SAFETY DATA SHEET FLAWFINDER CLEANER SPRAY Page 1 Issued: 16/08/2010 Revision No: 6 1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE
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1 FLAWFINDER CLEANER SPRAY Page 1 Revision No: 6 1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING Product name: FLAWFINDER CLEANER SPRAY Use of substance / preparation: Solvent cleaner. Company name: ROCOL ROCOL House Swillington Leeds West Yorkshire LS26 8BS ENGLAND Tel: +44 (0) Fax: +44 (0) Emergency tel: +44 (0) customer-service@rocol.com 2. HAZARDS IDENTIFICATION Main hazards: Extremely flammable. Irritating to eyes and skin. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Vapours may cause drowsiness and dizziness. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous ingredients: PROPAN-2-OL 30-50% EINECS: CAS: [F] R11; [Xi] R36; [-] R67 ISOPARAFFINIC HYDROCARBON 30-50% EINECS: CAS: [F] R11; [Xn] R65; [Xi] R38; [-] R67; [N] R51/53 CARBON DIOXIDE AEROSOL PROPELLANT 5-10% EINECS: CAS: [-] 4. FIRST AID MEASURES (SYMPTOMS) Skin contact: There may be irritation and redness at the site of contact. Eye contact: There may be irritation and redness. The eyes may water profusely. Ingestion: There may be soreness and redness of the mouth and throat. May cause dizziness. Inhalation: There may be irritation of the throat with a feeling of tightness in the chest. Drowsiness or mental confusion may occur. 4. FIRST AID MEASURES (ACTION) Skin contact: Wash immediately with plenty of soap and water. Eye contact: Bathe the eye with running water for 15 minutes. Consult a doctor. Ingestion: Wash out mouth with water. Do not induce vomiting. Consult a doctor. Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. 5. FIRE-FIGHTING MEASURES Extinguishing media: Alcohol resistant foam. Carbon dioxide. Dry chemical powder. Do not use water. Use water spray to cool containers. Exposure hazards: Highly flammable. Forms explosive air-vapour mixture. In combustion emits toxic fumes of carbon dioxide / carbon monoxide. Protection of fire-fighters: Wear self-contained breathing apparatus.
2 FLAWFINDER CLEANER SPRAY Page 2 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Refer to section 8 of SDS for personal protection details. Eliminate all sources of ignition. Environmental precautions: Do not discharge into drains or rivers. Clean-up procedures: Do not use equipment in clean-up procedure which may produce sparks. Mix with sand or vermiculite. Transfer to a closable, labelled salvage container for disposal by an appropriate method. 7. HANDLING AND STORAGE Handling requirements: Ensure there is sufficient ventilation of the area. Do not handle in a confined space. Smoking is forbidden. Storage conditions: Store in cool, well ventilated area. Keep away from sources of ignition. Keep away from direct sunlight. Ensure lighting and electrical equipment are not a source of ignition. Suitable packaging: Must only be kept in original packaging. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Hazardous ingredients: PROPAN-2-OL WEL (8 hr TWA): 999 mg/m3 WEL (15 min STEL): 1250 mg/m3 ISOPARAFFINIC HYDROCARBON WEL (8 hr TWA): 1200 mg/m3 CARBON DIOXIDE AEROSOL PROPELLANT WEL (8 hr TWA): 5000ppm 9150mg/m3 WEL (15 min STEL): 15000ppm 27400mg/m3 Engineering measures: Ensure there is sufficient ventilation of the area. Ensure lighting and electrical equipment are not a source of ignition. Respiratory protection: Respiratory protection not required. Hand protection: Nitrile gloves. Neoprene gloves. Eye protection: Safety glasses with side-shields. Skin protection: Protective clothing. 9. PHYSICAL AND CHEMICAL PROPERTIES State: Aerosol Colour: Colourless Odour: Characteristic odour Evaporation rate: Fast Oxidising: Non-oxidising (by EC criteria) Solubility in water: Miscible Viscosity: Non-viscous Flash point C: < -20 Relative density: STABILITY AND REACTIVITY Stability: Stable under normal conditions. Stable at room temperature. Conditions to avoid: Direct sunlight. Heat. Sources of ignition. Materials to avoid: Strong oxidising agents. Strong reducing agents. Haz. decomp. products: In combustion emits toxic fumes of carbon dioxide / carbon monoxide. 11. TOXICOLOGICAL INFORMATION Hazardous ingredients: PROPAN-2-OL IVN RAT LD mg/kg ORL MUS LD mg/kg ORL RAT LD mg/kg SCU MUS LDLO 6 gm/kg Routes of exposure: Refer to section 4 of SDS for routes of exposure and corresponding symptoms.
