SECTION 1: Identification of the substance/mixture and of the company/undertaking. SECTION 2: Hazards identification
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1 Date of issue: 13/08/2015 Revision date: 07/11/2016 Supersedes: 13/08/2015 Version: 2.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Substance Trade name : Silicone oil for heating baths LBSil 100 CAS No : Product code : S Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category : Laboratory use Uses advised against 1.3. Details of the supplier of the safety data sheet labbox labware s.l. Joan Peiró i Belis, Vilassar de Dalt - ES T F info@labkem.com Emergency telephone number Emergency number : ( Office Hours) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixtures/Substances: SDS EU 2015: According to Regulation (EU) 2015/830 (REACH Annex II) Not classified Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display No labelling applicable 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substances Name Product identifier % Silicone oil (CAS No) Full text of H-statements: see section Mixtures Not applicable SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Get medical advice/attention if you feel unwell Most important symptoms and effects, both acute and delayed 07/11/2016 EN (English) 1/5
2 4.3. Indication of any immediate medical attention and special treatment needed Never give anything by mouth to an unconscious person. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Water spray. Sand. Carbon dioxide. Foam. Dry powder. : Strong water jet Special hazards arising from the substance or mixture Hazardous decomposition products in case of fire : Toxic fumes may be released Advice for firefighters Precautionary measures fire : Stop leak if safe to do so. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Absorb spillage to prevent material damage For non-emergency personnel For emergency responders Emergency procedures : Stop leak if safe to do so. Ventilate area Environmental precautions Avoid release to the environment. Prevent entry to sewers and public waters Methods and material for containment and cleaning up For containment Methods for cleaning up 6.4. Reference to other sections : Collect spillage. : Take up liquid spill into absorbent material. On land, sweep or shovel into suitable containers. Collect spillage. SECTION 7: Handling and storage 7.1. Precautions for safe handling Hygiene measures : Do not eat, drink or smoke when using this product. Always wash hands after handling the product Conditions for safe storage, including any incompatibilities Special rules on packaging : Store in a closed container. Keep only in original container Specific end use(s) Laboratory chemicals. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Silicone oil for heating baths LBSil 100 ( ) DNEL/DMEL (Workers) Acute - systemic effects, dermal 8.2. Exposure controls Personal protective equipment: mg/kg bodyweight/day Gloves. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Other information: Do not eat, drink or smoke when using this product. The present safety data sheet is consistent with the specific conditions relied on to justify the registration of the substance as isolated intermediate. 07/11/2016 EN (English) 2/5
3 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Colour Odour Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point : Liquid : Colourless. : odourless. Boiling point : > 300 C Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Strong acids. Strong bases Hazardous decomposition products SECTION 11: Toxicological information Information on toxicological effects Acute toxicity : 0,965 g/cm³ Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT-single exposure STOT-repeated exposure 07/11/2016 EN (English) 3/5
4 Aspiration hazard SECTION 12: Ecological information Toxicity Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN-No. (ADR) UN-No. (IMDG) UN-No. (IATA) UN-No. (ADN) UN-No. (RID) UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport hazard class(es) ADR Transport hazard class(es) (ADR) IMDG Transport hazard class(es) (IMDG) IATA Transport hazard class(es) (IATA) ADN Transport hazard class(es) (ADN) RID Transport hazard class(es) (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) 07/11/2016 EN (English) 4/5
5 Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information : No : No : No supplementary information available Special precautions for user - Overland transport - Transport by sea - Air transport - Inland waterway transport - Rail transport Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations No REACH Annex XVII restrictions Silicone oil for heating baths LBSil 100 is not on the REACH Candidate List Silicone oil for heating baths LBSil 100 is not on the REACH Annex XIV List National regulations Germany 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV Netherlands SZW-lijst van kankerverwekkende stoffen SZW-lijst van mutagene stoffen giftige stoffen Borstvoeding giftige stoffen Vruchtbaarheid giftige stoffen Ontwikkeling : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) Chemical safety assessment SECTION 16: Other information SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 07/11/2016 EN (English) 5/5
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