C : Corrosive N : Dangerous for 8 : Corrosive substance. 9 : Miscellaneous
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1 Page : 1 / 9 êc ên { C : Corrosive N : Dangerous for 8 : Corrosive substance. 9 : Miscellaneous the environment dangerous substances and articles. Danger M»M M MÅ Producer CID LINES NV Waterpoortstraat, 2 B-8900 Ieper Belgique-Belgie SECTION 1. Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Identification of the product Trade name Type of product 1.2. Other Use Company : Liquid. : VIROCID : Disinfectant. : Industrial. See product bulletin for detailed information. Company identification : CID LINES NV Waterpoortstraat, 2 B-8900 Ieper Belgique-Belgie 1.4. Emergency telephone number SECTION 2. Hazards identification 2.1. Classification of the substance or mixture Classification EC 67/548 or EC 1999/45 :R10 Xn; R20/21/22 C; R34 R42/43 N; R50
2 Page : 2 / 9 SECTION 2. Hazards identification (continued) Hazard Class and Category Code Regulation EC 1272/2008 (CLP) Health hazards : Acute toxicity, Oral - Category 4 - Warning (CLP : Acute Tox. 4) Acute toxicity, dermal - Category 4 - Warning (CLP : Acute Tox. 4) Acute toxicity, Inhalation - Category 4 - Warning (CLP : Acute Tox. 4) Skin corrosion - Category 1B - Danger (CLP : Skin Corr. 1B) Serious eye damage - Category 1 - Danger (CLP : Eye Dam. 1) Respiratory sensitization - Category 1 - Danger (CLP : Resp. Sens. 1) Skin sensitisation - Category 1 - Warning (CLP : Skin Sens. 1) Physical hazards : Flammable liquids - Category 3 - Warning (CLP : Flam. Liq. 3) Environmental hazards : Hazardous to the aquatic environment - Acute hazard - Category 1 - Warning (CLP : Aquatic Acute 1) 2.2. Label elements Labelling EC 67/548 or EC 1999/45 Symbol(s) êc ên : C: Corrosive. N: Dangerous for the environment. R Phrase(s) : R10 : Flammable. R20/21/22 : Harmful by inhalation, in contact with skin and if swallowed. R34 : Causes burns. R42/43 : May cause sensitization by inhalation and skin contact. R50 : Very toxic to aquatic organisms. S Phrase(s) : S2 : Keep out of the reach of children. S13 : Keep away from food, drink and animal feedingstuffs. S20/21 : When using, do not eat, drink or smoke. S23 : Do not breathe the gas, fumes, vapours, spray. S24 : Avoid contact with skin. S26 : In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28 : After contact with skin, wash immediately with plenty of water S35 : This material and its container must be disposed of in a safe way. S36/37/39 : Wear suitable protective clothing, gloves and eye/face protection. S38 : In case of insufficient ventilation, wear suitable respiratory equipment. S42 : During fumigation/spraying wear suitable respiratory equipment. S45 : In case of accident or if you feel unwell, seek medical advice immediately ( show the label when possible). S51 : Use only in well-ventilated areas. S60 : This material and its container must be disposed of as hazardous waste. S61 : Avoid release to the environment. Refer to special instruct Labelling Regulation EC 1272/2008 (CLP) Hazard pictograms M» M M MÅ Hazard pictograms code : SGH05 - SGH08 - SGH02 - SGH09 Signal words : Danger
3 Page : 3 / 9 SECTION 2. Hazards identification (continued) Hazard statements Pictograms (Precautionary statements) : H314 : Causes severe skin burns and eye damage. H334 : May cause allergy or asthma symptoms or breathing difficulties if inhaled. H226 : Flammable liquid and vapour. H312 : Harmful in contact with skin. H332 : Harmful if inhaled. H302 : Harmful if swallowed. H317 : May cause an allergic skin reaction. H400 : Very toxic to aquatic life. [Æ ]Æ ÊÆ ; = ± Precautionary statements - Prevention : P280 : Wear protective gloves/protective clothing/eye protection/face protection. P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking. - Response : P304+P340: IF INHALED : Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor. Specific treatment is urgent. P305: IF IN EYES : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor. Specific treatment. P302: IF ON SKIN : Wash with plenty of soap and water. Call a POISON CENTER or doctor if