Sulfuric acid fuming (cas ) MSDS
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1 Click http// for suppliers of this product Sulfuric acid fuming (cas ) MSDS IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product identifiers Product name Sulfuric acid, fuming Product Number Brand Index-No. CAS-No Anonymous-Anonymous Relevant identified uses of the substance or mixture and uses advised against Identified uses Laboratory chemicals, Manufacture of substances HAZARDS IDENTIFICATION Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP] Skin corrosion (Category 1A) Specific target organ toxicity - single exposure (Category 3) Classification according to EU Directives 67/548/EEC or 1999/45/EC Causes severe burns. Irritating to respiratory system. Label elements Labelling according Regulation (EC) No 1272/2008 [CLP] Pictogram Signal word Hazard statement(s) H314 H335 Precautionary statement(s) P261 P280 P305 + P351 + P338 P310 Danger Causes severe skin burns and eye damage. May cause respiratory irritation. Supplemental Hazard information (EU) EUH014 According to European Directive 67/548/EEC as amended. Hazard symbol(s) Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. Wear protective gloves/ protective clothing/ eye protection/ face protection. IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. 2.3 R-phrase(s) R14 R35 R37 S-phrase(s) S26 S30 S45 Other hazards - none Causes severe burns. Irritating to respiratory system. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Never add water to this product. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible) COMPOSITION/INFORMATION ON INGREDIENTS Substances Synonyms Oleum Formula Molecular Weight H2O4S 98,08 g/mol
2 Component Oleum CAS-No. Index-No Concentration FIRST AID MEASURES Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. Most important symptoms and effects, both acute and delayed Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., Cough, Shortness of breath, Headache, Nausea Indication of any immediate medical attention and special treatment needed FIREFIGHTING MEASURES Extinguishing media Suitable extinguishing media Dry powder Special hazards arising from the substance or mixture Sulphur oxides Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. Further information ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Wear respiratory protection. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Methods and materials for containment and cleaning up Soak up with inert absorbent material and dispose of as hazardous waste. Do not flush with water. Keep in suitable, closed containers for disposal. Reference to other sections For disposal see section 13. HANDLING AND STORAGE Precautions for safe handling Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Never allow product to get in contact with water during storage. strongly hygroscopic Specific end uses
3 EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Components with workplace control parameters Exposure controls Appropriate engineering controls Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. Personal protective equipment Eye/face protection Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Splash protection Material Nitrile rubber Minimum layer thickness 0,4 mm Break through time > 30 min Material testedcamatril? (Anonymous Z677442, Size M) data source KCL GmbH, D Eichenzell, phone +49 (0) , test method EN374 If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an Industrial Hygienist familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario. Body Protection Complete suit protecting against chemicals, Flame retardant protective clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU) PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties a) b) c) d) e) f) g) h) Appearance Odour Odour Threshold ph Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Form liquid not applicable i) Flammability (solid, gas) j) k) l) Upper/lower flammability or explosive limits Vapour pressure Vapour density 7 hpa at 37,7 C 3 hpa at 25 C 3,39 - (Air = 1.0) m) Relative density 1,925 g/cm3 at 25 C n) Water solubility
4 o) p) Partition coefficient n- octanol/water Autoignition 9.2 q) r) s) temperature Decomposition temperature Viscosity Explosive properties t) Oxidizing properties Other safety information STABILITY AND REACTIVITY Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Exposure to moisture. Incompatible materials Metals, Water, Acetaldehyde, Acetonitrile, metal acetylides, Chlorates Hazardous decomposition products Other decomposition products - TOXICOLOGICAL INFORMATION Information on toxicological effects Acute toxicity LC50 Inhalation - rat - 1 h ppm Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Potential health effects Inhalation Ingestion Skin Eyes May be fatal if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Causes respiratory tract irritation. May be harmful if swallowed. Causes burns. May be harmful if absorbed through skin. Causes skin burns. Causes eye burns. Signs and Symptoms of Exposure Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., Cough, Shortness of breath, Headache, Nausea Additional Information
5 RTECS WS ECOLOGICAL INFORMATION Toxicity Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects DISPOSAL CONSIDERATIONS Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product TRANSPORT INFORMATION UN number ADR/RID 1831 UN proper shipping name ADR/RID IMDG IATA SULPHURIC ACID, FUMING SULPHURIC ACID, FUMING Sulphuric acid, fuming Passenger Aircraft Not permitted for transport Cargo Aircraft Not permitted for transport 14.3 Transport hazard class(es) ADR/RID 8 (6.1) 14.4 Packaging group ADR/RID I 14.5 Environmental hazards ADR/RID no 14.6 Special precautions for user IMDG 1831 IATA 1831 IMDG 8 (6.1) IMDG I IMDG Marine pollutant no IATA 8 (6.1) IATA - IATA no REGULATORY INFORMATION This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. Safety, health and environmental regulations/legislation specific for the substance or mixture Chemical Safety Assessment OTHER INFORMATION Further information The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information this document is based on the resent state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. guidechem shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale.
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