SAFETY DATA SHEET Product: MARC 254 RING-B-GONE Form R04132

Transcription

1 SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER AND NAME: MARC 254 RING-B-GONE SDS DATE: 06/03/15 SUPPLIER: Mid-American Research Chemical Corp. ADDRESS: P. O. Box 927 Columbus, NE PHONE: FAX: EMERGENCY PHONE: InfoTrac WEBSITE: RECOMMENDED USE: Toilet Bowl Cleaner. PREPARED BY: MARC SECTION 2: HAZARDS IDENTIFICATION CLASSIFICATION: Skin corrosion/irritation. Causes severe skin burns and eye damage. Toxic if swallowed. SIGNAL WORD AND PRECAUTIONARY STATEMENTS: DANGER: Contains ammonium bifluoride. Causes severe burns. Do not breathe mists. HAZARD STATEMENT: Toxic if swallowed. Causes severe skin burns and eye damage. PRECAUTIONARY STATEMENT: PREVENTION: Do not breathe mists. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves and eye protection. RESPONSE: STORAGE: DISPOSAL: IF SWALLOWED: Immediately call a poison center/doctor. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (OR HAIR): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center / doctor. Rinse mouth. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local regulation. POTENTIAL HEALTH EFFECTS: See Section 11 for more information. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS INGREDIENT CAS NO. % WT. Ammonium Bifluoride Nonyl Phenol Ethoxylate PAGE 1 OF 5

2 SECTION 4: FIRST AID MEASURES EYES: SKIN: Immediate medical attention is required. Take victim immediately to hospital. Rinse eyes cautiously with plenty of water, also under eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. In case of difficulty opening the lids, administer an analgesic eye wash (oxybuprocaine). Calcium gluconate solution. Continue rinsing. Immediately call a poison center / doctor. Call a physician immediately. Take victim immediately to hospital. Immediately remove all contaminated clothing and shoes. Wash off with plenty of water. First treatment with calcium gluconate paste. Immediately call a poison center / doctor. Wash clothes before reuse. INGESTION: INHALATION: DO NOT INDUCE VOMITING. Rinse mouth with water. Give to drink a 1% aqueous calcium gluconate solution. Artificial respiration and/or oxygen may be necessary. Immediately call a poison center / doctor. Remove casualty to fresh air and keep at rest. Oxygen or artificial respiration if needed. Victim to lie down in the recovery position, cover and keep person warm. Call a physician immediately. Take victim immediately to hospital. NOTES TO PHYSICIANS OR FIRST AID PROVIDERS: Treat symptoms. SECTION 5: FIRE FIGHTING MEASURES FLAMMABLE PROPERTIES: SUITABLE EXTINGUISHING MEDIA: This product is non-flammable. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. UNSUITABLE EXTINGUISHING MEDIA: SPECIAL FIRE FIGHTING PROCEDURES/ EQUIPMENT: UNUSUAL FIRE AND EXPLOSION HAZARDS: HAZARDOUS DECOMPOSITION PRODUCTS: Water may be ineffective. Use water spray to cool unopened containers. Wear self contained breathing apparatus for firefighting if necessary. May be corrosive to metals. Gives off hydrogen by reaction with metals. Hydrogen fluoride, Ammonia, nitrogen oxides (NOx). SECTION 6: ACCIDENTAL RELEASE MEASURES EMERGENCY PROCEDURES: Evacuate personnel to safe areas. Use personal protective equipment. Avoid breathing mist. Should not be released into the environment. Collect into suitable, closed containers (properly labelled) for disposal. PROTECTIVE EQUIPMENT: Use personal protective devices as stated in Section 8. METHODS AND MATERIALS FOR CONTAINMENT AND CLEANUP: Same as EMERGENCY PROCEDURES. SECTION 7: HANDLING AND STORAGE GENERAL HANDLING/ STORAGE: Avoid contact with skin and eyes. Avoid inhalation of mist. Store in original container. Keep in a wellventilated, dry place away from incompatible products. Keep in closed, properly labeled containers. OTHER PRECAUTIONS: KEEP OUT OF REACH OF CHILDREN!! CAREFULLY READ ENTIRE LABEL BEFORE USE! PAGE 2 OF 5

