SAFETY DATA SHEET NEUTRA SEAL STD

Transcription

1 Revision Date 10/11/11 Revision 2 Supersedes date 19/5/09 SAFETY DATA SHEET SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product name Product No. 40B Relevant identified uses of the substance or mixture and uses advised against Identified uses Overprint Varnish 1.3. Details of the supplier of the safety data sheet Supplier STEHLIN HOSTAG INK UK LTD UNIT D4 LINKMEL CLOSE QUEENS DRIVE INDUSTRIAL ESTATE NOTTINGHAM NG2 1NA Tel : Fax : sds@stehlin.co.uk 1.4. Emergency telephone number SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Physical and Chemical Hazards Human health Environment Classification (1999/45/EEC) R43. Not classified. Skin Sens. 1 - H317 Not classified. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. Human health May cause sensitisation by skin contact 2.2. Label elements Contains Cobalt Octoate Label In Accordance With (EC) No. 1272/2008 Signal Word Hazard Statements Warning H317 May cause an allergic skin reaction. 1 / 6

2 Precautionary Statements P280 Supplementary Precautionary Statements 2.3. Other hazards Contains Cobalt Octoate May produce an allergic reaction Wear protective gloves/protective clothing/eye protection/face protection. P272 Contaminated work clothing should not be allowed out of the workplace. P261 Avoid breathing vapour/spray. P321 Specific treatment (see medical advice on this label). P IF ON SKIN: Wash with plenty of soap and water. P If skin irritation or rash occurs: Get medical advice/attention. P363 Wash contaminated clothing before reuse. P501 Dispose of contents/container to SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures Distllates (petroleum), hydrodesulphurised middle 40-50% CAS-No.: EC No.: EUH066 Asp. Tox. 1 - H304 Classification (67/548/EEC) Xn;R65. R66. Cobalt Octoate <5% CAS-No.: EC No.: Acute Tox. 4 - H302 Skin Sens. 1 - H317 Classification (67/548/EEC) Xn;R22. R43. DE-Aromatised Kerosene <1.5% CAS-No.: EC No.: EUH066 Asp. Tox. 1 - H304 Classification (67/548/EEC) Xn;R65. R66. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures General information General first aid, rest, warmth and fresh air. Get medical attention if any discomfort continues. Remove contaminated clothes. Inhalation General first aid, rest, warmth and fresh air. If breathing stops, provide artificial respiration. Place unconscious person on the side in the recovery position and ensure breathing can take place. Get medical attention. 2 / 6

3 Ingestion Do not induce vomiting. Get medical attention immediately! Provide fresh air, warmth and rest, preferably in comfortable upright sitting position. Skin contact Remove contaminated clothing immediately and wash skin with soap and water. Eye contact Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyes wide apart. Get medical attention if any discomfort continues Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing media Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog Special hazards arising from the substance or mixture Unusual Fire & Explosion Hazards Keep containers cool by spraying with water Specific hazards In case of fire, toxic gases may be formed Advice for firefighters Special Fire Fighting Procedures Water spray should be used to cool containers. Protective equipment for fire-fighters Self contained breathing apparatus and full protective clothing must be worn in case of fire. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures For personal protection, see section Environmental precautions Spillages or uncontrolled discharges into watercourses must be IMMEDIATELY alerted to the Environmental Agency or other appropriate regulatory body Methods and material for containment and cleaning up Collect with absorbent, non-combustible material into suitable containers. Collect spillage in containers, seal securely and deliver for disposal according to local regulations Reference to other sections SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Avoid contact with skin and eyes Conditions for safe storage, including any incompatibilities Store in tightly closed original container in a dry and cool place. Keep upright Specific end use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters 3 / 6

4 Name STD TWA - 8 Hrs STEL - 15 Min Notes Cobalt Octoate WEL 0.1 mg/m3 DE-Aromatised Kerosene WEL 1000 mg/m3 WEL = Workplace Exposure Limit Exposure controls Protective equipment Engineering measures Provide adequate ventilation. Hand protection Use suitable protective gloves if risk of skin contact. Eye protection Wear approved safety goggles. Other Protection Wear suitable protective clothing as protection against splashing or contamination. Hygiene measures Wash hands after contact. No specific hygiene procedures noted, but good personal hygiene practices are always advisable, especially when working with chemicals. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance Viscous liquid. Colour White / off-white. Odour Characteristic. Solubility Immiscible with water Initial boiling point and boiling >250 range Relative density Viscosity 3-5 Pas 25 Flash point >110 degrees C 9.2. Other information SECTION 10: STABILITY AND REACTIVITY Reactivity Chemical stability Stable under normal temperature conditions and recommended use Possibility of hazardous reactions Not determined Conditions to avoid Avoid heat, flames and other sources of ignition Incompatible materials Materials To Avoid Flammable/combustible material. 4 / 6

5 10.6. Hazardous decomposition products In case of fire, toxic gases (CO, CO2, NOx) may be formed. SECTION 11: TOXICOLOGICAL INFORMATION Information on toxicological effects Toxicological information No data recorded. Skin contact Irritating to skin. Eye contact May cause irritation SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity There are no data on the ecotoxicity of this product. Do not discharge into drains, water courses or onto the ground Toxicity Acute Fish Toxicity No data available Persistence and degradability Degradability There are no data on the degradability of this product Bioaccumulative potential Bioaccumulative potential No data available on bioaccumulation Mobility in soil Mobility: The product is insoluble in water: it spreads on the surface of the water Results of PBT and vpvb assessment This product does not contain any PBT or vpvb substances Other adverse effects Not determined. SECTION 13: DISPOSAL CONSIDERATIONS General information Waste to be treated as controlled waste. Disposal to licensed waste disposal site in accordance with local Waste Disposal Authority Waste treatment methods Dispose of waste and residues in accordance with local authority requirements. SECTION 14: TRANSPORT INFORMATION General UN number The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA, ADR/RID). 5 / 6

6 14.2. UN proper shipping name Transport hazard class(es) Packing group Environmental hazards Special precautions for user Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code SECTION 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture Uk Regulatory References Health and Safety at Work Act Chemicals (Hazard Information & Packaging) Regulations. EU Legislation Updated to the Directive 2004/73/EC, revised to the 29th amendment Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments Chemical Safety Assessment SECTION 16: OTHER INFORMATION Revision Comments Items revised have been marked. Issued By Revision Date 10/11/11 Revision 2 Supersedes date 19/5/09 SDS No Safety Data Sheet Status B.A Hayden HSQE Manager Approved. Date Issued: 19/3/12 Risk Phrases In Full R22 R65 R43 R66 Hazard Statements In Full H302 H304 H317 EUH066 Harmful if swallowed. Harmful: may cause lung damage if swallowed. May cause sensitisation by skin contact. Repeated exposure may cause skin dryness or cracking. Harmful if swallowed. May be fatal if swallowed and enters airways. May cause an allergic skin reaction. Repeated exposure may cause skin dryness or cracking. Disclaimer This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 6 / 6