SECTION 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER Product name: Loctite 7387 Activator Product-Code: 991077 Intended use: activator Supplier: Henkel Australia Pty Ltd 135-141 Canterbury Road 3137 Kilsyth Australia Phone: +61 (61) 3-9724 6444 Fax-no.: +61 (61) 3-9728 7828 Emergency information: 24 HOUR EMERGENCY CONTACT NUMBER 03 9724 6556 SECTION 2. HAZARDS IDENTIFICATION STATEMENT OF HAZARDOUS NATURE: Hazardous according to the criteria of ASCC. Classification of material F - Highly flammable Xn - Harmful N - Dangerous for the environment Risk phrases: R11 Highly flammable. R21/22 Harmful in contact with skin and if swallowed. R36/38 Irritating to eyes and skin. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R65 Harmful: may cause lung damage if swallowed. R67 Vapours may cause drowsiness and dizziness. Safety phrases: S16 Keep away from sources of ignition - No smoking. S23 Do not breathe vapour. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28 After contact with skin, wash immediately with plenty of water and soap. S61 Avoid release to the environment. Refer to special instructions/safety data sheets. S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. Dangerous Goods information: Classified as Dangerous Goods according to the criteria of the Australian Code for the Transport of Dangerous Goods by Road and Rail (ADG Code). Signal word: HAZARDOUS Page 1 of 6 Loctite 7387 Activator
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Identity of ingredients: Chemical ingredients CAS-No. Proportion n-heptane 142-82-5 30-60 % 3,5-Diethyl-1,2-dihydro-1-phenyl-2-propylpyridine 34562-31-7 10-30 % Propan-2-ol 67-63-0 10-30 % Methylcyclohexane 108-87-2 < 5 % octane [and isomers] 111-65-9 < 5 % 3-ethyl-2-propylquinoline 3290-24-2 < 5 % Remainder not hazardous including water~ < 5 % SECTION 4. FIRST AID MEASURES Ingestion: Skin: Eyes: Inhalation: Rinse out mouth. Do not drink. Do not induce vomiting or give anything by mouth because this material can enter the lungs and cause severe lung damage. Get medical attention. Rinse with running water and soap. Seek medical advice. Rinse immediately with plenty of running water (for 10 minutes). Seek medical attention if necessary. Move to fresh air. If adverse health effects develop seek medical attention. SECTION 5. FIRE FIGHTING MEASURES Suitable extinguishing media: Improper extinguishing agent: Combustion behaviour: Decomposition products in case of fire: Particular danger in case of fire: Special protective equipment for fire-fighters: Hazchem code: Foam, extinguishing powder, carbon dioxide. Water jet (solvent-containing product). Solvent containing flammable product. In case of fire toxic gases are released. Oxides of carbon, oxides of nitrogen, irritating organic vapors. Vapours may accumulate in low or confined areas, travel considerable distance to source of ignition, and flash back. In case of fire, keep containers cool with water spray. Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear..3ye SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions and emergency procedures: Remove sources of ignition. Ensure adequate ventilation. Page 2 of 6 Loctite 7387 Activator
Environmental precautions: Clean-up methods: Do not let product enter drains. Wipe up using absorbent material. Store in a partly filled, closed container until disposal. Dispose of contaminated material as waste according to Section 13. SECTION 7. HANDLING AND STORAGE Precautions for safe handling: Conditions for safe storage: Keep away from sources of ignition - no smoking. Vapours should be extracted to avoid inhalation. Use only in well-ventilated areas. Store in a cool, dry place. Do not store near sources of heat or ignition, or reactive materials. Store below 100 F (38 C). SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION National exposure standards: Ingredient form of exposure TWA (ppm) TWA (mg/m3) Peak Limit. (mg/m3) STEL (ppm) STEL (mg/m3) n-heptane 400 1,640 - - - - - - 500 2,050 Propan-2-ol 400 983 - - - - - - 500 1,230 Methylcyclohexane 400 1,610 - - - Octane 300 1,400 - - - - - - 375 1,750 Engineering controls: Ensure adequate ventilation, especially in confined areas. Eye protection: Skin protection: Wear safety glasses with side shields. Suitable protective clothing Solvent resistant gloves such as Viton, poly (vinyl alcohol), or equivalent is recommended. Respiratory protection: Do not inhale vapors and fumes. Use only in well-ventilated areas. If inhalation risk exists, wear a respirator or air supplied mask complying with the requirements of AS/NZS 1715 and AS/NZS 1716. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Amber liquid Odor: Aliphatic Vapor density: Heavier than air Specific gravity: 0.78 Page 3 of 6 Loctite 7387 Activator