3 FLAWFINDER CLEANER SPRAY Page ECOLOGICAL INFORMATION Mobility: Highly volatile. Persistence and degradability: Only slightly biodegradable. Bioaccumulative potential: No data available. Other adverse effects: Toxic to aquatic organisms. 13. DISPOSAL CONSIDERATIONS Disposal operations: D5 Specially engineered landfill (e.g. placement into lined discrete cells which are capped and isolated from one another and the environment, etc.). R1 Solvent reclamation/regeneration. Waste code number: kk Disposal of packaging: Dispose of in a regulated landfill site or other method for hazardous or toxic wastes. NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal. 14. TRANSPORT INFORMATION ADR / RID UN no: 1950 ADR Class: 2 Classification code: 5F Shipping name: AEROSOLS +EHS IMDG / IMO EmS: F-D,S-U Marine pollutant:. +EHS IATA / ICAO +EHS 15. REGULATORY INFORMATION Hazard symbols: Extremely flammable. Irritant. Dangerous for the environment. Risk phrases: R12: Extremely flammable. R36/38: Irritating to eyes and skin. R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R67: Vapours may cause drowsiness and dizziness. Safety phrases: S16: Keep away from sources of ignition - No smoking. S23: Do not breathe spray. S51: Use only in well-ventilated areas. S24/25: Avoid contact with skin and eyes. S35: This material and its container must be disposed of in a safe way.
4 FLAWFINDER CLEANER SPRAY Page 4 Precautionary phrases: Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No smoking. Keep out of the reach of children. Haz. ingredients (label): PROPAN-2-OL; ISOPARAFFINIC HYDROCARBON Note: The regulatory information given above only indicates the principal regulations specifically applicable to the product described in the safety data sheet. The user's attention is drawn to the possible existence of additional provisions which complete these regulations. Refer to all applicable national, international and local regulations or provisions. 16. OTHER INFORMATION Other information: EC Directive 1999/45/EC relating to the classification, packaging and labelling of dangerous preparations. EC Directive 91/155/EEC defining the laying down and detailed arrangements for the system of specific information relating to dangerous preparations. EC Directive 94/1/EC adapting some technicalities of Council Directive 75/324/EEC on the approximation of the laws of Member States relating to aerosol dispensers. Risk phrases used in s.3: R11: Highly flammable. R36: Irritating to eyes. R67: Vapours may cause drowsiness and dizziness. R65: Harmful: may cause lung damage if swallowed. R38: Irritating to skin. R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. None Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product. [final page]
5 FLAWFINDER DYE PENETRANT SPRAY Page 1 Revision No: IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING Product name: FLAWFINDER DYE PENETRANT SPRAY Use of substance / preparation: Dye penetrant. Company name: ROCOL ROCOL House Swillington Leeds West Yorkshire LS26 8BS ENGLAND Tel: +44 (0) Fax: +44 (0) Emergency tel: +44 (0) customer-service@rocol.com 2. HAZARDS IDENTIFICATION Main hazards: Extremely flammable. Repeated exposure may cause skin dryness or cracking. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous ingredients: CARBON DIOXIDE AEROSOL PROPELLANT 1-5% EINECS: CAS: [-] ISOPARAFFINIC HYDROCARBON 30-50% EINECS: CAS: [Xn] R65; [-] R66 WHITE MINERAL OIL 50-70% EINECS: CAS: PETROLEUM DISTILLATE (SEVERE) HYDROTREATED 1-5% CAS: [Xn] R20 4. FIRST AID MEASURES (SYMPTOMS) Skin contact: There may be irritation and redness at the site of contact. Eye contact: There may be irritation and redness. The eyes may water profusely. Ingestion: There may be soreness and redness of the mouth and throat. Inhalation: There may be irritation of the throat with a feeling of tightness in the chest. 