SAFETY DATA SHEET. 1. Identification. 2. Hazard(s) identification. 3. Composition/information on ingredients. Product number

Transcription

1 SAFETY DATA SHEET 1. Identification Product number Product identifier Company information 5 GAL GOLD COAST CHEM PROTECTO FLEX LB GOLD COAST CHEMICAL PRODUCTS 2357 STIRLING RD. DANIA BEACH, FL United States Company phone General Assistance Emergency telephone US Emergency telephone outside US Version # 01 Recommended use Recommended restrictions Coating ne known. 2. Hazard(s) identification Physical hazards Health hazards Environmental hazards OSHA defined hazards Label elements Flammable liquids Germ cell mutagenicity Carcinogenicity Specific target organ toxicity, repeated exposure Aspiration hazard t classified. t classified. Category 3 Category 1B Category 1B Category 1 Category 1 Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Hazard(s) not otherwise classified (HNOC) Supplemental information Danger Flammable liquid and vapor. May be fatal if swallowed and enters airways. May cause genetic defects. May cause cancer. Causes damage to organs through prolonged or repeated exposure. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe mist or vapor. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves/protective clothing/eye protection/face protection. If swallowed: Immediately call a poison center/doctor. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If exposed or concerned: Get medical advice/attention. Do NOT induce vomiting. In case of fire: Use appropriate media to extinguish. Store in a well-ventilated place. Keep cool. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations. ne known. ne. 3. Composition/information on ingredients Mixtures 1 / 8

2 Chemical name Common name and synonyms CAS number % Mineral Spirits Synthetic Isoparaffinic Hydrocarbon Other components below reportable levels *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information Move to fresh air. Call a physician if symptoms develop or persist. Take off immediately all contaminated clothing. Rinse skin with water/shower. Get medical attention if irritation develops and persists. Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Get medical attention if irritation develops and persists. Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Dizziness. Irritation of eyes and mucous membranes. Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Prolonged exposure may cause chronic effects. Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water immediately. While flushing, remove clothes which do not adhere to affected area. Call an ambulance. Continue flushing during transport to hospital. Keep victim under observation. Symptoms may be delayed. Take off all contaminated clothing immediately. IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Wash contaminated clothing before reuse. 5. Fire-fighting measures Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire-fighting equipment/instructions Specific methods General fire hazards 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Do not use water jet as an extinguisher, as this will spread the fire. Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source of ignition and flash back. During fire, gases hazardous to health may be formed. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do so without risk. Use standard firefighting procedures and consider the hazards of other involved materials. Flammable liquid and vapor. Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate protective equipment and clothing during clean-up. Do not breathe mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take precautionary measures against static discharge. Use only non-sparking tools. Keep combustibles (wood, paper, oil, etc.) away from spilled material. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. 2 / 8

3 Environmental precautions Avoid discharge into drains, water courses or onto the ground. 7. Handling and storage Precautions for safe handling Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Explosion-proof general and local exhaust ventilation. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Use non-sparking tools and explosion-proof equipment. Do not breathe mist or vapor. When using, do not eat, drink or smoke. Should be handled in closed systems, if possible. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Observe good industrial hygiene practices. Conditions for safe storage, including any incompatibilities Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge build-up by using common bonding and grounding techniques. Store in a cool, dry place out of direct sunlight. Store in original tightly closed container. Store in a well-ventilated place. Refrigeration recommended. Keep in an area equipped with sprinklers. Store away from incompatible materials (see Section 10 of the SDS). 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) Components Type Value Mineral Spirits (CAS ) US. ACGIH Threshold Limit Values Components PEL Type 2900 mg/m3 500 ppm Value Mineral Spirits (CAS ) TWA US. NIOSH: Pocket Guide to Chemical Hazards Components Type 100 ppm Value Mineral Spirits (CAS ) Biological limit values Appropriate engineering controls Ceiling TWA biological exposure limits noted for the ingredient(s) mg/m3 350 mg/m3 Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment Eye/face protection Chemical respirator with organic vapor cartridge and full facepiece. Hand protection Skin protection Other Skin protection Respiratory protection Thermal hazards General hygiene considerations 9. Physical and chemical properties Appearance Odor Physical state Form Color Wear appropriate chemical resistant gloves. Wear suitable protective clothing. Use of an impervious apron is recommended. Chemical respirator with organic vapor cartridge and full facepiece. Wear appropriate thermal protective clothing, when necessary. When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Liquid. Liquid. 3 / 8

4 Odor threshold ph Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) 302 F (150 C) estimated F (38.0 C) estimated Upper/lower flammability or explosive limits Flammability limit - lower 0.9 % estimated (%) Flammability limit - upper (%) Explosive limit - lower (%) Explosive limit - upper (%) Vapor pressure Vapor density Relative density Solubility(ies) Solubility (water) Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity Other information Specific gravity estimated 743 F (395 C) estimated estimated 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products The product is stable and non-reactive under normal conditions of use, storage and transport. Material is stable under normal conditions. Hazardous polymerization does not occur. Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials. Strong oxidizing agents. hazardous decomposition products are known. 11. Toxicological information Information on likely routes of exposure Ingestion Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia. Inhalation Skin contact Eye contact Symptoms related to the physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity May cause damage to organs through prolonged or repeated exposure by inhalation. adverse effects due to skin contact are expected. Direct contact with eyes may cause temporary irritation. Dizziness. Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Irritation of eyes and mucous membranes. May be fatal if swallowed and enters airways. 4 / 8

