Pestell Minerals & Ingredients 141 Hamilton Rd., New Hamburg, ON N3A 2H1 CANADA CANUTEC (24hs)
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1 Safety Data Sheet Version: 2 Version Date: August 10, PRODUCT AND COMPANY IDENTIFICATION Product name: Other Names: Product Use: Uses Advised Against: Distributor: Telephone: Emergency Response: Ammonium Sulphate - Feed Grade Diammonium sulphate, Ammmonium tetraoxosulphate, Sulphuric acid diammonium salt For use in animal feed. Not intended for human consumption. Pestell Minerals & Ingredients 141 Hamilton Rd., New Hamburg, ON N3A 2H1 CANADA qa@pestell.com CANUTEC (24hs) HAZARDS IDENTIFICATION Emergency Overview WHMIS Classification Not WHMIS controlled. GHS Classification Acute toxicity, Oral (Category 5) Acute aquatic toxicity (Category 3) GHS Label elements, including precautionary statements Pictogram Signal word Hazard statement(s) H303 H402 Precautionary statement(s) HMIS Classification Health hazard: 1 Flammability: 0 Physical hazards: 0 Potential Health Effects Inhalation Skin Eyes Ingestion Warning May be harmful if swallowed. Harmful to aquatic life. none May be harmful if inhaled. May cause respiratory tract irritation. May be harmful if absorbed through skin. May cause skin irritation. May cause eye irritation. May be harmful if swallowed. 3. COMPOSITION/INFORMATION ON INGREDIENTS Compound : Ammonium sulphate Page 1 of 6
2 Formula : H 8 N 2 O 4 S Molecular Weight : g/mol CAS-No. EC-No. Index-No. Concentration Ammonium sulphate FIRST AID MEASURES General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Flush eyes with water as a precaution. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 5. FIREFIGHTING MEASURES Conditions of flammability Not flammable or combustible. Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Special protective equipment for firefighters Wear self contained breathing apparatus for fire fighting if necessary. Hazardous combustion products Hazardous decomposition products formed under fire conditions. - nitrogen oxides (NOx), Sulphur oxides Explosion data - sensitivity to mechanical impact Explosion data - sensitivity to static discharge Further information The product itself does not burn. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Avoid breathing dust. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Methods and materials for containment and cleaning up Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal. 7. HANDLING AND STORAGE Precautions for safe handling Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed. Page 2 of 6
3 Conditions for safe storage Keep container tightly closed in a dry and well-ventilated place. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Contains no substances with occupational exposure limit values. Personal protective equipment Respiratory protection Respiratory protection is not required. Where protection from nuisance levels of dusts are desired, use type N95 (US) or type P1 (EN 143) dust masks. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Hand protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Immersion protection Material: Nitrile rubber Minimum layer thickness: 0.11 mm Break through time: > 480 min Material tested:dermatril (Aldrich Z677272, Size M) Splash protection Material: Nitrile rubber Minimum layer thickness: 0.11 mm Break through time: > 30 min Material tested:dermatril (Aldrich Z677272, Size M) data source: KCL GmbH, D Eichenzell, phone +49 (0) , sales@kcl.de, test method: EN374 If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an Industrial Hygienist familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario. Eye protection Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin and body protection Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place., The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Hygiene measures Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Specific engineering controls Use mechanical exhaust or laboratory fumehood to avoid exposure. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Form Colour Safety data ph Melting point/freezing point crystalline colourless at 132 g/l at 25 C (77 F) Melting point/range: > 280 C (> 536 F) - dec. Page 3 of 6
4 Boiling point Flash point Ignition temperature Autoignition temperature Lower explosion limit Upper explosion limit Vapour pressure Density Water solubility Partition coefficient: n-octanol/water Relative vapour density Odour Odour Threshold Evaporation rate 1.77 g/cm3 at 25 C (77 F) 132 g/l at 20 C (68 F) - completely soluble log Pow: STABILITY AND REACTIVITY Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions Conditions to avoid Materials to avoid Strong oxidizing agents, Strong bases Hazardous decomposition products Hazardous decomposition products formed under fire conditions. - nitrogen oxides (NOx), Sulphur oxides Other decomposition products TOXICOLOGICAL INFORMATION Acute toxicity Oral LD50 Inhalation LC50 Dermal LD50 Other information on acute toxicity Skin corrosion/irritation Skin - rabbit - No skin irritation Skin - Human - Mild skin irritation Serious eye damage/eye irritation Eyes - rabbit - No eye irritation Page 4 of 6
5 Eyes - Human - Mild eye irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity IARC: ACGIH: Reproductive toxicity No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. Teratogenicity Specific target organ toxicity - single exposure (Globally Harmonized System) Specific target organ toxicity - repeated exposure (Globally Harmonized System) Aspiration hazard Potential health effects Inhalation Ingestion Skin Eyes May be harmful if inhaled. May cause respiratory tract irritation. May be harmful if swallowed. May be harmful if absorbed through skin. May cause skin irritation. May cause eye irritation. Signs and Symptoms of Exposure To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Synergistic effects Additional Information RTECS: BS ECOLOGICAL INFORMATION Toxicity Toxicity to fish Toxicity to daphnia and other aquatic invertebrates Persistence and degradability Bioaccumulative potential Mobility in soil PBT and vpvb assessment LC50 - Oncorhynchus mykiss (rainbow trout) mg/l - 96 h LC50 - Daphnia magna (Water flea) mg/l - 50 h Page 5 of 6
6 Other adverse effects An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Harmful to aquatic life. 13. DISPOSAL CONSIDERATIONS Product Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product. 14. TRANSPORT INFORMATION DOT (US) IMDG IATA TDG 15. REGULATORY INFORMATION WHMIS Classification Not WHMIS controlled. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. 16. OTHER INFORMATION Further information The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Pestell Minerals & Ingredients and its Affiliates shall not be held liable for any damage resulting from handling or from contact with the above product. Version: 2 Version Date: August 10, 2018 Page 6 of 6
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