1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER Product Name Other Names (if ) Product Code Barcode Number Recommended Use Company Name ABN Street Address Telephone Number Supplier Code Other Emergency Phone Number PROTANE Naturals Tea Tree Oil Shampoo 55732 26287072 Hair Care - Rinse-Off ALDI STORES (A Limited Partnership) 90 196 565 019 1 Sargents Road, MINCHINBURY, NSW 2770 +61 2 9675 9000 102 Australia - 13 11 26 (Poisons Information Centre) 2. HAZARDS IDENTIFICATION Classification of the substance or mixture HAZARDOUS CHEMICAL. DANGEROUS GOODS. According to the WHS Regulations and the ADG Code. NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to WHS Regulation and ADG Code. Label elements GHS label Not Applicable Not Applicable Not Applicable elements Not Applicable Signal Word Not Applicable Not Applicable Not Applicable Not Applicable Hazard statement (s) None under normal operating conditions Precautionary statement (s) None under normal operating conditions Other hazards Not Applicable This document becomes uncontrolled once printed. Page 1 of 7
3. COMPOSITION / INFORMATION ON INGREDIENTS Substances See section below for composition mixtures Mixtures Components CAS Number Proportion The specific chemical identity and/or exact percetage (concentration) of composition has been withheld as a trade secret. Ingredients determined not to be hazardous. This document becomes uncontrolled once printed. Page 2 of 7
4. FIRST AID MEASURES For advice, contact Poisons Information Centre (phone Australia 13 11 26) or a doctor (For each route of exposure provide indication of medical attention and special treatment needed including description of most important symptoms, acute and delayed) Inhalation Skin Contact Eye Contact Ingestion Note to Physician - If fumes, aerosols or combustion products are inhaled remove from contaminated area. - Other measures are usually unnecessary. - Concentrate and dilution solution is readily removed with water. - Abraded or broken skin should be washed carefully and thoroughly. - Seek medical attention in event of irritation. If this product comes in contact with the eyes: - Wash out immediately with fresh running water. - Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. - Seek medical attention without delay; if pain persists or recurs seek medical attention. - Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. - If swallowed do NOT induce vomiting. - If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. - Observe the patient carefully. - Never give liquid to a person showing signs of being sleepy or with reduced awareness i.e. becoming unconscious - Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. - Seek medical advice. Treat symptomatically 5. FIRE FIGHTING MEASURES Hazards from combustion products Precautions for firefighters and special protective equipment Suitable / Unsuitable extinguishing material - Non combustible Not considered a significant fire risk, however, containers may burn. - Alert Fire Brigade and tell them location and nature of hazard. - Wear breathing apparatus plus protective gloves in the event of fire. - Prevent, by any means available, spillage from entering drains or water courses. - Use fire fighting procedures suitable for surroundin area. - DO NOT approach containers suspected to be hot. - Cool fire exposed containers with water spray from a protected location. - If safe to do so, remove containers from path of fire. - Equipment should be thoroughly decontaminated after use. -There is no restriction on the type of extinguisher which may be used. Use extinguishing media suitable for surrounding area. 6. ACCIDENTAL RELEASE MEASURES Emergency procedures Methods and materials for containment and clean up Environmental precaution(s) 'For minor spills, slippery when spilt. - Clean up all spills immediately. - Avoid breathing vapours and contact with skin and eyes. - Control personal contact by using protective equipment. - Contain and absorb spill with sand, earth, inert material or vermiculite. For major spills, slippery when spilt. - Clear area of personnel and move upwind. - Alert Fire Brigade and tell them location and nature of hazard. - Control personal contact by using protective equipment. - Prevent spillage from entering drains, sewers or water courses. 7. HANDLING AND STORAGE Precautions for safe handling Procedure for handling: - None required when handling small quantities. OTHERWISE: - Limit all unncessary personal contact. - Wear protective clothing when risk of exposure occurs. - Use in a well-ventilated area. - When handling DO NOT eat, drink or smoke. This document becomes uncontrolled once printed. Page 3 of 7
Conditions for safe storage - Suitable Container: - Packaging as recommended by manufacturer - Check that containers are clearly labelled - Storage incompatibility: - Avoid contamination of water, foodstuffs, feed or seed. - None known - Store in original containers. - Keep containers securely sealed. - Store in a cool, dry, well-ventilated area. Avoid direct exposure to sunlight. - Store away from incompatible materials and foodstuff containers. - Protect containers against physical damage and check regularly for leaks. - Observe manufacturer's storage and handling recommendations contained within the MSDS. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION National Exposure Standards Biological Limit Values Engineering Controls Personal Protective Equipment None required when handling small quantities. Provide adequate ventilation in warehouse or closed storage areas. OTHERWISE - Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. - Well-designed engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection. The basic types of engineering controls are: - Process controls which involve changing the way a job activity or process is done to reduce the risk. - Enclosure and/ or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically "adds" and "removes" air in the work environment. For Eye - no special equipment for minor exposure i.e. when handling small quantities. OTHERWISE: Safety glasses with side shields For Hands/Feet - no special equipment needed when handling small quantities. OTHERWISE: Wear general protective gloves. e.g. light weight rubber gloves. OTHER - no special equipment needed when handling small quantities. OTHERWISE: Overalls, Barrier cream, Eyewash unit. This document becomes uncontrolled once printed. Page 4 of 7