3 SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION CONTROL PARAMETERS: OCCUPATIONAL EXPOSURE LIMITS (OEL) INGREDIENT DATA: SOURCE INGREDIENT TWA STEL PEAK US OSHA Permissible Exposure Levels (PELs) -Table Z1 Ammonium bifluoride 2.5 mg/m3 Not available Not available INGREDIENT ORIGINAL IDLH REVISED IDLH Ammonium Bifluoride 500 mg//m3 250 mg/m3 ENGINEERING CONTROLS: Handle in accordance with good hygiene and safety practice. Wash hands after using. VENTILATION/ RESPIRATORY PROTECTION: EYE PROTECTION: Respiratory protection is not expected to be necessary under normal conditions of use. Goggles. SKIN PROTECTION/PROTECTIVE GLOVES: Impervious gloves. Suitable material. Neoprene OTHER PROTECTIVE CLOTHING OR EQUIPMENT: As required to prevent contact. WORK HYGIENIC PRACTICES: Wash hands, forearms and face thoroughly after handling, before eating, smoking and using the lavatory. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE- PHYSICAL STATE: Liquid. COLOR: Blue ODOR: ODOR THRESHOLD: ph: 1-2 MELTING/FREEZING POINT: 32 F BOILING POINT: 212 F FLASH POINT/METHOD USED: EVAPORATION RATE: FLAMMABILITY (solid, gas): FLAMMABILITY LIMITS: UPPER % BY VOLUME: FLAMMABILITY LIMITS: LOWER % BY VOLUME: AUTO IGNITION: VOC: VAPOR PRESSURE (mmhg): VAPOR DENSITY (AIR = 1): RELATIVE DENSITY: DENSITY: SPECIFIC GRAVITY (H2O = 1): 1.03 SOLUBILITY IN WATER: Complete VISCOSITY: PAGE 3 OF 5

4 SECTION 10: STABILITY AND REACTIVITY REACTIVITY: STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Incompatible materials. Extremes of temperature. INCOMPATIBILITY (MATERIAL TO AVOID): Strong acids and strong bases, Silicate containing materials (glass, cement). Metals. HAZARDOUS DECOMPOSITION OR BY-PRODUCTS: Hydrogen fluoride, Ammonia, nitrogen oxides (NOx). HAZARDOUS POLYMERIZATION: No CONDITIONS TO AVOID (POLYMERIZATION): SECTION 11: TOXICOLOGICAL INFORMATION INFORMATION ON TOXICOLOGICAL EFFECTS: Ammonium Bifluoride: ACUTE TOXICITY: LD50 (Oral, Rat): LD50 ( Dermal, Rabbit): LC50 ( Inhalation, Rat): Skin corrosion/irritation: Serious eye damage/irritation: Respiratory or skin sensitization: Germ cell mutagenicity: Carcinogenicity: Reproductive toxicity: STOT single exposure: STOT repeated exposure: Aspiration hazard: 130 mg/kg bw Not available Not available EYES: SKIN: Causes severe eye damage. Causes severe skin burns and corrosion/irritation. INGESTION: INHALATION: Toxic if swallowed. DO NOT breathe mists. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: SECTION 12: ECOLOGICAL INFORMATION TOXICITY: Ammonium Bifluoride ACUTE TOXICITY TIME SPECIES METHOD EVALUATION REMARKS LC mg/l 96h Fish OECD 203 EC50 48h Daphnia OECD 202 EC50 72h Algae OECD 201 PERSISTENCE AND DEGRADABILITY: BIOACCUMULATIVE POTENTIAL: MOBILITY IN SOIL: PAGE 4 OF 5

5 RESULTS OF PBT&vPvB ASSESSMENT: OTHER ADVERSE EFFECTS: The substance is not PBT / vpvb No known significant effects or critical hazards. SECTION 13: DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD: Dispose of contents/container in accordance with local/regional/national/international regulations. SECTION 14: TRANSPORT INFORMATION U.S. DEPARTMENT OF TRANSPORTATION (for ground/non-bulk containers) CONTAINER SIZES(S): PROPER SHIPPING NAME: HAZARD CLASS: ID NUMBER: PACKING GROUP: LABEL STATEMENT: QUARTS COMPOUND, CLEANING LIQUID LIMITED QUANTITY SECTION 15: REGULATORY INFORMATION U.S. FEDERAL REGULATIONS TSCA (TOXIC SUBSTANCE CONTROL ACT): CERCLA (COMPREHENSIVE RESPONSE COMPENSATION, AND LIABILITY ACT): SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT): 311/312 HAZARD CATEGORIES: 313 REPORTABLE INGREDIENTS: SECTION 16: OTHER INFORMATION HMIS/NFPA Ratings: Health = 2 Flammability = 0 Reactivity = 1 Other = - Protection = - REVISION DATE: 06/03/15 DISCLAIMER: While the information contained herein is believed to be correct, no warranties are made with respect thereto, and all liability from reliance thereon is disclaimed. PAGE 5 OF 5