you feel unwell. Specific treatment. P301+P330+P331+P310+P321: IF SWALLOWED : Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor. Specific treatment Other hazards None under normal conditions. SECTION 3. Composition/information on ingredients Substance / Preparation : Preparation. Substance name Contents CAS No EC No Index No REACH Classification Alkyldimethylbenzylammoniumch : % Xn; R21/22 loride C; R34 N; R50 (M fact. = 10) Skin Corr. 1B Eye Dam 1 Acute Tox. 4 (skin) Acute Tox. 4 (oral) Aquatic Acute 1 Glutaraldehyde : 5-15 % X T; R23/25 C; R34 R42/43 N; R Acute Tox. 3 (inhal) Acute Tox. 3 (oral) Skin Corr. 1B Aquatic Acute 1 Resp. Sens. 1 Skin Sens. 1 Isopropanol : 5-15 % F; R11 R67 Xi; R Flam. Liq. 2 Eye irrit 2 STOT SE 3
4 Page : 4 / 9 SECTION 3. Composition/information on ingredients (continued) Substance name Contents CAS No EC No Index No REACH Classification Didecyldimethylammonium : 5-15 % Xn; R22 C; R34 chloride Skin Corr. 1B Eye Dam 1 Acute Tox. 4 (oral) SECTION 4. First aid measures 4.1. Description of first aid measures First aid - Inhalation : Assure fresh air breathing. Obtain medical attention if breathing difficulty persists. - Skin contact : Seek medical attention if irritation develops. Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. - Eye contact : Rinse immediately with plenty of water. Contact ophthalmologist immediately. - Ingestion : Rinse mouth. Do not induce vomiting because of corrosive effects. Call a physician immediately Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5. Fire-fighting measures 5.1. Extinguishing media Extinguishing media : All extinguishing media can be used Special hazards arising from the substance or mixture Special exposure hazards 5.3. Advice for fire-fighters Flammable class Protection against fire Special procedures Surrounding fires : High temperature may liberate dangerous gases. : Not combustible. : Do not enter fire area without proper protective equipment, including respiratory protection. : Exercise caution when fighting any chemical fire. Avoid (reject) fire-fighting water to enter environment. : Use water spray or fog for cooling exposed containers. SECTION 6. Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Personal precautions : Equip cleanup crew with proper protection. Respiratory protection equipment may be necessary Environmental precautions Environmental precautions : Prevent entry to sewers and public waters. Notify authorities if product enters sewers or public waters.
5 Page : 5 / 9 SECTION 6. Accidental release measures (continued) 6.3. Methods and material for containment and cleaning up After spillage and/or leakage : Clean up any spills as soon as possible, using an absorbent material to collect it. Dilute residues and flush. Recover the cleaning water for diposal Reference to other sections SECTION 7. Handling and storage 7.1. Precautions for safe handling Handling Precautions in handling and storage 7.2. Conditions for safe storage, including any incompatibilities Storage 7.3. Specific end use(s) : Where contact with eyes or skin is likely, wear suitable protection. Wash hands and other exposed areas with mild soap and water before eat, drink or smoke and when leaving work. : Handle in accordance with good industrial hygiene and safety procedures. : Store in dry, well-ventilated area. Protect from freezing. Keep at temperature not exceeding 50 C SECTION 8. Exposure controls/personal protection 8.1. Control parameters Personal protection - Respiratory protection : Approved dust or mist respirator should be used if airborne particles are generated when handling this material. - Skin protection : If skin contact or contamination of clothing is likely, protective clothing should be worn. - Eye protection : Eye protection should only be necessary where liquid could be splashed or sprayed. - Hand protection :Gloves. - Ingestion : When using, do not eat, drink or smoke. Industrial hygiene : Provide local exhaust or general room ventilation to minimize dust and/or vapour concentrations Occupational Exposure Limits Glutaraldehyde : TLV -TWA [ppm] : 0.2 Glutaraldehyde : TLV -TWA [mg/m³] : 20 Isopropanol : TLV -TWA [mg/m³] : 983 Isopropanol : TLV -TWA [ppm] : 400 SECTION 9. Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance
