MATERIAL SAFETY DATA SHEET

Transcription

1 Product Trade Name: MATERIAL SAFETY DATA SHEET Revision Date: 03-Jan IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Statement of Hazardous Nature Manufacturer/Supplier Hazardous according to the criteria of NOHSC, Dangerous Goods according to the criteria of ADG. Halliburton Australia Pty. Ltd. 15 Marriott Road Jandakot WA 6164 Australia Identification of Substances or Preparation ACN Number: Telephone Number: 61 (08) Fax Number: 61 (08) Product Emergency Telephone Australia: Papua New Guinea: NewZealand: Fire, Police & Ambulance - Emergency Telephone Australia: 000 Papua New Guinea: 000 New Zealand: 111 Product Trade Name: Synonyms: None Chemical Family: Not applicable UN Number:, UN3088 Dangerous Goods Class: 4.2 Subsidiary Risk: None Hazchem Code: None Allocated Poisons Schedule: None Allocated Application: Additive Prepared By Chemical Compliance Telephone: fdunexchem@halliburton.com 2. COMPOSITION/INFORMATION ON INGREDIENTS Substances CAS Number PERCENT Australia New Zealand ACGIH TLV-TWA NOHSC WES 2,2`-Azobis(2-amidopropane) dihydrochloride % Not applicable Not applicable Not applicable Page 1 of 6

2 3. HAZARDS IDENTIFICATION Non-Hazardous Substance to Total of 100% Hazard Overview May cause eye and skin irritation. May cause headache and nausea. May cause allergic skin reaction. May be harmful if swallowed. Airborne dust may be explosive. Risk Phrases R22 Harmful if swallowed. R43 May cause sensitization by skin contact. HSNO Classification 4. FIRST AID MEASURES Inhalation Skin Eyes Ingestion Notes to Physician If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult. Wash with soap and water. Remove contaminated clothing and launder before reuse. Get medical attention if irritation persists. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention if irritation persists. If swallowed, induce vomiting immediately by giving two glasses of water and sticking fingers down throat; never give anything to an unconscious person. Get medical attention. 5. FIRE FIGHTING MEASURES Suitable Extinguishing Media Extinguishing media which must not be used for safety reasons Special Exposure Hazards Water fog, carbon dioxide, foam, dry chemical. Organic dust in the presence of an ignition source can be explosive in high concentrations. Good housekeeping practices are required to minimize this potential. Special Protective Equipment for Fire-Fighters 6. ACCIDENTAL RELEASE MEASURES Full protective clothing and approved self-contained breathing apparatus required for fire fighting personnel. Personal Precautionary Measures Use appropriate protective equipment. Avoid creating and breathing dust. Environmental Precautionary Measures Procedure for Cleaning / Absorption Scoop up and remove. Flush area with water. 7. HANDLING AND STORAGE Handling Precautions Avoid contact with eyes, skin, or clothing. Wash hands after use. Avoid contact with persulfate which can lead to the formation of shock and friction sensitive mixtures. Page 2 of 6

3 Storage Information Store away from direct sunlight. Store in a cool well ventilated area. Keep from heat, sparks, and open flames. Keep away from friction, impact, and heat. Container should NOT be closed tightly. Product has a shelf life of 12 months. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Controls Respiratory Protection Hand Protection Skin Protection Eye Protection Other Precautions Use in a well ventilated area. Localized ventilation should be used to control dust levels. Organic vapor respirator with a dust/mist filter. (A2P2/P3) Impervious rubber gloves. Normal work coveralls. Dust proof goggles. Eyewash fountains and safety showers must be easily accessible. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: Off white Odor: Odorless ph: Specific 20 C (Water=1): C (kg/l): Bulk 20 C (kg/m 3 ): Boiling Point/Range (C): Freezing Point/Range (C): Pour Point/Range (C): Flash Point/Range (C): Flash Point Method: Autoignition Temperature (C): Flammability Limits in Air - Lower (g/m 3 ): Flammability Limits in Air - Lower (%): Flammability Limits in Air - Upper (g/m 3 ): Flammability Limits in Air - Upper (%): Vapor 20 C (mmhg): Vapor Density (Air=1): Percent Volatiles: Evaporation Rate (Butyl Acetate=1): Solubility in Water (g/100ml): 23.2 Solubility in Solvents (g/100ml): VOCs (g/l): Viscosity, 20 C (centipoise): Viscosity, 20 C (centistokes): Partition Coefficient/n-Octanol/Water: Molecular Weight (g/mole): Decomposition Temperature (C): 10. STABILITY AND REACTIVITY Stability Data: Hazardous Polymerization: Conditions to Avoid Stable Will Not Occur Keep away from heat, sparks and flame. Avoid contact with sunlight. Page 3 of 6