9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Colour Odour ph Specific Gravity or Density Vapour Pressure Vapour Density Percent Volatiles Boiling Point Range Freezing/ Melting Point Solubility Flash Point (include method detection) Flammability Limits Ignition Temperature Other Off-white, pearlised, slightly viscous; mixes with water. Off-white, pearlised Minty, herbal 6.50-6.80 0.99-1.04 Miscible 10. STABILITY AND REACTIVITY Reactivity Chemical Stability Conditions to avoid Incompatible Materials Hazardous Decomposition Products Hazardous Reactions Avoid contamination of water, foodstuffs, feed or seed. Product is considered stable and hazardous polymerisation will not occur. Avoid contamination of water, foodstuffs, feed or seed. Decomposition on heating and may produce toxic fumes of carbon monoxide. 11. TOXICOLOGICAL INFORMATION Health Effects Ingestion Eye Contact Skin Contact Inhalation Long term effects Acute Toxicity/ Chronic Toxicity: (ie LD 50 ) Considered to be non toxic. Ingestion may result in nausea, abdominal irritation, pain and diarrhoea. The Powder may produce eye discomfort causing smarting, pain and redness. Not considered an irritant through normal use. Discontinue use if irritation occurs. Not normally a hazard due to non-volatile nature of product. Not available. Data not available to make classification. 12. ECOLOGICAL INFORMATION Ecotoxicity Persistence and Degradability Mobility Other Adverse Effects Bioaccumulation Potential Do not discharge into sewer or waterways. This document becomes uncontrolled once printed. Page 5 of 7
13. DISPOSAL CONSIDERATIONS Disposal methods (including container disposal) Special precautions for landfill or incineration - Recycle wherever possible or consult manufacturer for recycling options. - Consult State Land Waste Management Authority for disposal. - Bury residue in an authorised landfill. - Recycle containers if possible, or dispose of in an authorised landfill. 14. TRANSPORT INFORMATION Regulation UN Number Proper Shipping Name DG Class ADG IMDG IATA Label Additional Information 15. REGULATORY INFORMATION Poisons Schedule (Australia only) APVMA Status TGA Status AICS Status None.. All the constituents of this product are listed on AICS. 16. OTHER INFORMATION SDS Version Number 1.0 SDS Version Date 18/08/2016 Reason for issue New Product Key/Legend to Abbreviations and Acronyms used in the SDS: Abbreviation/Acronym ADG AICS APVMA AQIS AS ASCC DG ERG Code IATA IMDG LD 50 NOHSC SDS STEL TGA TLV TWA UN Number Australian Inventory of Chemical Substances Australian Pesticides and Veterinary Medicines Authority Australian Quarantine and Inspection Service International Air Transport Association International Maritime Dangerous Goods The median lethal toxicological dose, LD 50 is an abbreviation for Lethal Dose, 50%. of a toxic substance. This is the dose required to kill half the members of a tested population. National Occupational Health and Safety Commission Safety Data Sheet Meaning Australian Code for the Transport of Dangerous Goods by Road and Rail Australian Standard (as issued by Standards Australia) Australian Safety and Compensation Council Dangerous Goods Emergency Response Guidebook Code. The Emergency Response Guidebook is used by first responders (eg firefighters, police officers and ambulance personnel) when responding to a transportation emergency involving hazardous materials. Short Term Exposure Limit - A 15 minute TWA exposure which should not be exceeded at any time during a working day even if the eight-hour TWA average is within the TWA exposure standard. Exposures at the STEL should not be longer than 15 minutes and should not be repeated more than four times per day. There should be at least 60 minutes between successive exposures at the STEL. Therapeutic Goods Administration Threshold Limit Value - TLV is a proprietary name registered by the American Conference of Governmental Industrial Hygienists (ACGIH) and refers to airborne concentrations of substances or levels of physical agents to which it is believed that nearly all workers may be repeatedly exposed day after day without adverse effect. Time Weighted Average - The average airborne concentration of a particular substance when calculated over a normal eight-hour working day, for a five-day working week. UN numbers are four-digit numbers that identify hazardous substances, and articles (such as explosives, flammable liquids, toxic substances, etc.) in the framework of international transport. This SDS has been prepared by the ALDI Stores product supplier from current technical data and summarises at the date of issue their best knowledge of the health and safety information of the product, and in particular how to safely handle and use the product in the workplace. This SDS may only be reproduced in full. Summaries or excerpts from this SDS may not contain all the relevant information and thus are not permitted. This document becomes uncontrolled once printed. Page 6 of 7
ALDI Stores gives no warranty and makes no representation as to the accuracy, reliability or completeness of the information contained herein. The user should make their own determination in light of their own circumstances as to the suitability of this information and the safe conditions for the use of this product. To the extent permitted by law, ALDI Stores will not be liable for any loss, damage or expense arising from the use of this SDS, whether caused by the negligent act or omission of ALDI Stores or otherwise. End of SDS This document becomes uncontrolled once printed. Page 7 of 7