5 Components Species Synthetic Isoparaffinic Hydrocarbon (CAS ) Acute Dermal LD50 Rabbit Inhalation LC50 Rat Oral LD50 Rat Test Results > 1900 mg/kg, 24 Hours > 5020 mg/m3, 4 Hours > 4980 mg/m3 > 4980 mg/m3, 4 Hours > 4.96 mg/l, 4 Hours 4820 mg/kg * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Skin sensitization Germ cell mutagenicity Carcinogenicity Prolonged skin contact may cause temporary irritation. Direct contact with eyes may cause temporary irritation. This product is not expected to cause skin sensitization. May cause genetic defects. May cause cancer. OSHA Specifically Regulated Substances (29 CFR ) t listed. Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Chronic effects 12. Ecological information Ecotoxicity Components This product is not expected to cause reproductive or developmental effects. t classified. Skin. Kidneys. Central nervous system. Central nervous system. Eyes. Causes damage to organs through prolonged or repeated exposure. May be fatal if swallowed and enters airways. Causes damage to organs through prolonged or repeated exposure. The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Species Synthetic Isoparaffinic Hydrocarbon (CAS ) Aquatic Algae IC50 Algae * Estimates for product may be based on additional component data not shown. Persistence and degradability data is available on the degradability of this product. Bioaccumulative potential data available. Partition coefficient n-octanol / water (log Kow) Mineral Spirits Mobility in soil Other adverse effects 13. Disposal considerations Disposal instructions Local disposal regulations data available. Test Results mg/l, 72 Hours other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of contents/container in accordance with local/regional/national/international regulations. Dispose in accordance with all applicable regulations. 5 / 8

6 Hazardous waste code Waste from residues / unused products Contaminated packaging The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport information DOT UN number UN1993 UN proper shipping name Flammable liquids, n.o.s. (Mineral Spirits, Naphtha (petroleum), Light Alkylate) Transport hazard class(es) Class 3 Subsidiary risk - Label(s) 3 Packing group III Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Read safety instructions, SDS and emergency procedures before handling. Special provisions B1, B52, IB3, T4, TP1, TP29 Packaging exceptions 150 Packaging non bulk 203 Packaging bulk 242 IATA UN number UN1993 UN proper shipping name Flammable liquid, n.o.s. (Mineral Spirits, Naphtha (petroleum), Light Alkylate) Transport hazard class(es) Class 3 Subsidiary risk - Packing group III Environmental hazards. ERG Code 3L Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Read safety instructions, SDS and emergency procedures before handling. Other information Passenger and cargo Allowed. aircraft Cargo aircraft only Allowed. IMDG UN number UN1993 UN proper shipping name FLAMMABLE LIQUID, N.O.S. (Mineral Spirits, Naphtha (petroleum), Light Alkylate) Transport hazard class(es) Class 3 Subsidiary risk - Packing group III Environmental hazards Marine pollutant. EmS F-E, S-E Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Read safety instructions, SDS and emergency procedures before handling. Transport in bulk according to This substance/mixture is not intended to be transported in bulk. Annex II of MARPOL 73/78 and the IBC Code 6 / 8

7 DOT IATA; IMDG General information IMDG Regulated Marine Pollutant. 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export tification (40 CFR 707, Subpt. D) t regulated. CERCLA Hazardous Substance List (40 CFR 302.4) t listed. SARA 304 Emergency release notification t regulated. OSHA Specifically Regulated Substances (29 CFR ) t listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - Yes Pressure Hazard - Reactivity Hazard - SARA 302 Extremely hazardous substance t listed. SARA 311/312 Hazardous chemical SARA 313 (TRI reporting) t regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List t regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR ) t regulated. Safe Drinking Water Act (SDWA) US state regulations t regulated. US. Massachusetts RTK - Substance List Mineral Spirits (CAS ) 7 / 8

8 US. New Jersey Worker and Community Right-to-Know Act Mineral Spirits (CAS ) US. Pennsylvania Worker and Community Right-to-Know Law Mineral Spirits (CAS ) US. Rhode Island RTK t regulated. US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Canada China Europe Europe Japan Korea New Zealand Philippines Domestic Substances List (DSL) n-domestic Substances List (NDSL) Inventory of Existing Chemical Substances in China (IECSC) European Inventory of Existing Commercial Chemical Substances (EINECS) European List of tified Chemical Substances (ELINCS) Inventory of Existing and New Chemical Substances (ENCS) Existing Chemicals List (ECL) New Zealand Inventory Philippine Inventory of Chemicals and Chemical Substances (PICCS) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date Version # 01 Disclaimer Revision Information The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Product and Company Identification: Alternate Trade Names Yes Yes Yes 8 / 8