picture 1: PROTEGO VD/SV

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PROTEGO FOR SAFETY AND ENVIRONMENT Advantages of Full-lift type vent technology Introduction Low pressure safety relief valves are highly sensitive devices, which have to fulfi ll nearly the same requirements as conventional safety valves with regard to safety and set pressure tolerance. This is particularly required if they are incorporated into a closed control loop. Tightness up to set pressure, minimum set pressure tolerance, minimum pressure increase after start open until full open, that means top performance. Low pressure vents cover a set pressure range starting at 2 mbar (0.79" wc) up to approx. 200 mbar (2.9 psi), conventional safety valves are designed for pressure higher than 0,2 bar (79" wc) as per ISO standard. Even low pressure vents must be able to achieve a leakage rate according to DIN 3230, test procedure B0. Leakage rate 3 represents the minimum standard. In order to reduce emissions, especially nitrogen losses, vents have to comply with leakage rate 2 or even leakage rate 1, if this can be realized economically. The PROTEGO low pressure vents have up to ten times lower leakage rates (up to 50 times lower for 8" sizes and larger) as required by API (American Petrolium Institute) and EPA (Environmental Protection Agency) standards and are state of the art technology. The PROTEGO business focus is mainly directed towards low pressure vents as well as defl agration and detonation fl ame arresters. Since 1985, PROTEGO has achieved many improvements making PROTEGO the world s technology leader in low pressure venting and fl ame arrester technology. This has been realized by investing in Quality Management Systems and permanent product improvement by involving customers and meeting their needs and expectations. Today, PROTEGO is well known worldwide for its high quality and tailor made solutions. picture 1: PROTEGO VD/SV

Technical Advantages of Vents Global companies are now strongly focusing on emission reduction for meeting environmental requirements according to EPA regulations. This emission reduction or vapor loss prevention and nitrogen blanketing gas reduction results in capitals savings. But how to achieve it? Looking into the general performance diagram figure 1: The set pressure pö = pö1 should be as close as possible to the max. allowable tank pressure ptzul (like pö2), to realize a better and wider operating range in the tank. At this new set pressure pö = pö2 the performance (the fl ow rate) shall be additionally increased by an optimized design of the housing (figure 2). The better the design of the housing the higher the volume fl ow V. V VBer. Pö1 Pö2 PTzul. vent performance p in mbar ("wc) fi gure 1: optimization of vent pallet To meet these goals, a new series of conservation vents have been developed, which only require 10% overpressure above the pressure setpoint to reach full performance. Flat standard discs were developed further up to full lift disc vent pallets having a design similar to those of safety valves. This means that the set pressures closer to the Maximum Allowable Working Pressure (MAWP) can be used. For small fl ow rates a fl at standard disc vent has an operating range, which is more or less unstable. The vent pallet operation of those vents, which are permanently working in the low pressure range, is the real problem: The pallet fl utters or hammers. The solution of the problem was a type of vent pallet which releases the complete cross section due to full lift immediately after opening. Actually, full lift pallets are nothing new. Nevertheless, correct sizing of the rim and the relation between vent seat diameter and the height, rim angle and diameter of the rim as well as a sophisticated technique to produce the rim without waviness of the pallet are the V V2 V1 Pö p in mbar ("wc) fi gure 2: improvement of vent performance target fundamental factors that infl uence the vent performance, especially for low set pressures. Moreover, fl uttering in the unstable range is prevented by proper adjustment of lift stop. The vent opening pressure can be selected very close to the maximum allowable tank pressure.

The idealized pressure increase until full open is nearly zero. Reproducible and lower leakage is achieved either by metallic sealing or at low pressure settings supported by air cushioned FEP (Tefl on-) gaskets under the crimped disc (figure 3). The design and accurate imprint of the crimp (figure 3.1) with texturefree metal sheets and a special high polished FEP-surface assure an impressive result. The flow capacity curve for the vent equipped with the fl at disc (=proportional lift pallet) on the one hand and the full lift type disc on the other hand is shown in figure 4. The characteristic shows pressure vs. volume fl ow. The pressure increase for the full lift type pallet vent at the design fl ow rate is nearly zero from start of opening until full lift, in contrast to the 40% pressure increase allowed - as a maximum - by DIN 4119 or even 100% by API. The advantage is using nearly the complete pressure range up to the tank design pressure for vents with real full lift. Flow Capacity Vent Set Pressure for fl at disc (Proportional Lift Pallet) Flow Capacity at full lift overpressure 40% - 2% Full Lift Tank Pressure Allowable Tank Pressure = Vent Set Pressure for Full Lift Pallet fi gure 4: fl ow capacity curve for proportional lift pallet and full lift pallet fi gure 3.1 fi gure 3: full lift vent pallet This is an advantage for the environment, because the vents start to open later and are therefore closed longer, which also reduces losses of blanketing gas, inerting gas or direct product losses. According to API 2000 the typical overpressure rating of weight loaded conservation vents is 80% - 100%. Knowing that higher set pressures can reduce emission and vapor losses signifi cantly (VDI 3479 Guideline), the full lift type technology vent pallet (10% overpressure rating) is a benefi cial asset to increase set pressure close to the MAWP. Figure 5 shows the vapor saving potential of a tank farm for a 100%, 40%, 10% and a theoretical 0% overpressure vent rating. These calculations are based on the VDI 3479 Guideline. The fi gure shows that compared to no pressure holding device (freely vented tank), a 100% pallet achieves a vapor saving of roughly 36%. A 40% pallet achieves a vapor saving of about 51% and a 10% pallet saves an additional 14%. The theoretical value of a 0% pallet would increase the vapor saving by another 6.5%. Replacing 100% vent technology by 10% full lift technology can reduce vapor losses up to 30%.

