1.4. Emergency telephone number Country Organisation/Company Address Emergency number
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1 Date of issue: 16/07/2015 Revision date: : Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Product name : Mixture : SIL Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Uses advised against 1.3. Details of the supplier of the safety data sheet Sidec Industrieweg Balen - BELGIE Emergency telephone number Country Organisation/Company Address Emergency number UNITED KINGDOM SECTION 2: Hazards identification Guy's & St Thomas' Poisons Unit Medical Toxicology Unit, Guy's & St Thomas' Hospital Trust 2.1. Classification of the substance or mixture Avonley Road SE14 5ER London Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixture/Substance: SDS EU 2015: According to Annex II of Regulation (EC) No. 453/2010 (REACH Annex II) Skin Sens. 1 H317 Full text of H-statements: see section Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) : Signal word (CLP) Hazardous ingredients Hazard statements (CLP) Precautionary statements (CLP) GHS07 : Warning : 1,2-Benzisothiazolin-3-one : H317 - May cause an allergic skin reaction : P280 - Wear protective gloves, eye protection P302+P352 - IF ON SKIN: Wash with plenty of water, soap P333+P313 - If skin irritation or rash occurs: Get medical advice/attention P362+P364 - Take off contaminated clothing and wash it before reuse 2.3. Other hazards Adverse physicochemical, human health and environmental effects : May cause an allergic skin reaction. SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture 29/07/2015 EN (English) 1/6
2 Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Ammonia (CAS No) (EC no) (EC index no) ,2-Benzisothiazolin-3-one (CAS No) (EC no) (EC index no) ,192 Flam. Gas 2, H221 Press. Gas Acute Tox. 3 (Inhalation), H331 Skin Corr. 1B, H314 Aquatic Acute 1, H400 0, ,08307 Acute Tox. 4 (Oral), H302 Skin Irrit. 2, H315 Eye Dam. 1, H318 Skin Sens. 1, H317 Aquatic Acute 1, H400 Specific concentration limits: Name Product identifier Specific concentration limits 1,2-Benzisothiazolin-3-one (CAS No) (EC no) (EC index no) Full text of H-phrases: see section 16 (C >= 0,05) Skin Sens. 1, H317 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact : If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. : If skin irritation or rash occurs: Get medical advice/attention. Gently wash with plenty of soap and water. Remove/Take off immediately all contaminated clothing Most important symptoms and effects, both acute and delayed Symptoms/injuries after skin contact : May cause an allergic skin reaction Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media 5.2. Special hazards arising from the substance or mixture Hazardous decomposition products in case of fire : Foam. Carbon dioxide. Powder. Water fog. : Toxic fumes may be released Advice for firefighters Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment : Avoid breathing {0 message=<specify applicable conditions> default=dust/fume/gas/mist/vapours/spray filter=(_)?inhal_condition_.+}. Do not get in eyes, on skin, or on clothing. Ventilate area. : Use personal protective equipment as required Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up : Collect spillage Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Use personal protective equipment as required. Avoid breathing vapours. Use only outdoors or in a well-ventilated area. Do not get in eyes, on skin, or on clothing. 29/07/2015 EN (English) 2/6
3 Hygiene measures : Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling Conditions for safe storage, including any incompatibilities Storage conditions : Store in a well-ventilated place. Keep cool Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Appropriate engineering controls Hand protection Eye protection Skin and body protection Respiratory protection Environmental exposure controls : Ensure good ventilation of the work station. : Protective gloves : Safety glasses : Wear suitable protective clothing : In case of insufficient ventilation, wear suitable respiratory equipment : Avoid release to the environment. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour Odour Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information SECTION 10: Stability and reactivity Reactivity Stable under normal conditions Chemical stability Stable under normal conditions Possibility of hazardous reactions No dangerous reactions known under normal conditions of use. 29/07/2015 EN (English) 3/6
4 10.4. Conditions to avoid Incompatible materials Hazardous decomposition products SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard : May cause an allergic skin reaction. SECTION 12: Ecological information Toxicity Ecology - general : The product is not considered harmful to aquatic organisms nor to cause long-term adverse effects in the environment Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13: Disposal considerations Waste treatment methods SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number Not regulated for transport UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport hazard class(es) ADR Transport hazard class(es) (ADR) IMDG 29/07/2015 EN (English) 4/6
5 Transport hazard class(es) (IMDG) IATA Transport hazard class(es) (IATA) ADN Transport hazard class(es) (ADN) RID Transport hazard class(es) (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information supplementary information available Special precautions for user - Overland transport No data available - Transport by sea No data available - Air transport No data available - Inland waterway transport Carriage prohibited (ADN) Not subject to ADN - Rail transport Carriage prohibited (RID) Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances National regulations Germany VwVwS Annex reference 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Water hazard class (WGK) 3, strongly hazardous to water (Classification according to VwVwS, Annex 4) : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) Netherlands SZW-lijst van kankerverwekkende stoffen SZW-lijst van mutagene stoffen : is listed : is listed 29/07/2015 EN (English) 5/6
6 NIET-limitatieve lijst van voor de voortplanting giftige stoffen Borstvoeding NIET-limitatieve lijst van voor de voortplanting giftige stoffen Vruchtbaarheid NIET-limitatieve lijst van voor de voortplanting giftige stoffen Ontwikkeling Denmark Recommendations Danish Regulation ne of the components are listed ne of the components are listed ne of the components are listed : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information Full text of H- and EUH-statements: Acute Tox. 3 (Inhalation) Acute toxicity (inhal.), Category 3 Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Aquatic Acute 1 Hazardous to the aquatic environment Acute Hazard, Category 1 Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Flam. Gas 2 Flammable gases, Category 2 Press. Gas Skin Corr. 1B Gases under pressure Skin corrosion/irritation, Category 1B Skin Irrit. 2 Skin corrosion/irritation, Category 2 Skin Sens. 1 Sensitisation Skin, category 1 H221 H302 H314 H315 H317 H318 H331 H400 Flammable gas Harmful if swallowed Causes severe skin burns and eye damage Causes skin irritation May cause an allergic skin reaction Causes serious eye damage Toxic if inhaled Very toxic to aquatic life This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 29/07/2015 EN (English) 6/6
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