4. FIRST AID MEASURES (ACTION) Skin contact: Wash immediately with plenty of soap and water. Eye contact: Bathe the eye with running water for 15 minutes. Consult a doctor. Ingestion: Wash out mouth with water. Do not induce vomiting. Consult a doctor. Inhalation: Consult a doctor. 5. FIRE-FIGHTING MEASURES Extinguishing media: Use water spray to cool containers. Alcohol resistant foam. Dry chemical powder. Carbon dioxide. Do not use water. Exposure hazards: In combustion emits toxic fumes of carbon dioxide / carbon monoxide. Protection of fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Refer to section 8 of SDS for personal protection details. Eliminate all sources of ignition. Environmental precautions: Do not discharge into drains or rivers.
6 FLAWFINDER DYE PENETRANT SPRAY Page 2 Clean-up procedures: Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate method. 7. HANDLING AND STORAGE Handling requirements: Ensure there is sufficient ventilation of the area. Do not handle in a confined space. Storage conditions: Store in cool, well ventilated area. Keep away from direct sunlight. Suitable packaging: Must only be kept in original packaging. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Hazardous ingredients: CARBON DIOXIDE AEROSOL PROPELLANT WEL (8 hr TWA): 5000ppm 9150mg/m3 WEL (15 min STEL): 15000ppm 27400mg/m3 ISOPARAFFINIC HYDROCARBON WEL (8 hr TWA): 1000mg/m³ WHITE MINERAL OIL WEL (8 hr TWA): 5 mg/m3 WEL (15 min STEL): 10 mg/m3 Engineering measures: Ensure there is sufficient ventilation of the area. Respiratory protection: Respiratory protection not normally required. Hand protection: Nitrile gloves. Neoprene gloves. PVA gloves. Eye protection: Safety glasses with side-shields. Skin protection: Protective clothing. 9. PHYSICAL AND CHEMICAL PROPERTIES State: Aerosol Colour: Red Odour: Characteristic odour Evaporation rate: Slow Oxidising: Non-oxidising (by EC criteria) Solubility in water: Not miscible Viscosity: Oily Flash point C: 75 min Relative density: < STABILITY AND REACTIVITY Stability: Stable under normal conditions. Conditions to avoid: Direct sunlight. Heat. Materials to avoid: Strong oxidising agents. Strong reducing agents. Haz. decomp. products: In combustion emits toxic fumes of carbon dioxide / carbon monoxide. 11. TOXICOLOGICAL INFORMATION Routes of exposure: Refer to section 4 of SDS for routes of exposure and corresponding symptoms. 12. ECOLOGICAL INFORMATION Mobility: Non-volatile. Readily absorbed into soil. Persistence and degradability: Only slightly biodegradable. Bioaccumulative potential: No bioaccumulation potential. 13. DISPOSAL CONSIDERATIONS Disposal of packaging: Dispose of in a regulated landfill site or other method for hazardous or toxic wastes. NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal. 14. TRANSPORT INFORMATION ADR / RID UN no: 1950 ADR Class: 2 Classification code: 5A
7 FLAWFINDER DYE PENETRANT SPRAY Page 3 Shipping name: AEROSOLS IMDG / IMO EmS: F-D,S-U Marine pollutant:. IATA / ICAO 15. REGULATORY INFORMATION Hazard symbols: Extremely flammable. Risk phrases: R12: Extremely flammable. R66: Repeated exposure may cause skin dryness or cracking. Safety phrases: S16: Keep away from sources of ignition - No smoking. S24: Avoid contact with skin. S51: Use only in well-ventilated areas. Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No smoking. Keep out of the reach of children. Precautionary phrases: Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 C. Do not pierce or burn, even after use. Haz. ingredients (label): ISOPARAFFINIC HYDROCARBON Note: The regulatory information given above only indicates the principal regulations specifically applicable to the product described in the safety data sheet. The user's attention is drawn to the possible existence of additional provisions which complete these regulations. Refer to all applicable national, international and local regulations or provisions. 