SAFETY DATA SHEET: GUGOLZ PITCH

Transcription

1 SECTION 1: CHEMICAL PRODUCT & COMPANY INFORMATION APPLICABLE PART #: PG0055, PG0064, PG0073, IDENTITY: Gugolz 55, Gugolz 64, Gugolz 73 PG0082, PG0091 Gugolz 82, Gugolz 91 SUPPLIER: Universal Photonics, Inc. FOR INFORMATION CALL 85 Jetson Lane CUSTOMER SERVICE (516) Central Islip, NY DATE PREPARED: September 7, 2016 EMERGENCY TELEPHONE NUMBER: E COMPANY - ACCT # 3665 SECTION 2: HAZARDS IDENTIFICATION CLASSIFICATION OF THE SUBSTANCE OR MIXTURE: CLASSIFICATION ACCORDING TO REGULATION (EC) NO 1272/2008: Skin Sens. 1 H317 May Cause an allergic skin reaction. GHS07 CLASSIFICATION ACCORDING TO DIRECTIVE 67/548/EEC OR DIRECTIVE 1999/45/EC: Xi; Sensitizing R43: May cause sensitization by skin contact. INFORMATION CONCERNING PARTICULAR HAZARDS FOR HUMAN AND ENVIRONMENT: CLASSIFICATION SYSTEM: The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. The classification is according to the latest editions of the EU-lists, and extended by company and literature data. LABEL ELEMENTS: LABELLING ACCORDING TO EU REGULATION (EC) NO 1272/2008: The product is classified and labelled according to the CLP regulation. HAZARD PICTOGRAM: GHS07 SIGNAL WORD: Warning HAZARD-DETERMINING COMPONENTS OF LABELLING: Gum Rosin Kolophonium 1

2 HAZARD STATEMENTS: PRECAUTIONARY STATEMENTS: H317 May cause an allergic skin reaction. P102 Keep out of reach of children. P261 Avoid breathing vapors. P280 Wear protective gloves/ protective clothing/eye protection/face protection. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P302+P352 If on skin: Wash with plenty of water. P501 Dispose of contents/container in accordance with local/regional/national/international regulations OTHER HAZARDS RESULTS OF PBT AND VPVB ASSESSMENT PBT: VPVB: SECTION 3: COMPOSITION INFORMATION COMPONENTS CAS #/EINECS WEIGHT % Xi R43 Gum Rosin % Skin Sens. 1, H317 Kolophonium Asphalt Substance with a community workplace exposure limit % SECTION 4: FIRST AID MEASURES AFTER INHALATION: AFTER SKIN CONTACT: AFTER EYE CONTACT: AFTER SWALLOWING: Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation. Immediately wash with water and soap and rinse thoroughly. Rinse opened eye for several minutes under running water. If symptoms persist consult doctor. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED: INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED: 2

3 SECTION 5: FIRE FIGHTING MEASURES SUITABLE EXTINGUISHING AGENTS: Use fire extinguishing methods suitable to surrounding conditions. FOR SAFETY REASONS UNSUITABLE EXTINGUISHING AGENTS: Carbon Dioxide SPECIFIC HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE: ADVICE FOR FIREFIGHTERS: PROTECTIVE EQUIPMENT: No special measures required. SECTION 6: ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES: ENVIRONMENTAL PRECAUTIONS: Not required Do not allow to enter sewers/surface or ground water. METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP: Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. REFERENCE TO OTHER SECTIONS: See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. SECTION 7: HANDLING & STORAGE HANDLING PRECAUTIONS FOR SAFE HANDLING: Ensure good ventilation/exhaustion at the workplace. INFORMATION ABOUT FIRE AND EXPLOSION PROTECTION: No special measures required. STORAGE: REQUIREMENTS TO BE MET BY STOREROOMS AND RECEPTACLES: No special requirements. INFORMATION ABOUT STORAGE IN ONE COMMON STORAGE FACILITY: Not required. FURTHER INFORMATION ABOUT STORAGE CONDITIONS: SPECIFIC END USE(S): None. 3

4 SECTION 8: PERSONAL PROTECTION AND EXPOSURE CONTROLS ADDITIONAL INFORMATION ABOUT DESIGN OF TECHNICAL FACILITIES: No further data; see item 7. CONTROL PARAMETERS INGREDIENTS WITH LIMIT VALUES THAT REQUIRE MONITORING AT THE WORKPLACE ROSIN: WEL: Short term value: 0.15 mg/m3 Long term value: 0.05 mg/m3 Sen ASPHALT: WEL: Short term value: 10 mg/m3 Long term value: 5 mg/m3 ADDITIONAL INFORMATION: The lists valid during the making were used as basis. EXPOSURE CONTROLS PERSONAL PROTECTIVE EQUIPMENT GENERAL PROTECTIVE AND HYGIENIC MEASURES: RESPIRATORY PROTECTION: PROTECTION OF HANDS: Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Do not inhale gases/fumes/aerosols. In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device. The glove material has to be impermeable and resistant to the product/the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/the preparation/the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation. MATERIAL OF GLOVES: The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material cannot be calculated in advance and has therefore to be checked prior to the application. 4