Boiling point: Flash point: Vapor pressure: Density: Solubility: VOC content (1999/13/EC) 80 C (176 F) -4 C (24.8 F) 35 mm hg 0.78 g/cm3 Solvent: Water, Not miscible 100 % SECTION 10. STABILITY AND REACTIVITY Stability: Conditions to avoid: Incompatible materials: Stable under recommended storage conditions. Heat, flames, sparks and other sources of ignition. Strong oxidizing agents. Strong acids. Hazardous decomposition products: Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. SECTION 11. TOXICOLOGICAL INFORMATION HEALTH EFFECTS: Ingestion: Skin: Eyes: Inhalation: May be harmful if swallowed. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Aspirated material can enter the lungs and result in pneumonitis. Causes skin irritation. Solvent action can dry and defat the skin, causing the skin to crack, leading to dermatitis. Vapors may irritate eyes. Contact with eyes will cause irritation. May cause respiratory tract irritation. Excessive inhalation of this material causes headache, dizziness, nausea and incoordination. Toxicity data: Acute oral toxicity: Propanol-2 67-63-0 LD 50 (Rat) = 5,045 mg/kg LD 50 (Mouse) = 3,600 mg/kg LD 50 (Dog) = 4,797 mg/kg LD 50 (Rabbit) = 6,410 mg/kg LD 50 (Rat) = 4.7 g/kg LD 50 (Mouse) = 4.5 g/kg LD 50 (Rabbit) = 8.0 g/kg LD 50 (Rabbit) = 5.03 g/kg SECTION 12. ECOLOGICAL INFORMATION General ecological information: Do not empty into drains / surface water / ground water. Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. Page 4 of 6 Loctite 7387 Activator
SECTION 13. DISPOSAL CONSIDERATIONS Waste disposal of product: Dispose of as hazardous waste in compliance with local and national regulations. Waste incineration or special disposal with the approval of the responsible local authority. SECTION 14. TRANSPORT INFORMATION Road and Rail Transport: Dangerous Goods information: Classified as Dangerous Goods according to the criteria of the Australian Code for the Transport of Dangerous Goods by Road and Rail (ADG Code). UN no.: 1993 Proper shipping name: FLAMMABLE LIQUID, N.O.S. (Heptanes,Isopropanol) Class or division: 3 Packaging group: II Hazchem code:.3ye Marine transport IMDG: UN no.: 1993 Proper shipping name: FLAMMABLE LIQUID, N.O.S. (Heptanes,Isopropanol) Class or division: 3 Packaging group: II EmS: F-E,S-E Seawater pollutant: Marine pollutant Air transport IATA: UN no.: 1993 Proper shipping name: Flammable liquid, n.o.s. (Heptanes,Isopropanol) Class or division: 3 Packaging group: II Packaging instructions (passenger) 353 Packaging instructions (cargo) 364 Further information for transport: The shipping classifications in this sections are for non-bulk packaging only (unless otherwise specified). Shipping classification may be different for bulk packaging. SECTION 15. REGULATORY INFORMATION SUSDP Poisons Schedule: 5 AICS: All components are listed or are exempt from listing on the Australian Inventory of Chemical Substances (AICS). SECTION 16. OTHER INFORMATION Abbreviations/acronyms: ADGC - Australian Dangerous Goods Code ASCC - Australian Safety and Compensation Council SUSDP - Standard for the Uniform Scheduling of Drugs and Poisons STEL - Short term exposure limit TWA - Time weighted average Page 5 of 6 Loctite 7387 Activator
Reason of change: Reviewed MSDS. Reissued with new date. involved chapters: Date of previous issue: 28.04.2009 Disclaimer: The percentage weight (% w/w) of ingredients is not to be taken as a specification guaranteed by Henkel Australia Pty. Limited, but only as an approximate guide to the content of hazardous ingredients in the material. The information contained herein does not constitute a guarantee by Henkel Australia Pty. Limited concerning the properties of the material. The information contained in this Material Safety Data Sheet is offered in good faith and has been developed from what is believed to be accurate and reliable sources. The information is offered without warranty, representation, inducement or licence and Henkel Australia Pty. Limited assumes no legal responsibility for reliance upon same. Henkel Australia Pty. Limited disclaims any liability for loss, injury or damage incurred in connection with the use of the material or its associated Material Safety Data Sheet. This information is not to be construed as a representation that the material is suitable for any particular purpose or use except those conditions and warranties implied by either Commonwealth or State statutes. Customers are encouraged to make their own enquiries as to the material's characteristics and, where appropriate, to conduct their own tests in the specific context of the material's intended use. Page 6 of 6 Loctite 7387 Activator