6 Page : 6 / 9 SECTION 9. Physical and chemical properties (continued) Physical state : Liquid. Colour : Clear. Brown. Odour Odour : Aldehyde. ph ph value (concentrated product) :ca. 4 Freezing point [ C] : -10 C Initial boiling point : 93 C Flash point [ C] :60 Relative density Density : ca Solubility Solubility in water : Complete. Auto-ignition temperature [ C] : Not applicable. Viscosity : Not applicable Other information SECTION 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Hazardous reactions : Avoid contact with : strong acids. strong oxidizing agents. Hazardous properties : None under normal conditions Conditions to avoid Incompatible materials Hazardous decomposition products Hazardous decomposition products : SECTION 11. Toxicological information Information on toxicological effects Acute toxicity : Corrosive to eyes and skin. Rat oral LD50 [mg/kg] : 1070 Rabbit dermal LD50 [mg/kg] : > 2000
7 Page : 7 / 9 SECTION 11. Toxicological information (continued) Rat inhalation LC50 [mg/kg] Sensitization : : May cause sensitization by inhalation and skin contact. SECTION 12. Ecological information Toxicity On ingredients 48 Hour-EC50 - Daphnia magna [mg/l] :1-10 LC50-96 Hour - fish [mg/l] : Persistence - degradability Bioaccumulative potential BOD5-value [mg/l] COD-value [mg/l] Mobility in soil : This product contains hazardous components for the environment. Biodegradable. : : Results of PBT and vpvb assessment Other adverse effects WGK class (Germany) :3 SECTION 13. Disposal considerations Waste treatment methods Disposal : Hazardous waste. Avoid release to the environment. Dispose in a safe manner in accordance with local/national regulations. SECTION 14. Transport information UN Number General information - UN No. : Proper shipping name - Proper shipping name : UN 1760 CORROSIVE LIQUID, N.O.S. (Alkyldimethylbenzylammoniumchloride, Glutaraldehyde), 8, III Transport Hazard Classification 19 Hazard Label(s) {
8 Page : 8 / 9 SECTION 14. Transport information (continued) :8 9E Land transport - ADR/RID : Group : III Class : 8 - H.I. nr : :80 - ADR Class :8 Sea transport - IMO-IMDG code : Class 8 IMO Packing group : III - IMDG-Marine pollution : YES ò - EMS-Nr :F-A S-B Air transport - ICAO/IATA : Packaging instructions cargo : 820 Packaging instructions passenger: Proper shipping name : CORROSIVE LIQUID, N.O.S. (Alkyldimethylbenzylammoniumchloride, Glutaraldehyde) - IATA - Class or division :8 IATA Packing group : III UN Packing group : III Packing group - ADR Packing group : III Environmental hazards In case of spillage and/or leakage Special precautions for user : Clean up even minor leaks or spills if possible without unecessary risk. Personal precautions : The driver shall not attempt to deal with any fire of the load. No naked lights. No smoking. Keep public away from danger area. NOTIFY POLICE AND FIRE BRIGADE IMMEDIATELY. Additional information Bulk transport - annex II Marpol 73/78 - IBC Not classified. SECTION 15. Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Ensure all national/local regulations are observed Chemical Safety Assessment
9 Page : 9 / 9 SECTION 16. Other information List of relevant R phrases (heading 3) : R11 : Highly flammable. R21/22 : Harmful in contact with skin and if swallowed. R22 : Harmful if swallowed. R23/25 : Toxic by inhalation and if swallowed. R34 : Causes burns. R36 : Irritating to eyes. R42/43 : May cause sensitization by inhalation and skin contact. R50 : Very toxic to aquatic organisms. R67 : Vapours may cause drowsiness and dizziness. List of relevant symbols (heading 3) : C: Corrosive. Highly flammable. N: Dangerous for the environment. Toxic. Irritant. Further information : None. The contents and format of this SDS are in accordance with EEC Commission "REACH" Regulation, EC 1907/2006 DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. End of document
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