ETHYL ACETATE AR/ACS MSDS. CAS No: MSDS MATERIAL SAFETY DATA SHEET (MSDS)

Transcription

1 MSDS CAS No MSDS MATERIAL SAFETY DATA SHEET (MSDS) SECTION 1 Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Substance EC index no EC no CAS No Product code Formula C4H8O2 Chemical structure 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Use of the substance/mixture Laboratory chemicals, Manufacture of substances Uses advised against 1.3. Details of the supplier of the safety data sheet LOBA CHEMIE PVT.LTD. 107 Wode House Road, Jehangir Villa, Colaba Mumbai - INDIA T F info@lobachemie.com Emergency telephone number Emergency number (900am pm) SECTION 2 Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Flammable liquids, Category 2 Acute toxicity (inhal.), Category 4 Serious eye damage/eye irritation, Category 2 Specific target organ toxicity Single exposure, Category 3, Narcosis H225 H332 H319 H336 Full text of classification categories and H statements see section /04/2015 1/10

2 Classification according to Directive 67/548/EEC or 1999/45/EC F; R11 Xi; R36 R66 R67 Full text of R-phrases see section 16 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) Signal word (CLP) Hazard statements (CLP) Precautionary statements (CLP) GHS02 Danger GHS07 H225 - Highly flammable liquid and vapour H319 - Causes serious eye irritation H332 - Harmful if inhaled H336 - May cause drowsiness or dizziness P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking P261 - Avoid breathing dust/fume/gas/mist/vapours/spray P305+P351+P338 - IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing 2.3. Other hazards SECTION 3 Composition/information on ingredients 3.1. Substance Name CAS No EC no EC index no Full text of R- and H-phrases see section Mixture Not applicable 09/04/2015 2/10

3 SECTION 4 First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation Symptoms/injuries after eye contact Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Repeated exposure may cause skin dryness or cracking. Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists Get medical advice/attention. Rinse mouth out with water. If you feel unwell, seek medical advice. May cause drowsiness or dizziness. Causes serious eye irritation Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5 Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2). Do not use a heavy water stream Special hazards arising from the substance or mixture Fire hazard Highly flammable liquid and vapour. Explosion hazard May form flammable/explosive vapour-air mixture Advice for firefighters Protection during firefighting Do not attempt to take action without suitable protective equipment. SECTION 6 Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures Remove ignition sources. Use special care to avoid static electric charges. No naked lights. No smoking For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures Evacuate unnecessary personnel. Avoid breathing dust/fume/gas/mist/vapours/spray. Stop release Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections SECTION 7 Handling and storage Collect spillage. On land, sweep or shovel into suitable containers. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible Precautions for safe handling Additional hazards when processed Handle empty containers with care because residual vapours are flammable. 09/04/2015 3/10

4 Precautions for safe handling Hygiene measures No naked lights. No smoking. Use only non-sparking tools. Avoid breathing dust/fume/gas/mist/vapours/spray. Use only outdoors or in a well-ventilated area. Wash... thoroughly after handling Conditions for safe storage, including any incompatibilities Technical measures Storage conditions Incompatible materials 7.3. Specific end use(s) Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Keep in fireproof place. Keep container tightly closed. Heat sources. SECTION 8 Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Hand protection Eye protection Skin and body protection Respiratory protection protective gloves Chemical goggles or safety glasses Wear suitable protective clothing Wear respiratory protection SECTION 9 Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Liquid Molecular mass Colour Odour Odour threshold ph g/mol Clear Colorless. fruity odor. No data available No data available Relative evaporation rate (butylacetate=1) 6 Melting point -83 C Freezing point No data available Boiling point 770 C Flash point -40 C Auto-ignition temperature No data available Decomposition temperature 4260 C Flammability (solid, gas) Flammable Highly flammable liquid and vapour 09/04/2015 4/10

5 Vapour pressure 76 mm Hg at 20C Relative vapour density at 20 C 3 Relative density No data available Density g/cm³ Solubility Water 25C (ml/10ml water ) Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties No data available No data available No data available No data available No data available Explosive limits vol % 9.2. Other information SECTION 10 Stability and reactivity Reactivity Chemical stability Highly flammable liquid and vapour. May form flammable/explosive vapour-air mixture Possibility of hazardous reactions Conditions to avoid Open flame. Direct sunlight Incompatible materials Hazardous decomposition products May release flammable gases. SECTION 11 Toxicological information Information on toxicological effects Acute toxicity Inhalation Harmful if inhaled. Skin corrosion/irritation Additional information Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Not classified Repeated exposure may cause skin dryness or cracking Causes serious eye irritation. Not classified Not classified Not classified Reproductive toxicity Not classified 09/04/2015 5/10

