MATERIAL SAFETY DATA SHEET (MSDS)
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1 MSDS CAS-No.: MSDS MATERIAL SAFETY DATA SHEET (MSDS) SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture : Product code : Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Industrial/Professional use spec : Industrial For professional use only Uses advised against 1.3. Details of the supplier of the safety data sheet LOBA CHEMIE PVT.LTD. 107 Wode House Road, Jehangir Villa, Colaba Mumbai - INDIA T F info@lobachemie.com Emergency telephone number Emergency number : (9:00am - 6:00 pm) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixtures/Substances: SDS EU 2015: According to Regulation (EU) 2015/830 (REACH Annex II) Not classified Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display No labelling applicable 15/01/2019 1/8
2 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substances 3.2. Mixtures Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] WATER AR (CAS-No.) Not classified (EC-No.) POTASSIUM NITRATE AR (CAS-No.) (EC-No.) Ox. Sol. 2, H272 Water (CAS-No.) (EC-No.) AMMONIA SOLUTION 30% AR (CAS-No.) (EC-No.) (EC Index-No.) SILVER NITRATE AR/ACS (CAS-No.) (EC-No.) (EC Index-No.) Not classified Acute Tox. 4 (Oral), H302 Skin Corr. 1B, H314 STOT SE 3, H335 Aquatic Acute 1, H Ox. Sol. 2, H272 Skin Corr. 1, H314 Aquatic Chronic 1, H410 Full text of H-statements: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Remove person to fresh air and keep comfortable for breathing. Give oxygen or artificial respiration if necessary. If you feel unwell, seek medical advice. : Gently wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. : Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously with water for several minutes. If eye irritation persists: Get medical advice/attention. : Rinse mouth out with water. If you feel unwell, seek medical advice Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. 15/01/2019 2/8
3 SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2). : Do not use a heavy water stream Special hazards arising from the substance or mixture 5.3. Advice for firefighters SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment : Avoid contact with skin, eyes and clothing. : Use personal protective equipment as required Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up : Clear up rapidly by scoop or vacuum Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Avoid contact with skin and eyes. : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work Conditions for safe storage, including any incompatibilities Storage conditions : Store in a well-ventilated place. Keep container tightly closed Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters 15/01/2019 3/8
4 8.2. Exposure controls Hand protection Eye protection Skin and body protection Respiratory protection : Protective gloves : Chemical goggles or safety glasses : Wear suitable protective clothing : Wear respiratory protection. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour Odour Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits : Clear Colorless Other information SECTION 10: Stability and reactivity Reactivity 15/01/2019 4/8
5 10.2. Chemical stability Stable under normal conditions Possibility of hazardous reactions Conditions to avoid Direct sunlight Incompatible materials Hazardous decomposition products SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT-single exposure STOT-repeated exposure Aspiration hazard SECTION 12: Ecological information Toxicity Persistence and degradability Bioaccumulative potential 15/01/2019 5/8
6 SILVER NITRATE AR/ACS ( ) Log Pow Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13: Disposal considerations Waste treatment methods SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN-No. (ADR) UN-No. (IMDG) UN-No. (IATA) UN-No. (ADN) UN-No. (RID) UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport hazard class(es) ADR Transport hazard class(es) (ADR) : : : : : : : : : : : IMDG Transport hazard class(es) (IMDG) : IATA Transport hazard class(es) (IATA) : ADN Transport hazard class(es) (ADN) : RID Transport hazard class(es) (RID) : Packing group Packing group (ADR) Packing group (IMDG) : : 15/01/2019 6/8
7 Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information : : : : No : No : No supplementary information available Special precautions for user - Overland transport - Transport by sea - Air transport - Inland waterway transport - Rail transport Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances National regulations Germany Reference to AwSV 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Water hazard class (WGK) 3, Highly hazardous to water (Classification according to AwSV, Annex 1) : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) Netherlands SZW-lijst van kankerverwekkende stoffen SZW-lijst van mutagene stoffen NIET-limitatieve lijst van voor de voortplanting giftige stoffen Borstvoeding 15/01/2019 7/8
8 NIET-limitatieve lijst van voor de voortplanting giftige stoffen Vruchtbaarheid NIET-limitatieve lijst van voor de voortplanting giftige stoffen Ontwikkeling Chemical safety assessment SECTION 16: Other information Full text of H- and EUH-statements: Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Aquatic Acute 1 Hazardous to the aquatic environment Acute Hazard, Category 1 Aquatic Chronic 1 Hazardous to the aquatic environment Chronic Hazard, Category 1 Ox. Sol. 2 Oxidising Solids, Category 2 Skin Corr. 1 Skin corrosion/irritation, Category 1 Skin Corr. 1B Skin corrosion/irritation, Category 1B STOT SE 3 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H272 May intensify fire; oxidiser. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 15/01/2019 8/8
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