1. Substance/preparation and manufacturer/supplier identification

Transcription

1 Safety data sheet Page: 1/12 1. Substance/preparation and manufacturer/supplier identification MasterSeal M 820 PTA Manufacturer/supplier: BASF Australia Limited (ABN ) Level 12, 28 Freshwater Place Southbank Victoria 3006, AUSTRALIA Telephone: Telefax number: Emergency information: BASF Emergency Advice Number: (24h) [within Australia] BASF Emergency Advice Number: [outside Australia] 2. Hazard identification Classification of the substance and mixture: Skin corrosion/irritation: Cat. 1C Specific target organ toxicity repeated exposure: Cat. 2 (oral) Skin sensitization: Cat. 1 Hazardous to the aquatic environment - chronic: Cat. 2 Hazardous to the aquatic environment - acute: Cat. 2 Label elements and precautionary statement: Pictogram: Signal Word: Danger

2 Page: 2/12 Hazard Statement: Causes severe skin burns and eye damage. May cause an allergic skin reaction. May cause damage to organs through prolonged or repeated exposure. Toxic to aquatic life. Toxic to aquatic life with long lasting effects. Precautionary Statements (Prevention): Do not breathe dust or mist. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash with plenty of water and soap thoroughly after handling. Do not eat, drink or smoke when using this product. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. Precautionary Statements (Response): IF SWALLOWED: rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Wash with plenty of soap and water. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Specific treatment (see on this label). If skin irritation or rash occurs: Get medical advice/attention. Collect spillage. Precautionary Statements (Storage): Store locked up. Precautionary Statements (Disposal): Dispose of contents/container to hazardous or special waste collection point. Other hazards which do not result in classification: No specific dangers known, if the regulations/notes for storage and handling are considered. 3. Composition/information on ingredients Chemical nature Preparation based on: amines, additives Hazardous ingredients polyetherdiamine Content (W/W): > 25 % - <= 80 % CAS Number: Acute Tox.: Cat. 5 (oral) Acute Tox.: Cat. 5 (dermal) Skin Corr./Irrit.: Cat. 1C Eye Dam./Irrit.: Cat. 1 Aquatic Chronic: Cat. 2 Aquatic Acute: Cat. 3 (neodecanoato-o)phenylmercury

3 Page: 3/12 Content (W/W): >= 0.1 % - < 1 % CAS Number: Acute Tox.: Cat. 3 (oral) Skin Corr./Irrit.: Cat. 1B STOT RE: Cat. 1 (oral) STOT RE: Cat. 1 (dermal) Aquatic Chronic: Cat. 1 Aquatic Acute: Cat. 1 diethylmethylbenzenediamine Content (W/W): >= 10 % - < 25 % CAS Number: Acute Tox.: Cat. 4 (dermal) Acute Tox.: Cat. 4 (oral) Eye Dam./Irrit.: Cat. 2A STOT RE (Pancreas): Cat. 2 (oral) Aquatic Chronic: Cat. 1 Aquatic Acute: Cat. 1 M-factor acute: 1 Reaction mass of bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate and methyl 1,2,2,6,6-pentamethyl- 4-piperidyl sebacate Content (W/W): >= 0.1 % - <= 2 % Skin Sens.: Cat. 1A Aquatic Chronic: Cat. 1 Aquatic Acute: Cat. 1 M-factor acute: 1 M-factor chronic: 1 4. First-Aid Measures General advice: Immediately remove contaminated clothing. If inhaled: Keep patient calm, remove to fresh air. If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical attention. On skin contact: Wash thoroughly with soap and water. On contact with eyes: Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist. On ingestion: Immediately rinse mouth and then drink plenty of water, do not induce vomiting, seek medical attention. Note to physician: Symptoms: allergic symptoms, skin corrosion Hazards: Symptoms can appear later. Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.

4 Page: 4/12 5. Fire-Fighting Measures Suitable extinguishing media: water spray, dry powder, foam, carbon dioxide Specific hazards: carbon monoxide, carbon dioxide, nitrogen oxides The substances/groups of substances mentioned can be released in case of fire. Special protective equipment: Wear a self-contained breathing apparatus. Further information: Dispose of fire debris and contaminated extinguishing water in accordance with official regulations. 6. Accidental Release Measures Personal precautions: Use personal protective clothing. Environmental precautions: Do not empty into drains. Methods for cleaning up or taking up: For large amounts: Pump off product. For residues: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder, kieselguhr). Dispose of contaminated material as prescribed. Additional information: High risk of slipping due to leakage/spillage of product. 7. Handling and Storage Handling Ensure thorough ventilation of stores and work areas. Protection against fire and explosion: No special precautions necessary. Storage Segregate from foods and animal feeds. Segregate from acids. Segregate from oxidants. Suitable materials for containers: Stainless steel (V2A), High density polyethylene (HDPE), Polytetrafluoroethylene-coated (PTFE), Carbon steel (Iron) Further information on storage conditions: Containers should be stored tightly sealed in a dry place.

