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1 Crayola TM Squeeze-A-Color TM Children's Toothpaste Revision date: 12/18/2013 Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product Identifier Product form: Mixture Product name: Crayola TM Squeeze-A-Color TM Children's Toothpaste Product code: 4050, 4052 (42 grams per tube; 3 tubes per package) Synonyms: Children's toothpaste, Crayola Mini Tubes 1.2. Intended Use Of The Product Use of the substance/mixture: Children's toothpaste. This mixture is a product regulated by the FDA. Within the meaning of the OSHA Hazard Communication Standard [29 CFR ]: this mixture is not considered a hazard when used in a manner which is consistent with the labeled directions Name, Address, And Telephone Of The Responsible Party Sunstar Americas, Inc West Foster Avenue Chicago, IL Emergency telephone number Emergency number : (within US) or (outside US) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Not classified 2.2. Label elements GHS-US labeling No labeling applicable 2.3. Other hazards No additional information available 2.4. Unknown acute toxicity (GHS US) No data available SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixture Name Product Identifier % GHS-US classification D-Glucitol (CAS No.) Not classified Xylitol (CAS No.) Comb. Dust Sodium fluoride (CAS No.) Acute Tox. 3 (Oral), H301 Acute Tox. 2 (Dermal), H310 Skin Irrit. 2, H315 Eye Irrit. 2A, H319 Full text of H-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation: When symptoms occur: go into open air and ventilate suspected area. First-aid measures after skin contact: Rinse with plenty of water. 12/18/2013 EN (English) 1/5
2 First-aid measures after eye contact: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. First-aid measures after ingestion: Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation: Not expected to present a significant inhalation hazard under anticipated conditions of normal use. Symptoms/injuries after skin contact: May cause mild skin irritation. Symptoms/injuries after eye contact: May cause mild eye irritation. Symptoms/injuries after ingestion: Diarrhea. Gastrointestinal irritation Indication of any immediate medical attention and special treatment needed If you feel unwell, seek medical advice (show the label where possible). SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media: Foam. Dry powder. Carbon dioxide. Water spray. Sand. Use extinguishing media appropriate for surrounding fire. Unsuitable extinguishing media: Do not use a heavy water stream Special hazards arising from the substance or mixture Fire hazard: Not considered flammable but may burn at high temperatures. Explosion hazard: None known Advice for firefighters Firefighting instructions: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Do not allow run-off from fire fighting to enter drains or water courses. Protection during firefighting: Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures: Spilled material may present a slipping hazard For non-emergency personnel Protective equipment: Use appropriate personal protection equipment (PPE) For emergency responders Protective equipment: Equip cleanup crew with proper protection. Emergency procedures: Ventilate area Environmental precautions Prevent entry to sewers and public waters Methods and material for containment and cleaning up For containment: Soak up diluted material with inert solids or flush with large amount of water. Methods for cleaning up: Clear up spills immediately and dispose of waste safely Reference to other sections See Heading 8, exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling: Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Hygiene measures: Handle in accordance with good industrial hygiene and safety procedures Conditions for safe storage, including any incompatibilities Storage conditions: Keep only in the original container in a cool, well ventilated place away from : incompatible materials. Keep container closed when not in use. Incompatible products: Strong bases. Strong acids. Strong oxidizers Specific end use(s) Children's toothpaste. SECTION 8: Exposure controls/personal protection 8.1. Control parameters No Occupational Exposure Limits have been established for this product or its chemical components. 12/18/2013 EN (English) 2/5
