SAFETY DATA SHEET Page 1 of 7

Transcription

1 SAFETY DATA SHEET Page 1 f 7 Date Prepared: June 1, 2015 MSDS N: Backscratchers Cavicide - GHS 1. PRODUCT AND COMPANY IDENTIFICATION GENERAL USE: Saln Aseptic/Disinfectant Cleaner PRODUCT DESCRIPTION: Hard surface cleaner and disinfectant. MANUFACTURER Backscratchers Saln Systems, Inc Elkmnt Way Elk Grve, Califrnia Emergency Cntact: CHEMTEL Emergency Phne: (USA) Alternate Emergency Phne: (Outside USA/Call Cllect) Prduct Stewardship: Backscratchers Saln Systems, Inc HAZARDS IDENTIFICATION GHS CLASSIFICATIONS Health: Flammable, Categry 3 Eye irritatin, Categry 2 Specific Target Organ Txicity Single Expsure Categry 3 (Narctic effects) SIGNAL WORD: WARNING GHS LABEL ELEMENTS Exclamatin Mark Flammable HAZARD STATEMENTS: H226: Flammable liquid and vapr. H319: Causes serius eye irritatin. H336: May cause drwsiness r dizziness. Precautinary Phrases P210: Keep away frm heat, sparks, pen flames, ht surfaces - N smking. P233: Keep cntainer tightly clsed. P241: Use explsin-prf electrical, ventilating and light equipment. P243: Take precautinary measures against static discharge.

2 SAFETY DATA SHEET Page 2 f 7 Date Prepared: June 1, 2015 MSDS N: Backscratchers Cavicide- GHS P312: Call a pisn center/dctr if yu feel unwell. P305+P351+P338 IF IN EYES: Rinse cautiusly with water fr several minutes. Remve cntact lenses if present and easy t d - cntinue rinsing. P337+P313: If eye irritatin persists get medical attentin. P370+P378: In case f fire: Use water spray r fg, alchl-resistant fam, carbn dixide r dry chemical t extinguish. P403+P235: Stre in a well-ventilated place. Keep cl. P501: Dispse f cntents and cntainer in accrdance with lcal and natinal regulatins. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name Wt. % CAS GHS Classificatin Isprpanl Ethylene Glycl Mnbutyl Ether (2-Butxyethanl) Diisbutylphenxeyethxyethyldin ethylbenzylammnium chlride Water % % % % Flam Liquid 2 (H226) Eye Irrt. 2 (H319) STOT SE 3 (H336) Acute Tx 4 (H302) Acute Tx 3 (H311) Acute Tx 3 (H331) Skin Irrit. 2 (H315) Eye Irrit. 2 (H319) Acute Tx 3 (H301) Skin Crr 1A (H314) Eye Dam 1 (H318) STOT SE 3 (H335) Aquatic Chrnic 2 (H411) Nt classified as hazardus 4. FIRST AID MEASURES INHALATION: Mve t fresh air if effects ccur and seek medical attentin if effects persist. SKIN CONTACT: Remve cntaminated clthing. Rinse skin immediately with plenty f water fr minutes. Call a pisn cntrl center r dctr fr further treatment advice. EYE CONTACT: Hld eye pen and rinse slwly and gently with water fr minutes. Remve cntact lenses, if present, after the first 5 minutes, then cntinue rinsing. Call a pisn cntrl center fr treatment advice. INGESTION: If swallwed, get medical advice by calling a pisn cntrl center r hspital emergency rm. If advice is nt available, take victim and prduct cntainer t the nearest emergency treatment center r hspital. D nt attempt t give anything by muth t an uncnscius persn. MOST IMPORTANT SYMPTOMS AND EFFECTS BOTH ACUTE AND DELAYED: Causes serius eye irritatin. Inhalatin f cncentrated vaprs may cause irritatin f the eyes, nse and thrat and dizziness and drwsiness. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT: Immediate medical attentin is generally nt required.

