHEET