Cleaning of hard floor surfaces. The IMEX Building Maxted Road HEMEL HEMPSTEAD Herts HP2 7DX

Transcription

1 Page 1 of 6 BONASYSTEMS LTD Material Safety Data Sheet: BONAPRO 1 Date of issue: June 2013 Revision No: 1 Reason for issue: New product. 1 Product and Company Information Product Name: Intended use: Supplier: Cleaning of hard floor surfaces Bonasystems Europe Ltd The IMEX Building Maxted Road HEMEL HEMPSTEAD Herts HP2 7DX Tel: (+44) Fax: (+44) info@bonasystems.com Emergency Contact: Tel: (+44) Composition/information on ingredients Contains the following substances that have workplace exposure limits and are present at concentrations greater than those specified in the Table attached to Article 3(3) of Directive 1999/45/EEC: CAS No EINECS No Amount present Classification* Ammonium Bifluoride % [T] R25; [C] R34 2-Butoxyethanol % [Xn] R20/21/22; [Xi] R36/38 Magnesium Hexafluorosilicate <1% [T] R25 Fatty Alcohol Ethoxylate 1-5% [Xn] R22; [Xi] R36 Amphoteric Surfactant 1-5% [Xi] R36 Apple Perfume <1% [Sens] R34; [N] R51/53 * at the concentration present

2 Page 2 of 6 3 Hazards identification Main hazards: Harmful if swallowed. Causes burns. 4a First aid measures (Symptoms) Inhalation: Skin contact: Eye contact: Ingestion: There may be shortness of breath with a burning sensation in the throat. Exposure may cause coughing or wheezing. Blistering may occur. Progressive ulceration will occur if treatment is not immediate. Corneal burns may occur. May cause permanent damage. Corrosive burns may appear around the lips. Blood may be vomited. There may be bleeding from the mouth or nose. 4b First aid measures (Actions) Inhalation: Skin contact: Eye contact: Ingestion: Remove the casualty from exposure ensuring one s own safety whilst doing so. If unconscious, and breathing is ok, place in the recovery position. If conscious, ensure the casualty sits or lies down. If breathing becomes bubbly, have the casualty sit and provide oxygen if available. Transfer to hospital as soon as possible. Remove all contaminated clothes and footwear immediately unless stuck to the skin. Drench the affected skin with running water for 10 minutes or longer if substance is still on skin. Transfer to hospital if there are burns or symptoms of poisoning. Bathe the eye with running water for 15 minutes. Transfer to hospital for specialist examination. Wash out mouth with water. Do not induce vomiting. Give 1 cup of water to drink every 10 minutes. If unconscious, check for breathing and apply artificial respiration if necessary. If unconscious and breathing is ok, place in the recovery position. Transfer to hospital as soon as possible. 5 Fire fighting measures Extinguishing media: Exposure hazards: Fire fighting protective Equipment: Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool containers. Corrosive. In combustion emits toxic fumes. Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes. 6 Accidental release measures Personal precautions: Ensure suitable personal protective equipment (see Section 8) during removal of spillages. 2

3 Page 3 of 6 Environmental precautions: Methods for clean up: Do not discharge into drains or rivers. Contain the spillage using bunding. Dilute with copious amounts of water. 7 Handling and storage Handling: Storage: Use protective clothing as described in section 8. Avoid contact with skin and eyes. Store in cool, well ventilated area. Keep container tightly closed. 8 Exposure control/personal protection Hazardous ingredients: Ammonium Bifluoride WEL(8 hr TWA): 2.5mg/m3 2-Butoxyethanol WEL(8 hr TWA): WEL(15 min STEL): 50ppm Exposure controls: Hand protection: Eye protection: Other personal protection: Chemical resistant gloves Safety glasses, safety goggles or face shield Protective overalls and safety shoes/boots. Environmental exposure controls: none 9 Physical and Chemical properties Description: Liquid Colour: Pale blue Odour: Characteristic odour Oxidising: Non- oxidising (by EC criteria) Solubility: Miscible with water Viscosity: Non-viscous Flash point: >70 ph: Stability and reactivity Stability: Stable under normal conditions. Conditions to avoid: Heat. Materials to avoid: Strong oxidising agents. Strong acids. Hazardous decomposition products: In combustion emits toxic fumes. 11 Toxicological information Hazardous ingredients: 2-Butoxyethanol: IVN RAT LD mg/kg 3