5 Page: 5/12 8. Exposure controls and personal protection Components with occupational exposure limits No occupational exposure limits known. Personal protective equipment Respiratory protection: Wear respiratory protection if ventilation is inadequate. Particle filter with medium efficiency for solid and liquid particles (e.g. EN 143 or 149, Type P2 or FFP2) Hand protection: Suitable chemical resistant safety gloves (EN 374) also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), butyl rubber (0.7 mm) etc. Eye protection: Safety glasses with side-shields (frame goggles) (e.g. EN 166) Body protection: Standard work clothes and shoes. General safety and hygiene measures: Avoid contact with the skin, eyes and clothing. Wearing of closed work clothing is required additionally to the stated personal protection equipment. When using, do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift. At the end of the shift the skin should be cleaned and skin-care agents applied. 9. Physical and Chemical Properties Form: Colour: Odour: Odour threshold: liquid yellowish amine-like not applicable ph value: 8-10 (20 C) solidification temperature: < 0 C Boiling point: > 140 C (1,013 hpa) Flash point: > 110 C (DIN 51758) Evaporation rate: Value can be approximated from Henry's Law Constant or vapor pressure. Flammability (solid/gas): not flammable

6 Page: 6/12 Lower explosion limit: For liquids not relevant for classification and labelling., The lower explosion point may be 5-15 C below the flash point. Upper explosion limit: For liquids not relevant for classification and labelling. Ignition temperature: > 250 C Thermal decomposition: No decomposition if stored and handled as prescribed/indicated. Explosion hazard: not explosive Vapour pressure: 10 mbar (20 C) Density: 1.05 g/cm3 (20 C) Relative density: 1.05 (20 C) Relative vapour density (air): not applicable Solubility in water: partly soluble Miscibility with water: partly miscible Partitioning coefficient n-octanol/water (log Pow): not applicable Viscosity, dynamic: not determined Other Information: If necessary, information on other physical and chemical parameters is indicated in this section. 10. Stability and Reactivity Conditions to avoid: Temperature: < 0 C Thermal decomposition: No decomposition if stored and handled as prescribed/indicated. Substances to avoid: acids, oxidizing agents, isocyanates Corrosion to metals: No corrosive effect on metal. Hazardous reactions: No hazardous reactions if stored and handled as prescribed/indicated.

7 Page: 7/12 No hazardous decomposition products if stored and handled as prescribed/indicated. 11. Toxicological Information Acute toxicity Assessment of acute toxicity: Virtually nontoxic by inhalation. Virtually nontoxic after a single skin contact. Virtually nontoxic after a single ingestion. LD50 rat (oral): 738 mg/kg (OECD Guideline 401) Information on: polyetherdiamine LD50 rat (oral): 2,885 mg/kg (similar to OECD guideline 401) LD50 rabbit (dermal): > 700 mg/kg (similar to OECD guideline 402) The European Union (EU) has classified this substance as 'harmful'. LD50 rat (dermal): > 1,000 mg/kg (similar to OECD guideline 402) The European Union (EU) has classified this substance as 'harmful'. No mortality was observed. LD50 rabbit (dermal): > 2,000 mg/kg (similar to OECD guideline 402) The European Union (EU) has classified this substance as 'harmful'. Information on: polyetherdiamine LD50 rabbit (dermal): 2,980 mg/kg (similar to OECD guideline 402) Irritation Assessment of irritating effects: Corrosive! Damages skin and eyes. Serious eye damage/irritation rabbit: Irritant. Respiratory/Skin sensitization Assessment of sensitization: Sensitization after skin contact possible. Information on: Reaction mass of bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate and methyl 1,2,2,6,6-pentamethyl-4-piperidyl sebacate

8 Page: 8/12 guinea pig: skin sensitizing (OECD Guideline 406) Germ cell mutagenicity Assessment of mutagenicity: The chemical structure does not suggest a specific alert for such an effect. Carcinogenicity Assessment of carcinogenicity: The chemical structure does not suggest a specific alert for such an effect. Reproductive toxicity Assessment of reproduction toxicity: The chemical structure does not suggest a specific alert for such an effect. Developmental toxicity Assessment of teratogenicity: The chemical structure does not suggest a specific alert for such an effect. Experiences in humans Information on: Reaction mass of bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate and methyl 1,2,2,6,6-pentamethyl-4-piperidyl sebacate Sensitizing effects by skin contact. Specific target organ toxicity (single exposure): Assessment of STOT single: Based on the available information there is no specific target organ toxicity to be expected after a single exposure. Repeated dose toxicity and Specific target organ toxicity (repeated exposure) Assessment of repeated dose toxicity: Repeated oral exposure may affect certain organs. Repeated exposure to the substance by dermal administration leads to effects similar to those found after single exposure. Repeated exposure to the substance by inhalative administration leads to effects similar to those found after single exposure. Aspiration hazard No aspiration hazard expected. Other relevant toxicity information

9 Page: 9/12 The product has not been tested. The statement has been derived from the properties of the individual components. danger of serious health hazards by longer exposure (subchronic, rat, oral) 12. Ecological Information Ecotoxicity Assessment of aquatic toxicity: Toxic to aquatic life with long lasting effects. Acutely toxic for aquatic organisms. May cause long-term adverse effects in the aquatic environment. Toxicity to fish: LC50 (48 h) 194 mg/l, Leuciscus idus (DIN Part 15) LC50 (96 h) > 104 mg/l, other Information on: Reaction mass of bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate and methyl 1,2,2,6,6-pentamethyl-4-piperidyl sebacate Toxicity to fish: LC50 (96 h) 0.9 mg/l, Brachydanio rerio (OECD Guideline 203, semistatic) The details of the toxic effect relate to the nominal concentration. The product has low solubility in the test medium. An aqueous solution prepared with solubilizers has been tested. Aquatic invertebrates: EC50 (48 h) 0.5 mg/l, Daphnia magna (OECD Guideline 202, part 1) Information on: Reaction mass of bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate and methyl 1,2,2,6,6-pentamethyl-4-piperidyl sebacate Aquatic invertebrates: Study does not need to be conducted. Microorganisms/Effect on activated sludge: EC50 (24 h) 170 mg/l, Pseudomonas putida (DIN Part 8) Information on: Reaction mass of bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate and methyl 1,2,2,6,6-pentamethyl-4-piperidyl sebacate Microorganisms/Effect on activated sludge: EC20 (3 h) >= 100 mg/l, activated sludge, domestic (OECD Guideline 209, aquatic) The details of the toxic effect relate to the nominal concentration.

10 Page: 10/12 Mobility Assessment transport between environmental compartments: Adsorption to solid soil phase is not expected. Persistence and degradability Assessment biodegradation and elimination (H2O): Poorly biodegradable. Elimination information: Poorly biodegradable. Bioaccumulation potential Assessment bioaccumulation potential: The product contains components with potential for bioaccumulation Other adverse effects Adsorbable organically-bound halogen (AOX): This product contains no organically-bound halogen. Additional information Other ecotoxicological advice: Do not allow to enter soil, waterways or waste water channels. Inhibition of degradation activity in activated sludge is not to be anticipated during correct introduction of low concentrations. The product has not been tested. The statement has been derived from the properties of the individual components. 13. Disposal Considerations Incinerate in suitable incineration plant, observing local authority regulations. Contaminated packaging: Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned. 14. Transport Information Domestic transport: Hazard class: 8 Packing group: III ID number: UN 2735 Hazard label: 8, EHSM Proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. (contains POLYETHERDIAMINE) Further information

11 Page: 11/12 Hazchem Code:2X IERG Number:36 Sea transport IMDG Hazard class: 8 Packing group: III ID number: UN 2735 Hazard label: 8, EHSM Marine pollutant: YES Proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. (contains POLYETHERDIAMINE) Air transport IATA/ICAO Hazard class: 8 Packing group: III ID number: UN 2735 Hazard label: 8 Proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. (contains POLYETHERDIAMINE) 15. Regulatory Information Other regulations If it is intended to use materials for the manufacture of consumer goods (e. g. products which will come into contact with foodstuffs or with the skin, toys) or medical products, national and international regulations have to be observed. Where no regulations exist, consumer goods or medical products must at least comply with European legislation. We recommend contacting our Sales and our Product Safety departments. If other regulatory information applies that is not already provided elsewhere in this safety data sheet, then it is described in this subsection. Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP): Not Scheduled Registration status: AICS, AU released; restriction on quantity / listed

12 Page: 12/ Other Information Recommended use: polyurethane component Vertical lines in the left hand margin indicate an amendment from the previous version. The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. The data do not describe the product's properties (product specification). Neither should any agreed property nor the suitability of the product for any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.