3 8.2. Exposure controls Appropriate engineering controls Consumer exposure controls Other information SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Gel Appearance Odour Odour threshold ph : 6-8 Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash Point Auto-ignition temperature Decomposition Temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits : Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Ensure adequate ventilation, especially in confined areas. : Not generally required. The use of personal protective equipment may be necessary as conditions warrant. : When using, do not eat, drink or smoke. : Clear, colored gel : Melon (red), apple (green), or blueberry (blue) : Water: Complete : Not applicable 9.2. Other information No additional information available SECTION 10: Stability and reactivity Reactivity No additional information available Chemical stability Stable under normal conditions Possibility of hazardous reactions Hazardous polymerization will not occur Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Strong acids. Strong bases. Strong oxidizers Hazardous decomposition products Carbon oxides (CO, CO2). Silicon oxides. Hydrofluoric Acid. Phosphates. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity : Not classified 12/18/2013 EN (English) 3/5
4 LD50 dermal rat Xylitol ( ) D-Glucitol ( ) Skin corrosion/irritation: Not classified ph: 6-8 Serious eye damage/irritation: Not classified ph: 6-8 Respiratory or skin sensitisation: Not classified Germ cell mutagenicity: Not classified Carcinogenicity: Not classified IARC group 3 National Toxicity Program (NTP) Status 1 52 mg/kg 175 mg/kg mg/kg mg/kg Reproductive toxicity: Not classified Specific target organ toxicity (single exposure): Not classified Specific target organ toxicity (repeated exposure): Not classified Aspiration hazard: Not classified Symptoms/injuries after inhalation: Not expected to present a significant inhalation hazard under anticipated conditions of normal use. Symptoms/injuries after skin contact: May cause mild skin irritation. Symptoms/injuries after eye contact: May cause mild eye irritation. Symptoms/injuries after ingestion: Diarrhea. Gastrointestinal irritation. SECTION 12: Ecological information Toxicity LC50 fishes 1 > 530 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus) EC50 Daphnia mg/l (Exposure time: 48 h - Species: Daphnia magna) EC50 other aquatic organisms mg/l (Exposure time: 96 h - Species: Pseudokirchneriella subcapitata) LC50 fish mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [semi-static]) EC50 Daphnia 2 98 mg/l (Exposure time: 48 h - Species: Daphnia magna [Static]) EC50 other aquatic organisms mg/l (Exposure time: 72 h - Species: Desmodesmus subspicatus [static]) Persistence and degradability Crayola Squeeze-A-Color Children's Toothpaste Persistence and degradability Not established Bioaccumulative potential Crayola Squeeze-A-Color Children's Toothpaste Bioaccumulative potential Not established Mobility in soil No additional information available Other adverse effects Other information : Avoid release to the environment. SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations: Dispose of waste material in accordance with all local, regional, national, and international regulations. Ecology - waste materials: Avoid release to the environment. 12/18/2013 EN (English) 4/5
5 SECTION 14: Transport information In accordance with ICAO/IATA/DOT/TDG UN number Not regulated for transport UN proper shipping name Not regulated for transport Additional information Not regulated for transport Overland transport Not regulated for transport Transport by sea Not regulated for transport Air transport Not regulated for transport SECTION 15: Regulatory information US Federal regulations Xylitol ( ) D-Glucitol ( ) US State regulations U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List U.S. - Pennsylvania - RTK (Right to Know) List SECTION 16: Other information Data sources : This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR GHS Full Text Phrases: Acute Tox. 2 (Dermal) Acute toxicity (dermal) Category Acute Tox. 3 (Dermal) Acute toxicity (dermal) Category Acute Tox. 3 (Oral) Acute toxicity (oral) Category Acute Tox. 2 (Dermal) Acute toxicity (dermal) Category Acute Tox. 3 (Oral) Acute toxicity (oral) Category Comb. Dust Combustible Dust Eye Irrit. 2A Serious eye damage/eye irritation Category 2A Skin Irrit. 2 skin corrosion/irritation Category H301 Toxic if swallowed H310 Fatal in contact with skin H315 Causes skin irritation H319 Causes serious eye irritation NFPA health hazard NFPA fire hazard NFPA reactivity : 1 - Exposure could cause irritation but only minor residual injury even if no treatment is given. : 1 - Must be preheated before ignition can occur. : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. HMIS III Rating Health : 0 Minimal Hazard - No significant risk to health Flammability : 1 Slight Hazard Physical : 0 Minimal Hazard This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product. SDS US (GHS HazCom) 12/18/2013 EN (English) 5/5
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