PROTEGO vents have an overpressure rating as small as 3% - 6% depending on size and construction of the devices, for this reason we included the 0% pallet as an example. For safety reasons we do recommend to use the 10% rating for design purposes. Higher set pressures and lower leakage rates have a direct impact on complying with EPA requirements. PROTEGO offers devices for pressure settings lower than 5 Emission Massfl ow (t/a) and percentage of Emission Reduction 80.00 70.00 60.00 50.00 40.00 30.00 20.00 10.00 0.00 mbar (2.0 "wc) that have an extremely low leakage rate for FEP to metal sealing. The leakage rates depend on the size of the device (table 1). Depending on the set pressure the leakage rates are measured at a test pressure 75%, 80%, 85% and 90% of the set pressure (table 2). In addition to the previously mentioned vent standards, the full lift type pallet technology has advantages in nitrogen blanketing applications (figure 6). For example, in the USA typical set pressures of nitrogen blanketing regulators are 1.8 mbar (0.72 "wc) and the MAWP of the tank is 5 mbar (2.0 "wc) and 100% overpressure pallet has to be set at 2.5 mbar (1.0 "wc). Considering the blow down, the vent closes below 1.8 mbar (0.72 "wc), therefor the pallet fl oats if the nitrogen regulator has opened once. This results in expensive losses of nitrogen. With the full lift type technology the vent can be set higher and reseats above the nitrogen regulator set pressure. In this way nitrogen losses are reduced and vapors are saved. A blow down of 0%, like mentioned in API 2000, table C-1 (operating characteristics of venting devices), is only a theoretical value and can never be achieved in reality. fi gure 5: vapor saving potential for a tank farm 9.78% 35.84% 7.44% 51.27% table 1: admissible leakage rates according to the normal PROTEGO standard, but also lower leakage rates are available (extract of the PROTEGO Quality Standard) nominal width DN admissible leakage rate test time [over] [up to] [bubbles/min] [min 3 /min*] [min] 40 6 1.8 1 40 100 18 5.4 1 100 150 27 8.1 2 150 200 36 10.8 2 200 150 45 13.5 2 250 300 54 16.2 2 300 350 63 18.9 2 350 400 72 21.6 2 400 500 90 27.0 2 table 2: test pressures as a function of the adjusted set pressures for measuring the admissible leakage rates. Adjusted set pressure in mbar ("wc) [over] [up to] 5.31% 65.17% Test pressure as percentage of adjusted set pressure [%] 5 (2.0) 75 5 (2.0) 10 (3.94) 80 10 (3.94) 20 (7.87) 85 20 (7.87) - 90 4.32% 71.66% 100% pallet 40% pallet 10% pallet 0% pallet

Conclusion To fulfi ll the demands of the German clean air act, PROTEGO had to develop state of the art vent technology, with improved sealing capabilities and vapor reduction potential by also increasing the application range of the devices. The goal was met through vents which only need 10% overpressure before reaching full fl ow performance. With the presented vent technology, plant venting installations are benefi cially improved by saving vapor and nitrogen losses. Furthermore, low leakage rates achieved through accurate manufacturing and quality control help to meet more strigent EPA requirements. An additional design advantage of the full lift type technology is the higher fl exibility in setting the vent closer to the set pressure of the emergency relief vents without forcing these into the chattering zone. It is our recommendation to achieve full performance from a conservation vent 10% to 20% below the set pressure of the emergency relief vent. Considering the best available practice ensures save operation for the benefi t of the environment and in addition reduces fi nancial losses. fi gure 6: example: design problem with 100% overpressure technology ERV = emergency relief valve, CV = conservation vent, BV = blanketing vent CV set at 1" wc BV set at 0.72" wc ERV set at 2" wc PROTEGO, FLAMEFILTER and FLAMMENFILTER are international registered trademarks of Flammenfi lter GmbH. Authors: Dr.-Ing. Victor Halstrick, Flammenfi lter (PROTEGO Germany) Dr.-Ing. Michael Davies, PROTEGO (USA), Inc. Dr.-Ing. Philip Bosse, Flammenfi lter (PROTEGO Germany) Layout: Nina Leinemann, Flammenfi lter (PROTEGO Germany)