5 EYE PROTECTION: PENETRATION TIME OF GLOVE MATERIAL: The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Not required. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: FORM: COLOR: Solid Black ODOR: ODOR THRESHOLD: PH VALUE: MELTING POINT/MELTING RANGE: BOILING POINT/BOILING POINT RANGE: FLASH POINT: FLAMMABILITY (SOLID, GASEOUS): IGNITION TEMPERATURE: DECOMPOSITION TEMPERATURE: SELF-IGNITING: DANGER OF EXPLOSION: EXPLOSION LIMITS: VAPOR PRESSURE: Characteristic Not determined Not applicable Undetermined. 469 C 230 C Not determined 340 C Not determined. Product is not self-igniting. Product does not present an explosion hazard Lower: Not determined. Upper: Not determined. DENSITY AT 20 C: g/cm 3 RELATIVE DENSITY: VAPOR DENSITY: EVAPORATION RATE: SOLUBILITY IN/MISCIBILITY WITH WATER: PARTITION COEFFICIENT (N-OCTANOL/WATER): Not determined. Insoluble. Not determined. 5

6 VISCOSITY: DYNAMIC: KINEMATIC: ORGANIC SOLVENTS: 0.0% SOLIDS CONTENT: 100.0% OTHER INFORMATION: No further relevant information available, SECTION 10: STABILITY & REACTIVITY REACTIVITY CHEMICAL STABILITY THERMAL DECOMPOSITION/ CONDITIONS TO BE AVOIDED: No decomposition if used according to specifications. POSSIBILITY OF HAZARDOUS REACTIONS: No dangerous reactions known. CONDITIONS TO AVOID: INCOMPATIBLE MATERIALS: HAZARDOUS DECOMPOSITION PRODUCTS: No dangerous decomposition products are known. SECTION 11: TOXICOLOGICAL INFORMATION ACUTE TOXICITY: PRIMARY IRRITANT EFFECT SKIN CORROSION/IRRITATION: SERIOUS EYE DAMAGE/IRRITATION: RESPIRATORY OR SKIN SENSITIZATION: May cause an allergic skin reaction. CMR EFFECTS (CARCINOGENITY, MUTAGENICITY, AND TOXICITY FOR REPRODUCTION) GERM CELL MUTAGENICITY: CARCINOGENICITY: REPRODUCTIVE TOXICITY: STOT-SINGLE EXPOSURE: 6

7 STOT-REPEATED EXPOSURE: ASPIRATION HAZARD: SECTION 12: ECOLOGICAL INFORMATION AQUATIC TOXICITY: PERSISTENCE AND DEGRADABILITY: BEHAVIOR IN ENVIRONMENTAL SYSTEMS: BIOACCUMULATIVE POTENTIAL: MOBILITY IN SOIL: GENERAL NOTES: RESULTS OF PBT AND VPVB ASSESSMENT: OTHER ADVERSE EFFECTS: Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water. Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. PBT: vpvb: SECTION 13: DISPOSAL INFORMATION WASTE TREATMENT METHODS: UNCLEANED PACKAGING: Recommendation: Must not be disposed together with household garbage. Do not allow product to reach sewage system. Disposal must be made according to official regulations. SECTION 14: TRANSPORTATION INFORMATION UN-NUMBER: ADR, ADN, IMDG, IATA: Void UN PROPER SHIPPING NAME: ADR, ADN, IMDG, IATA: Void TRANSPORT HAZARD CLASS(ES): ADR, ADN, IMDG, IATA: Void PACKING GROUP: ADR, IMDG, IATA: Void 7

8 ENVIRONMENTAL HAZARDS: MARINE POLLUTANT: No SPECIAL PRECAUTIONS FOR USER: TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE: UN MODEL REGULATION : - SECTION 15: REGULATORY INFORMATION SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS ACCORDING TO EU GUIDELINES: None of the ingredients is listed SECTION 16: OTHER INFORMATION HMIS RATING: Health 0, Flammability 1, Physical Hazard 0, Personal Protection B NFPA RATING: Health 0, Flammability 1, Physical Hazard ABBREVIATIONS AND ACRONYMS: DOT Department of Transportation GHS The Globally Harmonized System of Classification and Labeling of Chemicals HMIS Hazardous Materials Identification System NIOSH National Institute for Occupational Safety and Health NORM Natural Occurring Radioactive Materials IATA International Air Transportation Association IMO International Maritime Organization OSHA Occupational Safety & Health Administration TSCA Toxic Substance Control Act DISCLAIMER WHILE UNIVERSAL PHOTONICS, INC. BELIEVES THAT THE DATA AND INFORMATION CONTAINED HEREIN ARE FACTUAL AND THE OPINIONS ARE THOSE OF QUALIFIED EXPERTS, THEY ARE NOT TO BE TAKEN AS A WARRANTY OR REPRESENTATION FOR WHICH UNIVERSAL PHOTONICS, INC. ASSUMES ANY LEGAL RESPONSIBILITY. THEY ARE OFFERED SOLEY FOR THE CONSIDERATION, INVESTIGATION AND VERIFICATION BY THE USER. IT IS THE USER S RESPONSIBILITY TO DETERMINE THE SUITABILITY OF THIS PRODUCT, DATA AND INFORMATION WITH APPLICABLE LAWS AND REGULATIONS.pitchgugolz sds 8