4 Page 4 of 6 Routes of exposure: ORL MUS LD mg/kg ORL RAT LD mg/kg Fatty Alcohol Ethoxylate: ORL RAT LD mg/kg Amphoteric Surfactant: ORL RAT LD50>2000 mg/kg Refer to section 4 of SDS for routes of exposure and corresponding symptoms. 12 Ecological information: Hazardous ingredients: Mobility: Persistence and degradability: Bioaccumulative potential: Other adverse effects: Fatty Alcohol Ethoxylate Daphnia Fish Rainbow Trout Readily absorbed into soil. Biodegradable. No bioaccumulation potential. Negligible ecotoxicity. 48H EC mg/l 96H LC mg/l 13 Disposal considerations N.B. The user s attention is drawn to the possible existence of regional or national regulations regarding disposal. 14 Transport information ADR/RID UN Number: 2817 Class: 8 Packing group: III Classification code: CT1 Proper shipping name: Ammonium Hydrogendifluoride Solution Labelling: Hazard ID no: 86 Corrosive 8 image Toxic 6 image IMDG/IMO UN Number: 2817 Class: 8 Packing group: III EmS: F-A,S-B Marine Pollutant: NO Labelling:

5 Page 5 of 6 IATA/ICAO UN Number: 2817 Class: 8 Packing group: III Subsidary risk: 6.1 Packing Instructions: 819(P&CA); 821(CAO) Labelling: Regulatory information Labelling: Symbol for corrosive (x2 test tubes, drips, hands) R 22 Harmful if swallowed R 34 Causes burns S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice S 36/37/39 wear suitable protective clothing, gloves and eye/face protection S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible) May produce an allergic reaction Haz. Ingredients (label): Ammonium Bifluoride N.B. The regulatory information given above only indicates the principal regulations specifically applicable to the product described in the safety data sheet. The user s attention is drawn to the possible existence of additional provisions which complete these regulations. Refer to all applicable national, international and local regulations or provisions. Bonasystems Europe Ltd. The IMEX Building, Maxted Road, HEMEL HEMPSTEAD Herts HP2 7DX, Tel: (+44) EINECS Status: Except for the surfactants, the listed components are on EINECS and also listed in Annex 1 of Directive 67/548/EEC. Additional information: This MSDS has been prepared in accordance with the requirements of: The Dangerous Substances Directive (67/548/EEC), as amended; The Dangerous Preparations Directive (1999/45/EEC) The Safety Data Sheets Directive (91/155/EEC) as amended The Chemicals (Hazardous Information and Packaging for Supply) Regulations ACOP The compilation of safety data sheets (third edition, 2002) The information contained in this MSDS may be of assistance in complying with the 5

6 Page 6 of 6 Control of Substances Hazardous to Health Regulations 2002 and appropriate pollution prevention and control regulations. 16 Other information Risk phrases used in s.3: R25 : Toxic if swallowed. R34: Causes burns. R20/21/22: Harmful by inhalation, in contact with skin and if swallowed. R36/38: Irritating to eyes and skin. R22: Harmful if swallowed. R41: Risk of serious damage to eyes. R36: Irritating to eyes. R43: May cause sensitisation to skin by contact. R51/53 Toxic to aquatic organisims, may cause long-term adverse effects in the aquatic environment. The preparation is intended only for professional use. Only suitably trained professionals should use this preparation and it should be used only for its intended purpose. Further information can be obtained from Bonasystems Europe Ltd. The IMEX Building, Maxted Road, HEMEL HEMPSTEAD Herts HP2 7DX, Tel: (+44) Legal Disclaimer The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product. Sources of key data used in compiling this MSDS: Approved Supply List (Eighth edition, 2005) CESIO (2006) Classification and labelling of surfactants for human health hazards according to the Dangerous Substances Directive CESIO recommendations for anionic and non ionic surfactants accessed via the CESIO website) ESIS (European Substances Information System accessed via the European Chemicals Bureau website) EH40/2005 Workplace exposure limits 2005, and (Publicly available versions from the European Chemicals Bureau website) UN Recommendations and Model Regulations on the Transport of Dangerous Goods (Fifteenth edition) 6