4 Incompatibility (Materials to Avoid) Hazardous Decomposition Products Additional Guidelines Strong oxidizers. Strong alkalis. Hydrogen chloride. Oxides of nitrogen. Carbon monoxide and carbon dioxide. Not Applicable 11. TOXICOLOGICAL INFORMATION Principle Route of Exposure Eye or skin contact, inhalation. Sympotoms related to exposure Inhalation May cause respiratory irritation. May cause central nervous system depression including headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and unconsciousness. Skin Contact Eye Contact Ingestion Aggravated Medical Conditions Chronic Effects/Carcinogenicity Other Information May cause skin irritation. May be absorbed through the skin and contribute to the symptoms listed under ingestion. May cause an allergic skin reaction. May cause eye irritation. Irritation of the mouth, throat, and stomach. May cause headache, dizziness, nausea, vomiting, gastrointestinal irritation and central nervous system depression. Skin disorders. Eye ailments. No data available to indicate product or components present at greater than 1% are chronic health hazards. Toxicity Tests Oral Toxicity: Dermal Toxicity: Inhalation Toxicity: Primary Irritation Effect: Carcinogenicity Genotoxicity: Reproductive / Developmental Toxicity: 12. ECOLOGICAL INFORMATION Mobility (Water/Soil/Air) Persistence/Degradability Bio-accumulation Ecotoxicological Information Page 4 of 6

5 Acute Fish Toxicity: Acute Crustaceans Toxicity: Acute Algae Toxicity: Chemical Fate Information Other Information Not applicable 13. DISPOSAL CONSIDERATIONS Disposal Method Contaminated Packaging Disposal should be made in accordance with federal, state, and local regulations. Follow all applicable national or local regulations. 14. TRANSPORT INFORMATION Land Transportation ADR UN3088,Self-heating, Solid, Organic, N.O.S.(2,2'-Azobis (2-Amidinopropane) Dihydrochloride), 4.2, II Air Transportation ICAO/IATA UN3088,Self-heating, Solid, Organic, N.O.S., 4.2, II (2,2'-Azobis (2-Amidinopropane) Dihydrochloride) Sea Transportation IMDG UN3088,Self-heating, Solid, Organic, N.O.S.(2,2'-Azobis (2-Amidinopropane) Dihydrochloride), 4.2, II EmS F-A, S-J Other Transportation Information Labels: Spontaneously Combustible 15. REGULATORY INFORMATION Chemical Inventories Australian AICS Inventory New Zealand Inventory of Chemicals US TSCA Inventory EINECS Inventory All components listed on inventory or are exempt. This product does not comply with NZIOC All components listed on inventory or are exempt. This product, and all its components, complies with EINECS Classification Xn - Harmful. Risk Phrases R22 Harmful if swallowed. R43 May cause sensitization by skin contact. Page 5 of 6

6 Safety Phrases S2 Keep out of reach of children. S24 Avoid contact with skin. S37 Wear suitable gloves. 16. OTHER INFORMATION The following sections have been revised since the last issue of this SDS Not applicable Contact Australian Poisons Information Centre 24 Hour Service: Police or Fire Brigade: (exchange): New Zealand National Poisons Centre Additional Information For additional information on the use of this product, contact your local Halliburton representative. For questions about the Safety Data Sheet for this or other Halliburton products, contact Chemical Compliance at Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtained from various sources including the manufacturer and other third party sources. The information may not be valid under all conditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of any material is the sole responsibility of the user. ***END OF MSDS*** Page 6 of 6