3 SAFETY DATA SHEET Page 3 f 7 MSDS N: Backscratchers Cavicide - GHS 5. FIRE FIGHTING MEASURES EXTINGUISHING MEDIA: Use water spray r fg, alchl-resistant fam, carbn dixide r dry chemical. Cl fire expsed cntainers with water. SPECIAL HAZARDS ARISING FROM SUBSTANCE OR MIXTURE: Flammable liquid and vapr. May frm explsive mixtures in air temperatures at r abve flashpint. Flammable vaprs may cllect in cnfined areas. Vaprs are heavier than air and may travel alng surfaces t remte ignitin surces and flashback. Fire expsed cntainers may rupture explsively. ADVICE FOR FIREFIGHTERS: Firefighters shuld wear psitive pressure self-cntained breathing apparatus and full prtective clthing fr fires in areas where chemicals are used r stred. 6. ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES: Wear apprpriate prtective clthing and equipment. ENVIRONMENTAL PRECAUTIONS: Avid release t the envirnment. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP: Eliminate all ignitin surces. Ventilate area. Use explsin-prf equipment if large amunts are released. Stp leak if it is safe t d s and mve cntainers frm the spill area. Cllect material with an inert absrbent material and place in apprpriate, labeled cntainer fr dispsal. 7. HANDLING & STORAGE PRECAUTIONS FOR SAFE HANDLING: D nt get in eyes r n clthing. Wear apprpriate eye prtectin when handling. Wash thrughly with sap and water after handling and befre eating, drinking, chewing gum, using tbacc r using the tilet. Remve and wash cntaminated clthing befre reuse. Flammable liquid and vapr. Keep away frm heat, sparks, pen flames and all ther surces f ignitin. D nt smke in strage r use areas. Keep cntainers clsed when nt in use. D nt reuse empty cntainers. CONDITIONS FOR SAFE STORAGE, INCLUDING AND INCOMPATIBILITIES: Stre in a cl, well-ventilated area away frm heat, xidizers and all surces f ignitin. D nt cntaminate water, fd r feed by strage. Empty cntainers retain prduct residues and may be hazardus. D nt flame cut, drill, weld, etc. n r near empty cntainers, even empty. SPECIFIC END USE(S): Hard surface cleaner and disinfectant. 8. EXPOSURE CONTROLS /PERSONAL PROTECTION CHEMICAL KOREAN EXPOSURE LIMIT Isprpanl Ethylene Glycl Mnbutyl Ether (2-Butxyethanl) Diisbutylphenxyethxyethyldimethyl benzylammnium chlride Water 200 ppm 8 hr. Expsure Limit 400 ppm Shrt Term Expsure 20 ppm 8 hr Expsure Limit Nne established Nne established

4 SAFETY DATA SHEET Page 4 f 7 MSDS N: Backscratchers Cavicide - GHS EXPOSURE CONTROLS: RECOMMENDED MONITORING PROCEDURES: Cllectin n charcal and analysis by gas chrmatgraphy. APPROPRIATE ENGINEERING CONTROLS: General ventilatin shuld be adequate fr nrmal use. Fr peratins where expsure limits may be exceeded, mechanical ventilatin such as lcal exhaust may be needed t minimize expsure. Use explsin prf electrical equipment and wiring where required. PERSONAL PROTECTIVE MEASURES: RESPIRATORY PROTECTION: General ventilatin shuld be adequate fr nrmal use. Fr peratins where the expsure limits may be exceeded, mechanical ventilatin such as lcal exhaust may be needed t minimize expsure. Use explsin prf electrical equipment and wiring where required. EYE PROTECTION: Splash prf gggles, face shield, r safety glasses are recmmended t prevent eye cntact. SKIN PROTECTION: Impervius glves such as butyl rubber r nitrile are recmmended fr peratins which may result in prlnged r repeated skin cntact. OTHER PROTECTION: Wear prtective clthing if needed t avid prlnged/repeated skin cntact. Suitable washing and eye flushing facilities shuld be available in the wrk area. Cntaminated clthing shuld be remved and laundered befre reuse. 9. PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Clear liquid ODOR: Alchl ODOR THRESHOLD: Odr Threshld = ppm ph: FREEZING POINT: Nt determined MELTING POINT: Nt determined BOILING POINT: 215 F 102 C FLASHPOINT: 28.3 C (83 F) EVAPORATION RATE: Nt determined FLAMMABILITY (SOLID/GAS): Nt applicable FLAMMABLE EXPLOSIVE LIMITS: LEL: 2% UEL: 12.7% PERCENT VOLATILE: Nt available VAPOR PRESSURE: 43.3 C (isprpanl) VAPOR DENSITY: 2.1 (isprpanl) RELATIVE DENSITY/SPECIFIC GRAVITY: SOLUBILITY IN WATER: Cmplete PARTITION COEFF. NOCTANOL/WATER: Nt determined AUTOIGNITION TEMPERATURE: Nt determined DECOMPOSITION TEMPERATURE: Nt determined VISCOSITY #1: Nt determined EXPLOSIVE PROPERTIES: Vaprs may explde if cnfined OXIDIZING PROPERTIES: Nne 10. STABILITY AND REACTIVITY REACTIVITY: Nt reactive at ambient temperatures. CHEMICAL STABILITY: Stable POSSIBILITY IF HAZARDOUS REACTIONS: Nt reactive. CONDITIONS TO AVOID: Heat, sparks, flames and all ther surces f ignitin. INCOMPATIBLE MATERIALS: Strng xidizing agents, acids and strng reducing agents. HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decmpsitin will prduce carbn mnxide, carbn dixide, nitrgen xides, amines, chlrine and hydrgen chlride.