6 Specific target organ toxicity (single exposure) May cause drowsiness or dizziness. Specific target organ toxicity (repeated exposure) Not classified Aspiration hazard Not classified SECTION 12 Ecological information Toxicity Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13 Disposal considerations Waste treatment methods Product/Packaging disposal recommendations Additional information Dispose of contents/container to... Handle empty containers with care because residual vapours are flammable. SECTION 14 Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN-No. (ADR) 1173 UN-No. (IMDG) 1173 UN-No.(IATA) 1173 UN-No.(ADN) 1173 UN-No. (RID) /04/2015 6/10

7 14.2. UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport document description (ADR) Transport document description (IMDG) Transport document description (IATA) Transport document description (ADN) Transport document description (RID) ETHYL ACETATE ETHYL ACETATE ETHYL ACETATE ETHYL ACETATE ETHYL ACETATE UN 1173 ETHYL ACETATE, 3, II, (D/E) UN 1173 ETHYL ACETATE, 3, II (-4 C c.c.) UN 1173 ETHYL ACETATE, 3, II UN 1173 ETHYL ACETATE, 3, II UN 1173 ETHYL ACETATE, 3, II Transport hazard class(es) ADR Transport hazard class(es) (ADR) 3 Danger labels (ADR) 3 IMDG Transport hazard class(es) (IMDG) 3 Danger labels (IMDG) 3 IATA Transport hazard class(es) (IATA) 3 Hazard labels (IATA) 3 ADN Transport hazard class(es) (ADN) 3 Danger labels (ADN) 3 RID Transport hazard class(es) (RID) /04/2015 7/10

8 Danger labels (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information II II II II II No No No supplementary information available Special precautions for user - Overland transport Classification code (ADR) Limited quantities (ADR) Excepted quantities (ADR) Packing instructions (ADR) Mixed packing provisions (ADR) Portable tank and bulk container instructions (ADR) Portable tank and bulk container special provisions (ADR) Tank code (ADR) Vehicle for tank carriage F1 1L E2 P001, IBC02, R001 MP19 T4 TP1 LGBF FL Transport category (ADR) 2 Special provisions for carriage - Operation (ADR) Hazard identification number (Kemler No.) 33 Orange plates S2, S20 Tunnel restriction code (ADR) EAC code D/E 3YE - Transport by sea Limited quantities (IMDG) 1 L Excepted quantities (IMDG) E2 Packing instructions (IMDG) P001 IBC packing instructions (IMDG) IBC02 Tank instructions (IMDG) T4 Tank special provisions (IMDG) TP1 EmS-No. (Fire) F-E EmS-No. (Spillage) S-D Stowage category (IMDG) B Flash point (IMDG) -4 C c.c. 09/04/2015 8/10

9 MFAG-No Air transport PCA Excepted quantities (IATA) PCA Limited quantities (IATA) PCA limited quantity max net quantity (IATA) E2 Y341 1L PCA packing instructions (IATA) 353 PCA max net quantity (IATA) 5L CAO packing instructions (IATA) 364 CAO max net quantity (IATA) ERG code (IATA) - Inland waterway transport Classification code (ADN) Limited quantities (ADN) Excepted quantities (ADN) Carriage permitted (ADN) Equipment required (ADN) Ventilation (ADN) 60L 3L F1 1 L E2 T Number of blue cones/lights (ADN) 1 - Rail transport Classification code (RID) Limited quantities (RID) Excepted quantities (RID) Packing instructions (RID) Mixed packing provisions (RID) Portable tank and bulk container instructions (RID) Portable tank and bulk container special provisions (RID) Tank codes for RID tanks (RID) PP, EX, A VE01 F1 1L E2 P001, IBC02, R001 MP19 T4 TP1 Transport category (RID) 2 Colis express (express parcels) (RID) LGBF CE7 Hazard identification number (RID) Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations No REACH Annex XVII restrictions is not on the REACH Candidate List is not on the REACH Annex XIV List National regulations 09/04/2015 9/10

10 Germany AwSV/VwVwS Annex reference 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV Water hazard class (WGK) 1, slightly hazardous to water (Classification according to VwVwS, Annex 2; WGK No 95) Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) Denmark Classification remarks Recommendations Danish Regulation Emergency management guidelines for the storage of flammable liquids must be followed Young people below the age of 18 years are not allowed to use the product Chemical safety assessment SECTION 16 Other information Full text of R-, H- and EUH-phrases Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Flam. Liq. 2 Flammable liquids, Category 2 STOT SE 3 Specific target organ toxicity Single exposure, Category 3, Narcosis H225 Highly flammable liquid and vapour H319 Causes serious eye irritation H332 Harmful if inhaled H336 May cause drowsiness or dizziness R11 Highly flammable R36 Irritating to eyes R66 Repeated exposure may cause skin dryness or cracking R67 Vapours may cause drowsiness and dizziness F Highly flammable Xi Irritant This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 09/04/ /10