SAFETY DATA SHEET PRINTLAC HIGH GLOSS FD

Transcription

1 Revision Date 13/03/10 Revision 2 Supersedes date 12/05/10 SAFETY DATA SHEET SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product name Product No Relevant identified uses of the substance or mixture and uses advised against Identified uses Overprint Varnish 1.3. Details of the supplier of the safety data sheet Supplier 1.4. Emergency telephone number SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture STEHLIN HOSTAG INK UK LTD UNIT D4 LINKMEL CLOSE QUEENS DRIVE INDUSTRIAL ESTATE NOTTINGHAM NG2 1NA Tel : Fax : sds@stehlin.co.uk Classification (1999/45/EEC) Physical and Chemical Hazards Human health Environment 2.2. Label elements Contains Distllates (petroleum), hydrodesulphurised middle Cobalt Octoate DE-Aromatised Kerosene ETHYL METHYL KETOXIME Label In Accordance With (EC) No. 1272/2008 Supplemental label information EUH Other hazards Contains Cobalt Octoate May produce an allergic reaction Safety data sheet available on request. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures 1 / 6

2 Distllates (petroleum), hydrodesulphurised middle 30-40% CAS-No.: EC No.: EUH066 Asp. Tox. 1 - H304 Xn;R65. R66. Cobalt Octoate <1.5% CAS-No.: EC No.: Acute Tox. 4 - H302 Skin Sens. 1 - H317 Xn;R22. R43. DE-Aromatised Kerosene <1.5% CAS-No.: EC No.: EUH066 Asp. Tox. 1 - H304 Xn;R65. R66. ETHYL METHYL KETOXIME <1.5% CAS-No.: EC No.: Acute Tox. 4 - H312 Eye Dam. 1 - H318 Skin Sens. 1 - H317 Carc. 2 - H351 Carc. Cat. 3;R40 Xn;R21 R43 Xi;R41 The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures General information General first aid, rest, warmth and fresh air. Remove contaminated clothes. Get medical attention if any discomfort continues. Inhalation General first aid, rest, warmth and fresh air. Perform artificial respiration if breathing has stopped. Place unconscious person on the side in the recovery position and ensure breathing can take place. Get medical attention if any discomfort continues. Ingestion DO NOT induce vomiting. Get medical attention immediately. Provide fresh air, warmth and rest, preferably in comfortable upright sitting position. Skin contact Remove contaminated clothing immediately and wash skin with soap and water. Eye contact Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyes wide apart. Get medical attention if any discomfort continues Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: FIREFIGHTING MEASURES 2 / 6

3 5.1. Extinguishing media Extinguishing media Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog Special hazards arising from the substance or mixture Unusual Fire & Explosion Hazards Keep containers cool by spraying with water Specific hazards In case of fire, toxic gases may be formed Advice for firefighters Protective equipment for fire-figthers Self contained breathing apparatus and full protective clothing must be worn in case of fire. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures For personal protection, see section Environmental precautions Spillages or uncontrolled discharges into watercourses must be IMMEDIATELY alerted to the Environmental Agency or other appropriate regulatory body. Do not discharge into drains, water courses or onto the ground Methods and material for containment and cleaning up Collect with absorbent, non-combustible material into suitable containers. Collect spillage in containers, seal securely and deliver for disposal according to local regulations Reference to other sections SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Avoid contact with skin and eyes Conditions for safe storage, including any incompatibilities Store in tightly closed original container in a dry, cool and well-ventilated place. Keep upright Specific end use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Name STD TWA - 8 Hrs STEL - 15 Min Notes Cobalt Octoate WEL 0.1 mg/m3 DE-Aromatised Kerosene WEL 1000 mg/m3 Distllates (petroleum), hydrodesulphurised middle WEL = Workplace Exposure Limit. WEL 5 ppm 8.2. Exposure controls Protective equipment Engineering measures Provide adequate ventilation. Hand protection Use suitable protective gloves if risk of skin contact. Eye protection Wear approved safety goggles. 3 / 6

4 Other Protection Wear appropriate clothing to prevent any possibility of skin contact. Wear suitable protective clothing as protection against splashing or contamination. Hygiene measures Wash hands after contact. No specific hygiene procedures noted, but good personal hygiene practices are always advisable, especially when working with chemicals. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance Colour Odour Solubility Viscous liquid. Amber brown Characteristic. Immiscible with water Initial boiling point and boiling range >250 degrees C Flash point ( C) 9.2. Other information >110 degrees C SECTION 10: STABILITY AND REACTIVITY Reactivity Chemical stability Stable under normal temperature conditions and recommended use Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products In case of fire, toxic gases (CO, CO2, NOx) may be formed. SECTION 11: TOXICOLOGICAL INFORMATION Information on toxicological effects Toxicological information No data recorded. Skin contact Irritating to skin. Eye contact May cause irritation SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity There are no data on the ecotoxicity of this product. Do not discharge into drains or the environment Toxicity Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13: DISPOSAL CONSIDERATIONS General information Waste to be treated as controlled waste. Disposal to licensed waste disposal site in accordance with local Waste Disposal Authority. 4 / 6

5 13.1. Waste treatment methods SECTION 14: TRANSPORT INFORMATION General UN number The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA, ADR/RID) UN proper shipping name Transport hazard class(es) Packing group Environmental hazards Special precautions for user Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code SECTION 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture Uk Regulatory References Chemicals (Hazard Information & Packaging) Regulations. Health and Safety at Work Act EU Legislation Updated to the Directive 2004/73/EC, revised to the 29th amendment Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments Chemical Safety Assessment SECTION 16: OTHER INFORMATION Revision Comments 2 Converted to GHS format Issued By Revision Date 13/03/10 Revision 2 Supersedes date 12/05/10 SDS No Safety Data Sheet Status B.A Hayden HSQE Manager Approved. Date 09/01/12 Risk Phrases In Full R22 R21 R65 R40 R43 R66 R41 Hazard Statements In Full H318 H302 H312 H304 H317 EUH066 H351 Harmful if swallowed. Harmful in contact with skin. Harmful: may cause lung damage if swallowed. Limited evidence of a carcinogenic effect. May cause sensitisation by skin contact. Repeated exposure may cause skin dryness or cracking. Risk of serious damage to eyes. Causes serious eye damage. Harmful if swallowed. Harmful in contact with skin. May be fatal if swallowed and enters airways. May cause an allergic skin reaction. Repeated exposure may cause skin dryness or cracking. Suspected of causing cancer. 5 / 6

6 Disclaimer This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 6 / 6