16. OTHER INFORMATION Other information: EC Directive 1999/45/EC relating to the classification, packaging and labelling of dangerous preparations. EC Directive 91/155/EEC defining the laying down and detailed arrangements for the system of specific information relating to dangerous preparations. EC Directive 94/1/EC adapting some technicalities of Council Directive 75/324/EEC on the approximation of the laws of Member States relating to aerosol dispensers. Risk phrases used in s.3: None R65: Harmful: may cause lung damage if swallowed. R66: Repeated exposure may cause skin dryness or cracking. R20: Harmful by inhalation. Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product. [final page]
8 FLAWFINDER DEVELOPER SPRAY Page 1 Issued: 21/05/2010 Revision No: 7 1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING Product name: FLAWFINDER DEVELOPER SPRAY Use of substance / preparation: Developer. Company name: ROCOL ROCOL House Swillington Leeds West Yorkshire LS26 8BS ENGLAND Tel: +44 (0) Fax: +44 (0) Emergency tel: +44 (0) customer-service@rocol.com 2. HAZARDS IDENTIFICATION Main hazards: Extremely flammable. Irritating to eyes. Vapours may cause drowsiness and dizziness. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous ingredients: HYDROCARBON AEROSOL PROPELLANT (<0.1% 1,3-BUTADIENE) 30-50% EINECS: CAS: [F+] R12 ACETONE 30-50% EINECS: CAS: [F] R11; [Xi] R36; [-] R66; [-] R67 SILICON DIOXIDE 5-10% EINECS: CAS: FIRST AID MEASURES (SYMPTOMS) Skin contact: There may be irritation and redness at the site of contact. Eye contact: There may be irritation and redness. The eyes may water profusely. Ingestion: There may be soreness and redness of the mouth and throat. May cause dizziness. Inhalation: There may be irritation of the throat with a feeling of tightness in the chest. Drowsiness or mental confusion may occur. 4. FIRST AID MEASURES (ACTION) Skin contact: Wash immediately with plenty of soap and water. Consult a doctor. Eye contact: Bathe the eye with running water for 15 minutes. Consult a doctor. Ingestion: Wash out mouth with water. Do not induce vomiting. Consult a doctor. Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. Consult a doctor. 5. FIRE-FIGHTING MEASURES Extinguishing media: Do not use water. Alcohol resistant foam. Carbon dioxide. Dry chemical powder. Use water spray to cool containers. Exposure hazards: Extremely flammable. Forms explosive air-vapour mixture. In combustion emits toxic fumes of carbon dioxide / carbon monoxide. Protection of fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Refer to section 8 of SDS for personal protection details. Eliminate all sources of ignition. Environmental precautions: Do not discharge into drains or rivers. Clean-up procedures: Do not use equipment in clean-up procedure which may produce sparks. Absorb into dry earth
9 FLAWFINDER DEVELOPER SPRAY Page 2 Issued: 21/05/2010 or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate method. 7. HANDLING AND STORAGE Handling requirements: Ensure there is sufficient ventilation of the area. Do not handle in a confined space. Smoking is forbidden. Storage conditions: Store in cool, well ventilated area. Keep away from sources of ignition. Keep away from direct sunlight. Ensure lighting and electrical equipment are not a source of ignition. Suitable packaging: Must only be kept in original packaging. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Hazardous ingredients: HYDROCARBON AEROSOL PROPELLANT (<0.1% 1,3-BUTADIENE) WEL (8 hr TWA): 1000ppm 1750mg/m3 WEL (15 min STEL): 1250ppm 2180mg/m3 ACETONE WEL (8 hr TWA): 1210 mg/m3 WEL (15 min STEL): 3620 mg/m3 SILICON DIOXIDE WEL (8 hr TWA): 6mg/m3 Respirable dust: SILICON DIOXIDE WEL (8 hr TWA): 2.4mg/m3 Engineering measures: Ensure there is sufficient ventilation of the area. Ensure lighting and electrical equipment are not a source of ignition. Respiratory protection: Respiratory protection not normally required for normal use in well ventilated areas. Respiratory protection should be used in enclosed spaces, with poor ventilation, for extended repeated use, or if workplace exposure limits may be exceeded. A dust mask with P2 particle filter is recommended Hand protection: Neoprene gloves. Butyl gloves. Eye protection: Safety glasses with side-shields. Skin protection: Protective clothing. 9. PHYSICAL AND CHEMICAL PROPERTIES State: Aerosol Colour: White Odour: Characteristic odour Evaporation rate: Fast Oxidising: Non-oxidising (by EC criteria) Solubility in water: Insoluble Viscosity: Non-viscous Boiling point/range C: < 0 Melting point/range C: < 0 Flash point C: < -20 Relative density: STABILITY AND REACTIVITY Stability: Stable under normal conditions. Conditions to avoid: Direct sunlight. Heat. Sources of ignition. Materials to avoid: Strong oxidising agents. Strong reducing agents. Haz. decomp. products: In combustion emits toxic fumes of carbon dioxide / carbon monoxide. 11. TOXICOLOGICAL INFORMATION Hazardous ingredients: ACETONE IVN RAT LD mg/kg ORL MUS LD50 3 gm/kg ORL RAT LD mg/kg Routes of exposure: Refer to section 4 of SDS for routes of exposure and corresponding symptoms.
10 FLAWFINDER DEVELOPER SPRAY Page 3 Issued: 21/05/ ECOLOGICAL INFORMATION Mobility: Volatile. Persistence and degradability: Only slightly biodegradable. Bioaccumulative potential: No bioaccumulation potential. 13. DISPOSAL CONSIDERATIONS Disposal of packaging: Dispose of in a regulated landfill site or other method for hazardous or toxic wastes. NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal. 14. TRANSPORT INFORMATION ADR / RID UN no: 1950 ADR Class: 2 Classification code: 5F Shipping name: AEROSOLS IMDG / IMO EmS: F-D,S-U Marine pollutant:. IATA / ICAO 15. REGULATORY INFORMATION Hazard symbols: Extremely flammable. Irritant. Risk phrases: R12: Extremely flammable. R36: Irritating to eyes. R67: Vapours may cause drowsiness and dizziness. Safety phrases: S16: Keep away from sources of ignition - No smoking. S23: Do not breathe spray. S25: Avoid contact with eyes. S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S38: In case of insufficient ventilation, wear suitable respiratory equipment. Precautionary phrases: Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No smoking. Keep out of the reach of children. Haz. ingredients (label): ACETONE Note: The regulatory information given above only indicates the principal regulations specifically applicable to the product described in the safety data sheet. The user's attention is drawn to
11 FLAWFINDER DEVELOPER SPRAY Page 4 Issued: 21/05/2010 the possible existence of additional provisions which complete these regulations. Refer to all applicable national, international and local regulations or provisions. 16. OTHER INFORMATION Other information: EC Directive 1999/45/EC relating to the classification, packaging and labelling of dangerous preparations. EC Directive 91/155/EEC defining the laying down and detailed arrangements for the system of specific information relating to dangerous preparations. EC Directive 94/1/EC adapting some technicalities of Council Directive 75/324/EEC on the approximation of the laws of Member States relating to aerosol dispensers. Risk phrases used in s.3: R12: Extremely flammable. R11: Highly flammable. R36: Irritating to eyes. R66: Repeated exposure may cause skin dryness or cracking. R67: Vapours may cause drowsiness and dizziness. Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product. [final page]
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