5 SAFETY DATA SHEET Page 5 f 7 MSDS N: Backscratchers Cavicide - GHS 11. TOXICOLOGICAL INFORMATION POTENTIAL HEALTH EFFECTS: INHALATION: May cause irritatin f the nse, thrat and upper respiratry tract. High vapr cncentratins may prduce nausea, vmiting, headache, dizziness, drwsiness, weakness, fatigue, narcsis and pssible uncnsciusness. SKIN CONTACT: Prlnged r repeated expsure may cause mild irritatin. EYE CONTACT: May cause irritatin with tearing, redness and pain. INGESTION: Ingestin may cause gastrintestinal disturbances and central nervus system effects such as headache, dizziness, drwsiness and nausea. ACUTE TOXICITY VALUES: LD50 ORAL : Oral rate >5000 mg/kg LD50 DERMAL LD: Dermal rabbit >2000 mg/kg LC50 INHALATION LC: LC50 rat>2.08 mg/l 12. ECOLOGICAL INFORMATION TOXICITY: Isprpanl: L50 fathead minnws 11, 130 mg/l/48 hr; LC50 brwn shrimp 1400 mg/l/48 hr; Diisbutylphenxyethyldimethylbenzylammnium Chlride: LC50 pimephales prmelas 1.6 mg/l/96 hr. LC50 lepmis macrchirus 1.4 mg/l/96 hr. PERSISTENCE AND DEGRADABILITY: Isprpanl and 2-butxyethanl are readily bidegradable in screening tests. Diisbutylphenxyethyldimethylbenzylammnium Chlride is nt readily bidegradable. BIOACCUMULATIVE POTENTIAL: Isprpanl has an estimated BCF f 3 suggesting that the ptential fr biaccumulatin is lw. MOBILITY IN SOIL: Isprpanl is expected t have a very high mbility in sil. RESULTS OF PVT AND VPvB ASSESSMENT: Nne required. OTHER ADVERSE EFFECTS: Nne knwn. 13. DISPOSAL CONSIDERATIONS WASTE TREATMENT METHODS: D nt cntaminate water, fd, r feed by strage and dispsal. PESTICIDE DISPOSAL: Unused prduct r wastes resulting frm the use f this prduct may be dispsed f accrding t applicable federal, state r lcal prcedures. CONTAINER DISPOSAL: Nnrefillable cntainer. D nt use r refill this cntainer. Offer recycling, if available.

6 SAFETY DATA SHEET Page 6 f 7 MSDS N: Backscratchers Cavicide- GHS 14. TRANSPORT INFORMATION DOT (DEPARTMENT OF TRANSPORTATION) PROPER SHIPPING NAME: Cnsumer Cmmdity ROAD AND RAIL (ADR/RID): PROPER SHIPPING NAME: Backscratchers Cavicide AIR (ICAO/IATA) SHIPPING NAME: Nt regulated VESSEL (IMO/IMDG) SHIPPING NAME: Nt regulated CANADA TRANSPORT OF DANGEROUS GOODS SHIPPING NAME: Nt regulated 15. REGULATORY INFORMATION UNITED STATES SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT) 311/312 HAZARD CATEGORIES: Fire Hazard, Acute Health, Chrnic Health 313 REPORTABLE INGREDIENTS: This prduct cntains the fllwing chemicals subject t annual release reprting under the SARA Title III. Sectin 313 (40 CFR 372) requirements. Ethyl Glycl Mnbutyl Ether (Glycl Ethr) 1-5% TSCA (TOXIC SUBSTANCE CONTROL ACT) TSCA STATUS: All cmpnents are listed n r are exempt frm listing n the Txic Substances Cntrl Act. CALIFORNIA PROPOSITION 65: N Califrnia Prpsitin 65 ingredients are knwn in this prduct. CANADA: Minimum risk, Grade 0 MEXICO: Minimum risk, Grade 0

7 SAFETY DATA SHEET Page 7f 7 MSDS N: Backscratcher s Cavicide - GHS 16. OTHER INFORMATION PREPARED BY: Julie Petrne DATE REVISED: June 1, 2015 REVISION SUMMARY: This SDS replaces the January 1, 2011 MSDS. HMIS RATING HEALTH FLAMMABILITY PHYSICAL HAZARD NFPA CODES PERSONAL PROTECTION MANUFACTURER DISCLAIMER: T the best f ur knwledge, the infrmatin cntained herein is accurate. Hwever, Backscratchers Saln Systems, Inc., des nt assume any liability fr the accuracy r cmpleteness f the infrmatin cntained herein. Final determinatin f suitability f any materials is the sle respnsibility if the user. All materials may present unknwn hazards and shuld be used with cautin. Althugh certain hazards are described herein, we cannt guarantee that these are the nly hazards that exist.